Biology Chapter on Elements and Molecules
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Questions and Answers

What is the approximate percentage of living matter composed of carbon, hydrogen, oxygen, and nitrogen?

  • 4%
  • 96% (correct)
  • 20-25%
  • 75%
  • Which subatomic particle has a positive charge?

  • Proton (correct)
  • Neutron
  • Electron
  • Isotope
  • What is the atomic number of an element defined by?

  • The number of protons in the nucleus. (correct)
  • The number of electrons in the electron cloud.
  • The number of neutrons in the nucleus.
  • The total number of protons and neutrons in the nucleus.
  • What is the term for atoms of the same element that differ in the number of neutrons?

    <p>Isotopes (B)</p> Signup and view all the answers

    Which of the following is true about a cation?

    <p>It has more protons than electrons, resulting in a positive charge. (C)</p> Signup and view all the answers

    What makes radioactive isotopes unstable?

    <p>They spontaneously decay, emitting particles and energy. (C)</p> Signup and view all the answers

    What determines the mass number of an atom?

    <p>The sum of protons and neutrons in the nucleus. (A)</p> Signup and view all the answers

    Which of the following is NOT considered a trace element?

    <p>Calcium (B)</p> Signup and view all the answers

    What is the primary role of a buffer in a biological system?

    <p>To maintain a stable pH by binding or releasing H+ ions. (B)</p> Signup and view all the answers

    Which of the following best describes the versatility of carbon in organic molecules?

    <p>Its electron configuration that allows it to form covalent bonds with multiple elements. (B)</p> Signup and view all the answers

    How does the structure of carbon chains contribute to the diversity of organic molecules?

    <p>They can vary in length, shape, and bonding patterns. (C)</p> Signup and view all the answers

    How do functional groups contribute to the properties of organic molecules?

    <p>They are components that are involved in the chemical reactions and determine the unique characteristics of a molecule. (C)</p> Signup and view all the answers

    What primarily determines an atom's chemical behavior?

    <p>The distribution of electrons in its electron shells (A)</p> Signup and view all the answers

    How can two steroid hormones, such as estradiol and testosterone, with the same carbon skeleton have different properties?

    <p>They differ in the type and arrangement of functional groups attached to the carbon rings. (B)</p> Signup and view all the answers

    What is the term for electrons located in the outermost shell of an atom?

    <p>Valence electrons (B)</p> Signup and view all the answers

    What is the maximum number of electrons that the first electron shell of an atom can typically accommodate?

    <p>2 (D)</p> Signup and view all the answers

    A covalent bond is formed by which process?

    <p>Sharing of a pair of valence electrons between two atoms (A)</p> Signup and view all the answers

    What is the primary difference between a molecule and a compound?

    <p>All compounds are molecules, but not all molecules are compounds. (C)</p> Signup and view all the answers

    What does the term "valence" refer to in the context of an atom?

    <p>The bonding capacity of an atom (B)</p> Signup and view all the answers

    What causes the formation of partial positive and negative charges within a molecule?

    <p>Unequal sharing of electrons due to electronegativity differences (D)</p> Signup and view all the answers

    What is the primary distinction between polar and nonpolar covalent bonds?

    <p>Polar bonds involve unequal sharing of electrons due to differences in electronegativity, whereas nonpolar bonds involve equal sharing. (C)</p> Signup and view all the answers

    What type of bond is formed due to the attraction between a cation and an anion?

    <p>Ionic bond (B)</p> Signup and view all the answers

    In an ionic compound, such as MgCl2, what does the formula represent?

    <p>The ratio of ions in the crystal lattice (A)</p> Signup and view all the answers

    What is required for the formation of a hydrogen bond?

    <p>A hydrogen atom covalently bonded to an electronegative atom and attraction to another electronegative atom (D)</p> Signup and view all the answers

    Which of the following is most associated with a 'hot spot' of positive or negative charge formation?

    <p>Van der Waals interactions (C)</p> Signup and view all the answers

    What is the primary reason water is considered a versatile solvent?

    <p>Its polarity and capacity to form hydrogen bonds. (B)</p> Signup and view all the answers

    What is the term used to refer to the starting molecules of a chemical reaction?

    <p>Reactants (A)</p> Signup and view all the answers

    What term describes a substance that does not have an affinity for water?

    <p>Hydrophobic (B)</p> Signup and view all the answers

    When is chemical equilibrium reached in a reversible reaction?

    <p>When the forward and reverse reactions occur at the same rate (C)</p> Signup and view all the answers

    What is the result of a water molecule gaining an extra proton?

