Solubility Unit Quiz
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Questions and Answers

What occurs when ionic compounds are separated into their individual ions?

  • Dissociation (correct)
  • Precipitation
  • Solvation
  • Hydration

Which statement accurately describes a saturated solution?

  • It is at equilibrium with the solute and solvent. (correct)
  • It contains no undissolved solute.
  • It contains more solute than can usually dissolve.
  • It is unable to dissolve any solute.

Which factor does NOT affect the solubility of a solute in a solvent?

  • Temperature of the solution
  • Size of the solute particles (correct)
  • Nature of the solute and solvent
  • Pressure of the environment

What happens to the solubility of most solid solutes as temperature increases?

<p>It increases. (D)</p> Signup and view all the answers

Which of the following is an example of a covalent solid dissolving in water?

<p>C6H12O6 (s) → C6H12O6 (aq) (C)</p> Signup and view all the answers

What is the definition of 'hydration' in the context of solubility?

<p>The process by which solute molecules are surrounded by solvent molecules. (D)</p> Signup and view all the answers

What is true regarding the solubility of gases in liquids as temperature increases?

<p>It typically decreases. (D)</p> Signup and view all the answers

What characterizes the particles in a colloid compared to those in a suspension?

<p>Colloid particles are smaller and do not settle out. (B)</p> Signup and view all the answers

What does 'like dissolves like' refer to in the context of solubility?

<p>Similar types of substances tend to dissolve well together. (A)</p> Signup and view all the answers

In a dissociation equation, what are the products generated when a chemical dissolves?

<p>Ions only (A)</p> Signup and view all the answers

What is the molarity of a solution if 0.75 moles of CaCl are dissolved in 2.5 liters of solution?

<p>0.3 M (D)</p> Signup and view all the answers

How many grams of KCl are needed to create a 0.2 M solution in 1.8 L of water?

<p>30 g (D)</p> Signup and view all the answers

If you need to dilute 18 M H2SO4 to create 2 M H2SO4, how much of the concentrated solution is required for 1.5 L of the diluted solution?

<p>0.167 L (A)</p> Signup and view all the answers

To what volume does 10 g of NaCl increase the molarity of an existing 180 mL solution to get the new molarity?

<p>230 mL (B)</p> Signup and view all the answers

What does Henry's law state regarding the solubility of gases?

<p>Solubility is directly proportional to the pressure of the gas above the liquid. (D)</p> Signup and view all the answers

What is the relationship between molarity (M) and concentration?

<p>Molarity is a measure of concentration in moles per liter. (D)</p> Signup and view all the answers

Which of the following is NOT a factor affecting the rate of dissolving?

<p>Pressure of the gas above the liquid (B)</p> Signup and view all the answers

What does a chemical need to be classified as an electrolyte?

<p>It must dissolve in water and produce ions. (A)</p> Signup and view all the answers

What characterizes an undersaturated solution?

<p>It is below the solubility curve. (A)</p> Signup and view all the answers

Which colligative property relates to the need for more heat to boil a solution?

<p>Boiling point elevation (A)</p> Signup and view all the answers

How does the presence of a solute in a solution affect vapor pressure?

<p>It reduces the vapor pressure due to interference with vaporization. (A)</p> Signup and view all the answers

What is a key characteristic of a suspension?

<p>It settles out if left undisturbed. (D)</p> Signup and view all the answers

What happens to the freezing point of water when a solute is added?

<p>It decreases. (B)</p> Signup and view all the answers

What differentiates a solution from a mixture?

<p>Solutions are uniform in composition with a single phase. (A)</p> Signup and view all the answers

What is the molarity of the new solution after adding 10g of NaCl to the original 0.18L solution?

<p>2.44M (A)</p> Signup and view all the answers

How many moles of HCl are present in 1.5L of a 3.5M solution?

<p>5.25 mol (D)</p> Signup and view all the answers

Using reaction stoichiometry, how many moles of Mg are required to react with 5.25 moles of HCl?

<p>2.625 mol (C)</p> Signup and view all the answers

What is the molarity of the solution when 150 ml of a 2M solution is mixed with 550 ml of a 3.5M solution?

