Alkenes and Their Reactivity Quiz
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Questions and Answers

Alkenes are more reactive than alkanes due to the presence of a weaker π bond in the C=C double bond.

True

The typical reaction of alkenes is ______ addition reactions.

electrophilic

What is the main reason why alkenes are more reactive than alkanes?

  • Alkenes have a higher number of carbon atoms.
  • Alkenes have a weaker π bond in the C=C double bond. (correct)
  • Alkenes have a stronger C-C bond.
  • Alkenes are more soluble in water.
  • What type of species are attracted to the electron-rich center of the C=C double bond in alkenes?

    <p>Electrophiles</p> Signup and view all the answers

    Match the following terms with their descriptions:

    <p>Electrophile = An electron-deficient species that attacks the π bond of an alkene. Carbocation = A positively charged species formed during the reaction of an alkene with an electrophile. Addition reaction = A reaction in which a molecule adds across a multiple bond, breaking the double or triple bond. π bond = The weaker bond in the C=C double bond that is easily broken by electrophiles.</p> Signup and view all the answers

    What is the primary structural requirement for a molecule to exhibit cis/trans isomerism?

    <p>Restricted rotation around a double bond.</p> Signup and view all the answers

    Cis and trans isomers have different chemical formulas.

    <p>False</p> Signup and view all the answers

    In a cis isomer, are the substituent groups on the same side or opposite sides of the double bond?

    <p>same side</p> Signup and view all the answers

    The rotation around a carbon-carbon double bond is generally ______.

    <p>restricted</p> Signup and view all the answers

    Match the isomer type to its description:

    <p>Cis isomer = Substituents on the same side of the double bond Trans isomer = Substituents on opposite sides of the double bond</p> Signup and view all the answers

    What is the functional group of alkenes?

    <p>Carbon-carbon double bond</p> Signup and view all the answers

    Alkenes are considered saturated hydrocarbons.

    <p>False</p> Signup and view all the answers

    What is the general formula for alkenes?

    <p>$C_nH_{2n}$</p> Signup and view all the answers

    The first member of the alkene series is ______.

    <p>ethene</p> Signup and view all the answers

    Match the alkene with its boiling point:

    <p>Ethene = -104 °C Propene = -48 °C Butene = -6 °C</p> Signup and view all the answers

    What is the primary difference between cis and trans isomers that affects their boiling points?

    <p>The presence of dipole-dipole interactions in cis isomers.</p> Signup and view all the answers

    Trans isomers have a higher melting point because they pack more efficiently in the solid state.

    <p>True</p> Signup and view all the answers

    What type of intermolecular forces are present in both cis and trans isomers?

    <p>van der Waals dispersion forces</p> Signup and view all the answers

    The shape of the cis isomer is often described as ______, which hinders efficient packing in the solid phase.

    <p>U-shaped</p> Signup and view all the answers

    Match the isomer type with its corresponding property:

    <p>Cis Isomer = Higher boiling point, lower melting point Trans Isomer = Lower boiling point, higher melting point</p> Signup and view all the answers

    What is the primary catalyst used for the hydrogenation of alkenes?

    <p>Nickel</p> Signup and view all the answers

    Alkenes do not react with bromine solution under normal conditions.

    <p>False</p> Signup and view all the answers

    What does the reaction between ethene and hydrogen produce?

    <p>alkane</p> Signup and view all the answers

    The process of converting vegetable oil into margarine is known as _____.

    <p>hydrogenation</p> Signup and view all the answers

    Match the following reactions with their descriptions:

    <p>Hydrogenation = Formation of an alkane from an alkene and hydrogen Halogenation = Reaction of an alkene with bromine Bromination = Chemical test for unsaturated hydrocarbons Hydration = Addition of water to an alkene</p> Signup and view all the answers

    What product is formed when ethene reacts with concentrated $H_2SO_4$?

    <p>Hydrogensulfate(VI)</p> Signup and view all the answers

    Halogenation involves the reaction of alkenes with halogens to form alkanes.

    <p>False</p> Signup and view all the answers

    What is the byproduct produced when refluxing hydrogensulfate(VI) with water?

    <p>Sulfuric acid</p> Signup and view all the answers

    The process where ethene reacts with hydrogen halides is known as __________.

    <p>halogenation</p> Signup and view all the answers

    Match the following reactions with their corresponding products:

    <p>Ethene + $H_2SO_4$ = Hydrogensulfate(VI) Hydrogensulfate(VI) + H₂O = Ethanol Ethene + Halogen = Halogenoalkane Ethanol + H₂SO₄ = No significant product</p> Signup and view all the answers

    What is the temperature required for the dehydration of alcohols to form alkenes?

    <p>180°C</p> Signup and view all the answers

    Dehydration of alcohols can occur without the presence of a β-hydrogen.

    <p>False</p> Signup and view all the answers

    What reagent is commonly used in the dehydration of alcohols to form alkenes?

    <p>Excess H₂SO₄</p> Signup and view all the answers

    Dehydrohalogenation occurs using hot, alcoholic _____ to form alkenes.

    <p>KOH</p> Signup and view all the answers

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