    <p>A hydronium ion (H3O+) (A)</p> Signup and view all the answers

    What is the pH of a neutral aqueous solution at 25°C?

    <p>7 (B)</p> Signup and view all the answers

    Why is water considered a polar molecule?

    <p>Because of the highly electronegative oxygen atoms causing an uneven charge distribution (B)</p> Signup and view all the answers

    What is the role of a buffer in a solution?

    <p>To minimize changes in the concentrations of H+ and OH−. (B)</p> Signup and view all the answers

    In the context of chemical reactions, what is conserved?

    <p>The number of atoms (C)</p> Signup and view all the answers

    Which of the following represents a base according to the text?

    <p>$NH_3 + H^+ \rightarrow NH_4^+$ (C)</p> Signup and view all the answers

    What type of bond allows water to have a high degree of versatility as a solvent?

    <p>Hydrogen bond (D)</p> Signup and view all the answers

    If a solution has a pH of 3, what is true about the solution?

    <p>It is acidic. (D)</p> Signup and view all the answers

    Flashcards

    Element

    A substance that cannot be broken down into simpler substances by chemical reactions.

    Atom

    The smallest unit of matter that retains the properties of an element.

    Atomic number

    The number of protons in an atom's nucleus.

    Mass number

    The sum of protons and neutrons in an atom's nucleus.

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    Isotopes

    Atoms of the same element that have the same number of protons but different numbers of neutrons.

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    Ion

    An atom or molecule with a net electrical charge due to the gain or loss of electrons.

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    Electron’s energy

    The potential energy that an electron possesses.

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    Chemical bonding

    The formation and function of molecules depend on the chemical bonds between atoms that connect them.

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    Electronegativity

    An atom's ability to attract shared electrons in a covalent bond.

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    Nonpolar covalent bond

    Atoms share electrons equally. Example: H-H

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    Polar covalent bond

    Atoms share electrons unequally, creating partial positive and negative charges. Example: Water (H2O)

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    Weak chemical bonds

    Weak chemical bonds (e.g., hydrogen bonds) that play a crucial role in the function of molecules.

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    Covalent bond

    The sharing of a pair of valence electrons by two atoms.

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    Molecule

    Two or more atoms held together by covalent bonds.

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    Compound

    A combination of two or more different elements held together by covalent bonds.

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    Valence

    The number of covalent bonds an atom can form. Example: Hydrogen has a valence of 1, Oxygen has a valence of 2.

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    Ionic bond

    A chemical bond formed by the attraction between oppositely charged ions. It arises when one atom donates an electron to another, creating a positively charged ion (cation) and a negatively charged ion (anion).

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    Ionic compound

    Compounds formed by ionic bonds. These compounds consist of repeating patterns of cations and anions organized in a crystal lattice. They do not exist as individual molecules.

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    Hydrogen bond

    A weak chemical bond that arises from the attraction between a hydrogen atom covalently linked to a highly electronegative atom (usually oxygen or nitrogen) and another electronegative atom.

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    Van der Waals interactions

    Weak attractions between molecules that arise from temporary, fluctuating, uneven distributions of electrons within the molecule.

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    Chemical reaction

    The process of making and breaking chemical bonds. It involves the rearrangement of atoms and molecules.

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    Reactants

    The starting molecules involved in a chemical reaction.

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    Products

    The final molecules that result from a chemical reaction.

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    Chemical equilibrium

    A state in a reversible chemical reaction where the rates of the forward and reverse reactions are equal. It does not mean the concentrations of reactants and products are the same.

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    Polarity

    The ability of a molecule to attract or repel electrons, leading to a slightly positive or negative end.

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    Aqueous Solution

    A solution where water is the dissolving agent.

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    Hydrophilic

    A substance that has an affinity for water, meaning it readily dissolves in water.

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    Hydrophobic

    A substance that repels water, meaning it does not dissolve in water.

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    Water Dissociation

    The process of water molecules dissociating into hydrogen ions (H+) and hydroxide ions (OH-) with equal rates.

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    pH

    A measure of the acidity or basicity of a solution.

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    Acid

    A substance that increases the hydrogen ion (H+) concentration of a solution, making it more acidic.

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    Base

    A substance that decreases the hydrogen ion (H+) concentration of a solution, making it more basic.

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    What is a buffer solution?

    A buffer solution is a mixture of a weak acid and its conjugate base, which resists changes in pH upon addition of small amounts of either acid or base. This is because the weak acid can neutralize added base, and the conjugate base can neutralize added acid.