<p>3.17M (C)</p> Signup and view all the answers

What is the final mass of Na2SO4 formed when 500ml of a 4.5M solution of H2SO4 is mixed with excess NaOH?

<p>126.5g (C)</p> Signup and view all the answers

How many grams of magnesium (Mg) are needed to react with 5.25 moles of HCl?

<p>63.85g (D)</p> Signup and view all the answers

Which balanced equation correctly represents the reaction between sulfuric acid and sodium hydroxide?

<p>H2SO4 + 2NaOH -&gt; Na2SO4 + H2O (D)</p> Signup and view all the answers

What is the total volume of the resulting solution when 150 ml of a 2M solution is mixed with 550 ml of a 3.5M solution?

<p>700 ml (D)</p> Signup and view all the answers

What is the term used when solvent molecules surround solute molecules?

<p>Solvation (A)</p> Signup and view all the answers

What happens to the solubility of gases in liquids at higher temperatures?

<p>Solubility decreases (B)</p> Signup and view all the answers

Which of the following best describes a saturated solution?

<p>At equilibrium with crystallization (C)</p> Signup and view all the answers

What does the term 'crystallization' refer to in the context of solutions?

<p>Formation of solid solute from a saturated solution (B)</p> Signup and view all the answers

What characteristic best illustrates the phrase 'like dissolves like'?

<p>Polar solvents dissolve polar solutes (D)</p> Signup and view all the answers

Which condition is required for a solution to be classified as super-saturated?

<p>Contains more solute than maximum without crystallization (A)</p> Signup and view all the answers

In which scenario would you expect an increase in the solubility of a solid solute?

<p>Increase in temperature (C)</p> Signup and view all the answers

What is the primary factor that affects the rate of dissolving an ionic solid in water?

<p>Temperature of the water (D)</p> Signup and view all the answers

What is the molarity of a solution that contains 50g of sodium chloride (NaCl) dissolved in 1L of water? (Molar mass of NaCl = 58.44 g/mol)

<p>1.0 M (A)</p> Signup and view all the answers

How many grams of potassium chloride (KCl) are in a 0.5 M solution with a total volume of 3 L? (Molar mass of KCl = 74.55 g/mol)

<p>222.65 g (B)</p> Signup and view all the answers

What is the final concentration of sodium chloride after mixing 100 mL of a 3M solution with 400 mL of a 1.5M solution?

<p>2.25 M (D)</p> Signup and view all the answers

What volume of water is needed to dilute 500 mL of a 5M solution of HCl to a 1M solution?

<p>2000 mL (D)</p> Signup and view all the answers

To create a 0.5 M solution, how many moles of solute are needed in 1.5 L of solution?

<p>0.75 moles (D)</p> Signup and view all the answers

What final concentration results from combining 250 mL of a 2M solution and 750 mL of a 4M solution?

<p>3.0 M (A)</p> Signup and view all the answers

If 10g of NaCl are added to 500 mL of a solution already at 1 M, what will be the new molarity? (NaCl = 58.44 g/mol)

<p>1.5 M (C)</p> Signup and view all the answers

What is the number of moles in 2 L of a 2.5M solution?

<p>5.0 moles (C)</p> Signup and view all the answers

What effect does increasing the surface area of a solute have on its rate of dissolving?

<p>It increases the rate of dissolution. (C)</p> Signup and view all the answers

How does the presence of a solute affect the boiling point of a solution compared to pure solvent?

<p>It raises the boiling point and requires more heat to boil. (B)</p> Signup and view all the answers

Which of the following correctly describes an undersaturated solution?

<p>It has not reached its maximum solubility and can dissolve more solute. (A)</p> Signup and view all the answers

What happens to the freezing point of a solution when a solute is added?

<p>It decreases, requiring more energy removal to solidify. (A)</p> Signup and view all the answers

Which of the following is NOT a colligative property?

<p>Melting point elevation (D)</p> Signup and view all the answers

What is the relationship described by Henry's law?

