Calculate the number of moles of solute present in each of the following solutions: (a) 245 mL of 1.50 M HNO3; (b) 50.0 mg of an aqueous solution that is 1.25 m NaCl.

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Understand the Problem

The question is asking to calculate the number of moles of solute in two different solutions: one is given in milliliters and molarity (M) of HNO₃, and the other in milligrams and molarity (m) of NaCl. We will apply the formulas for calculating moles from volume and concentration.

Answer

(a) $0.3675$ moles of HNO₃; (b) $0.000856$ moles of NaCl.
Answer for screen readers

(a) The number of moles of HNO₃ is approximately 0.3675 moles.

(b) The number of moles of NaCl is approximately 0.000856 moles.

Steps to Solve

  1. Calculate Moles of HNO₃ To find the number of moles of HNO₃, we use the formula: $$ \text{moles} = \text{molarity} \times \text{volume (L)} $$ Convert 245 mL to liters: $$ 245 , \text{mL} = 0.245 , \text{L} $$ Now substitute the values into the formula: $$ \text{moles of HNO}_3 = 1.50 , \text{M} \times 0.245 , \text{L} $$

  2. Calculate Moles of NaCl For NaCl, we start by converting the mass from milligrams to grams: $$ 50.0 , \text{mg} = 0.0500 , \text{g} $$ Next, we convert grams to moles using the formula: $$ \text{moles} = \frac{\text{mass (g)}}{\text{molar mass (g/mol)}} $$ The molar mass of NaCl is approximately 58.44 g/mol. Therefore: $$ \text{moles of NaCl} = \frac{0.0500 , \text{g}}{58.44 , \text{g/mol}} $$ Finally, since the concentration is molality (m), we must consider the density of the solution if needed; however, in this case, we calculate the moles directly from the mass.

  3. Finalizing the Calculations Calculating both moles:

  • For HNO₃: $$ \text{moles of HNO}_3 = 1.50 \times 0.245 = 0.3675 , \text{moles} $$

  • For NaCl: $$ \text{moles of NaCl} = \frac{0.0500}{58.44} \approx 0.000856 , \text{moles} $$

(a) The number of moles of HNO₃ is approximately 0.3675 moles.

(b) The number of moles of NaCl is approximately 0.000856 moles.

More Information

  • Molarity (M) is defined as moles of solute per liter of solution.
  • Molality (m) is defined as moles of solute per kilogram of solvent; however, in this case, we're using mass to find moles directly.
  • The calculations involve unit conversions from mL to L and mg to g.

Tips

  • Forgetting to convert units (like mL to L or mg to g).
  • Confusing molality with molarity. Ensure you use the correct definitions for your calculations.
  • Not including the correct molar mass for the solute.

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