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    Why is carbon important for life?

    Carbon is the backbone of life, forming the basis of all organic molecules. It is able to form long chains and rings, allowing for a wide variety of complex structures.

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    What are functional groups?

    Functional groups are specific arrangements of atoms in organic molecules that contribute to their unique properties. They often determine how molecules react and interact with other molecules.

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    What are hydrocarbons?

    Hydrocarbons are organic molecules composed solely of carbon and hydrogen atoms. They form the basis of many fuels and are also found in lipids (fats and oils).

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    Why is carbon so versatile?

    The versatility of carbon stems from its ability to form four covalent bonds. This allows it to create long chains, branched structures, and rings, leading to the vast diversity of organic molecules.

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    Study Notes

    Lecture 1: Chemical Biology

    • Matter is composed of chemical elements in pure form or combined as compounds.
    • An element's properties are determined by its atomic structure.
    • Molecular formation and function depend on chemical bonds between atoms.
    • Covalent bonds in water molecules lead to hydrogen bonding.
    • Acidic and basic conditions influence living organisms' properties.
    • Carbon forms diverse molecules by bonding with up to four other atoms.
    • Specific chemical groups are essential for molecular function.

    1.1 Atoms

    • Each element consists of unique atoms, the smallest units maintaining element properties.
    • Atoms are comprised of subatomic particles (neutrons, protons, and electrons).
    • Neutrons and protons form the atomic nucleus.
    • Electrons orbit the nucleus in electron clouds.

    Elements

    • Matter is comprised of elements that can't be broken down chemically.
    • Approximately 20-25% of the 92 natural elements are crucial for life.
    • The four most abundant elements in living matter are carbon, hydrogen, oxygen, and nitrogen (make up ~96% of living matter).
    • Other essential elements include calcium, phosphorus, potassium, and sulfur (also vital components).

    Table 2.1 Elements in the Human Body

    • Provides the percentage of body mass for various elements, including major and trace elements.
    • Oxygen accounts for 65.0% of the body's mass.
    • Carbon accounts for 18.5% of the body's mass.
    • Hydrogen constitutes 9.5% of the body's mass
    • Additional elements contribute to the remaining 3.7%.

    Atoms

    • Each element is characterized by its unique atomic structure.

    Atomic Number and Mass Number

    • Atoms of different elements vary in the number of subatomic particles.
    • Atomic number: the number of protons in an atom's nucleus
    • Mass number: the total number of protons and neutrons in an atom.
    • Approximate atomic mass can be determined from mass number (Protons + Neutrons).

    Isotopes

    • Atoms of the same element might have differing numbers of neutrons, thus generating isotopes.
    • Radioactive isotopes decay spontaneously releasing particles and energy.
      • Example: Carbon-12, Carbon-13, Carbon-14

    Ions

    • An ion is an atom or molecule with an unequal number of protons and electrons, conferring a net charge.
    • A cation is formed when an atom loses an electron (positive charge).
    • An anion is formed when an atom gains an electron (negative charge).
      • Example: Sodium (Na+) and Chloride (Cl-)

    Electrons' Energy

    • Electrons in atoms have varying potential energies.
    • Electron shells or energy levels describe these energy states (first shell, second shell, etc.).
    • An atom's chemical behavior depends on the arrangements of electrons within these shells.

    Periodic Table

    • The periodic table displays elements' electron distributions.
    • Rows represent periods reflecting atomic shell numbers.
    • Columns correspond to additions of electrons in the valence shell.
    • Valence electrons determine an atom's chemical reactivity.
    • Atoms with complete valence shells (inert elements) exhibit stable chemical properties.

    1.2 Chemical Bonds

    • Covalent, ionic, hydrogen, and Van der Waals forces form bonds.

    Covalent Bonds

    • Atoms share one or more electron pairs to attain complete valence shells.
      • Single, double, or triple bonds indicate multiple shared pairs.
    • Molecules are formed from atoms held together by covalent bonds.
    • Sharing of electrons may involve atoms of different elements.
      • Example of molecules formed by covalent bonding: O2, H2O, CH4.

    Valence

    • Valence is the bonding capacity of an atom.
    • Example: Valence numbers for H, O, N, and C are 1, 2, 3, and 4 respectively

    Electronegativity

    • Atoms exhibit varying attractions for shared electrons in covalent bonds (electronegativity).
    • Nonpolar covalent bonds: Equal sharing of electrons.
    • Polar covalent bonds: Unequal sharing of electrons results in partial charges on atoms.