<p>The solubility of a gas in a liquid is directly proportional to the pressure of the gas above it. (A)</p> Signup and view all the answers

What characterizes a suspension compared to a colloid?

<p>A suspension will settle out if left undisturbed. (C)</p> Signup and view all the answers

What is indicated by a high vapor pressure in a liquid?

<p>The liquid is likely to evaporate quickly. (A)</p> Signup and view all the answers

What is the final molarity of the new solution after adding 10g of NaCl to the original 0.18L solution with a molarity of 1.5M?

<p>2.44M (D)</p> Signup and view all the answers

How many moles of magnesium (Mg) are needed to react with 5.25 moles of hydrochloric acid (HCl)?

<p>2.625 moles (B)</p> Signup and view all the answers

What is the total volume of the resulting solution when mixing 150 mL of a 2M solution with 550 mL of a 3.5M solution?

<p>700 mL (A)</p> Signup and view all the answers

How many grams of Na2SO4 are produced when 500 mL of a 4.5M solution of H2SO4 is reacted with excess NaOH?

<p>110.5 g (D)</p> Signup and view all the answers

Given the molar masses of Na (22.989 g/mol) and Cl (35.457 g/mol), what is the total mass of NaCl produced from 0.17 moles?

<p>10.03 g (A)</p> Signup and view all the answers

What is the molarity of HCl if 1.5L of 3.5M solution provides how many moles of HCl?

<p>5.25 moles (C)</p> Signup and view all the answers

What stoichiometric relationship can be established from the reaction between Mg and HCl?

<p>1 mole of Mg reacts with 2 moles of HCl (A)</p> Signup and view all the answers

When diluting a solution, what would be the correct formula to calculate molarity after mixing different volumes?

<p>($M_1V_1$ + $M_2V_2$) / ($V_1 + V_2$) = $M_f$ (B)</p> Signup and view all the answers

Flashcards

Solubility

The maximum amount of a solute that can dissolve in a given amount of solvent at a specific temperature.

Dissolving ionic solids

Ionic compounds separate into their constituent ions when mixed with a polar solvent like water.

Solvation

A process where solute molecules are surrounded by solvent molecules.

Saturated solution

A solution where the maximum amount of solute has dissolved and the rate of dissolving equals the rate of crystallization.

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Solubility of solids

The solubility of solids usually increases with increasing temperature.

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Solubility of gases

The solubility of gases usually decreases with increasing temperature.

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Like dissolves like

Polar solvents dissolve polar solutes, and nonpolar solvents dissolve nonpolar solutes.

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Crystal Structure/Lattice

The repeating arrangement of ions in an ionic solid.

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Solubility of gases in liquids & Pressure

The solubility of a gas in a liquid is directly proportional to the pressure of the gas above the liquid (Henry's Law).

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Factors affecting dissolving rate

The rate at which a solute dissolves depends on surface area and the amount of solute already dissolved.

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Types of solutions

Solutions are homogeneous mixtures (uniform in composition) with a single phase. Mixtures can be heterogeneous where components are distinct.

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Colligative Properties

Properties of a solution that depend on the concentration of solute particles, not the type of solute.

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Vapor Pressure

The pressure exerted by molecules that have evaporated from a liquid's surface.

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Vapor Pressure Reduction

A solute lowers the vapor pressure of a solution because it interferes with vaporization.

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Boiling Point Elevation

Lower vapor pressure in solutions requires more heat to reach boiling point.

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Freezing Point Depression

Solute disrupts ice crystal formation in water, needing more cooling for freezing.

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Dissociation Equation

An equation showing how a chemical breaks down into ions when dissolved in water.

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Electrolyte

A substance that, when dissolved in water, produces ions that allow the solution to conduct electricity.

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Molarity (M)

A measure of concentration, expressed as moles of solute per liter of solution.

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Molarity Calculation

Molarity (M) = moles of solute / liters of solution

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Dilution

The process of reducing the concentration of a solution by adding more solvent.

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Mixing Solution Calculation, M1V1=M2V2

Formula to calculate the amount of a concentrated solution required to prepare a diluted solution: (Initial Molarity * Initial Volume) = (Final Molarity * Final Volume).

