Alcohol, Phenol, Ether PDF
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Summary
The document presents detailed information about the chemical properties, reactions, and preparation methods of alcohols, phenols, and ethers. The notes illustrate various chemical mechanisms, such as addition, oxidation, and reduction.
Full Transcript
Alcohol, Phenol , Ether OH Alcohols 1H20...
Alcohol, Phenol , Ether OH Alcohols 1H20 + CH3 H I I R-CH = CH2 R CH CH3 - - of CH, CHy-CHz-OH - y--- CH - 1o alcohol dis H+ R-CH - CH H20 2: alcohol So alcohol Carbocation OH vinylic alcohol x Electrophilic Addition CHI = CH - Rate of a stability of x alcohol CH2CH-cHy-oH allylic = Run Carbocation Benzylic alcohol CHOH Mercuration) 2) OMDM (Ony Mercuration De CH2-OH CH2-OH ) HgCOAC2 OH tRO dre-or R cte R-CH CH2 2) CH - - = OH NaBHn CH2 = ethylene glycol dia-or Source ofOH: - H20 glycerol Source of H: -NaBHy PreparationofAlcohols NOTE: addition From Alkenes Addition ofWater x Ants ) Markovnikoy'srule a) Acidcatalysed hydration > No rearrangement Reagent: bil. H2SO4 or HT H20 or Hot > No carbocation Cyclic x intermediate - ** ~