    Ionic Bonds

    • Atoms gain or lose valence electrons, forming ions with opposite charges.
    • An ionic bond results from the electrostatic attraction between oppositely charged ions.

    Ionic Compounds

    • Ionic compounds, also called salts, are formed from ionic bonds.
    • Unlike molecules, ionic compounds form crystal lattices rather than distinct molecules.

    Hydrogen Bonds

    • A hydrogen bond forms when a hydrogen atom covalently bonded to an electronegative atom (like oxygen or nitrogen) is attracted to another electronegative atom.

    Van der Waals Interactions

    • Weak attractions between molecules due to temporary, fluctuating charges.
      • These attractions can be significant when many molecules interact.

    Chemical Reactions

    • Chemical reactions involve the making and breaking of chemical bonds.
    • Reactants are transformed into products.
    • Matter is conserved (atoms are neither created nor destroyed).
    • Most reactions are reversible (products can revert to reactants).
    • Chemical equilibrium occurs when forward and reverse rates are equal.

    1.3 Water and pH

    Water as a Polar Molecule

    • Water's polarity arises from the oxygen atom's high electronegativity.
    • Water molecules form hydrogen bonds with each other due to their polarity.

    Aqueous Solutions

    • In an aqueous solution, water is the solvent, dissolving other substances.
    • Water's polarity makes it a versatile solvent.
    • When ionic solutes are dissolved in water, they're surrounded by water molecules (hydration shell).

    Dissolution of Nonionic Molecules

    • Water can dissolve nonionic polar substances if they have polar or ionic parts.
    • Polar molecules (hydrophilic) have affinity for water.
    • Nonpolar molecules (hydrophobic) do not have an affinity for water.

    Water Dissociation

    • A hydrogen atom can shift between water molecules causing dissociation into H+ and OH- ions.
    • Water molecules, with extra protons, become hydronium (H3O+ ) while hydroxyl (OH-) ions are formed.

    pH

    • pH quantifies a solution's hydrogen ion (H+) concentration.
      • pH scale ranges from 0 to 14.
      • pH 7 is neutral
      • pH values less than 7 indicate acidity.
      • pH values greater than 7 indicate alkalinity.

    pH Scale

    • A scale for measuring the acidity or basicity of a solution.
    • Acids increase H+ concentration.
    • Bases decrease H+ concentration.
    • pH affects the chemical properties and functions in biological organisms.

    Buffers

    • Buffers resist changes in pH by absorbing and releasing H+ ions.
    • Crucial to maintain stable biological conditions.
      • Example: carbonic acid-bicarbonate system.

    1.4 Organic Molecules

    • Most biological molecules are carbon-based.
    • Carbon forms extensive complex molecules with many diverse shapes and properties.

    Life is carbon-based

    • Living organisms are largely composed of carbon compounds.
    • Carbon's ability to form numerous bonds facilitates the diversity of complex organic molecules.
    • Organic compounds include proteins, DNA, and carbohydrates

    Versatility of Carbon

    • Carbon's electron configuration allows for diverse covalent bonding partnerships.
    • Valency: Number of bonds carbon can form—four.
    • Hydrogen(H): one bond
    • Oxygen (O): two bonds
    • Nitrogen (N): three bonds.

    Carbon Skeleton

    • Carbon chains form the backbones of most organic molecules.
    • Carbon chain length, branching, double bond positioning, and ring structure influence properties.
    • Hydrocarbons are organic molecules built from only carbon and hydrogen.

    Importance of Functional Groups

    • Functional groups: Groups of atoms attached to the carbon skeleton.
    • They impart specific properties to organic molecules and participate in many reactions.
    • Example: Estrogen and testosterone (steroids)

    Hydroxyl and Carbonyl Groups

    • Hydroxyl (–OH) group: makes molecules soluble in water; important in alcohols.

    • Carbonyl (C=O) group: found in ketones and aldehydes, sugars and other molecules.

    Carboxyl and Amino Groups

    • Carboxyl (-COOH) group: acts as an acid, donating H+ ions; crucial for organic acids (like acetic acid) and contributing to a molecule's polarity.
    • Amino (-NH2) group: acts as a base, accepting H+ ions; vital for amines and amino acids.

    Phosphate and Methyl Groups

    • Phosphate (-OPO32-) group: contributes negative charge and releases energy when hydrolyzed; essential for many biological molecules such as ATP.
    • Methyl (-CH3) group: affects gene expression and shapes proteins or hormones by modifying its molecules.

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