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Mole Calculation

Determining the amount of moles (or grams) of a substance in a solution given molarity and volume.

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Steps to find moles of solute from mass and concentration

Find moles using molarity equation, convert moles to grams using molar mass.

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Molarity of NaCl solution

Molarity is the concentration of a solution expressed as the number of moles of solute per liter of solution. It measures concentration in moles per liter (M).

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Calculate moles of NaCl

To determine the amount of a substance in moles, you divide the given mass by its molar mass. This will tell you how much solute (NaCl) is present in the solution.

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Calculate the total moles of final solution

Add the moles of solute from the original solution to the moles from the added solute.

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Calculate final molarity

Divide the total moles of solute by the total volume of the solution in liters.

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Reaction Stoichiometry

Reaction stoichiometry involves using the balanced chemical equation to determine the mole ratios between reactants and products.

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Moles of HCl calculation

Calculate the moles of HCl using the molarity and volume of HCl solution. Moles = molarity x volume (in liters)

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Convert Moles to Grams

Convert the calculated moles of Mg to grams using the molar mass of Mg.

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Calculate Moles from Balanced Equation

Determine the moles of a reactant or product using the balanced equation's stoichiometry. Use the mole ratios from balanced reaction.

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Dissociation

The separation of an ionic compound into its individual ions when dissolved in a polar solvent, like water.

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What happens to the solubility of a solid as temperature increases?

Generally, the solubility of a solid in a liquid increases as temperature increases.

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What happens to the solubility of a gas as temperature increases?

The solubility of a gas in a liquid decreases as temperature increases.

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What is the 'like dissolves like' rule?

Polar solvents dissolve polar solutes, and nonpolar solvents dissolve nonpolar solutes.

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Undersaturated solution

A solution that can still dissolve more solute at the given temperature.

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Supersaturated solution

A solution that contains more solute than it can normally hold at a given temperature, but crystallization has not yet occurred.

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Henry's Law

The solubility of a gas in a liquid is directly proportional to the partial pressure of the gas above the liquid.

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Surface Area & Dissolving

Increasing the surface area of a solid solute speeds up dissolving because it creates more contact points for solvent molecules.

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Solute Concentration & Dissolving

As more solute dissolves in a solvent, the rate of dissolving slows down.

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How many moles of solute are in a solution?

To calculate the moles of solute, multiply the molarity (M) of the solution by the volume of the solution in liters. Moles = Molarity x Volume.

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How many grams of solute are in a solution?

First, calculate the moles using the molarity and volume. Then, convert moles to grams using the molar mass of the solute.

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M1V1=M2V2

A formula used to calculate the volume of a concentrated solution needed to make a diluted solution. Initial Molarity times Initial Volume equals Final Molarity times Final Volume.

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Mixing Solutions

Combine two solutions to create a new solution with a different concentration. Requires calculation of the total moles and final volume to determine the new molarity.

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Molarity Formula

A formula used to relate concentration, moles, and volume: Molarity (M) = moles of solute / liters of solution

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Calculating Moles from Molarity

To find the moles of a solute in a solution, multiply the molarity by the volume of the solution in liters.

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Final Molarity

The molarity of the resulting solution after mixing is calculated by dividing the total moles of solute by the total volume of the solution.

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Balanced Chemical Equation

A chemical equation where the number of atoms of each element on the reactants' side equals the number of atoms of that element on the products' side.

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Calculating Moles from a Balanced Equation

Use the coefficients in a balanced equation to determine the mole ratio between reactants and products. This ratio helps calculate the moles of one substance from the known moles of another.

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Study Notes

Solubility Unit

  • Ionic compounds arrange themselves to increase attractive forces between ions and decrease repulsive forces. This arrangement is known as a crystal structure or lattice.
  • Polar solvent molecules surround each ion.
  • Separation of ions is called dissociation.
  • Solvation is when solute molecules are surrounded by solvent molecules.
  • Hydration is solvation when the solvent is water.
  • Covalent molecules are held together by weak intermolecular forces.
  • During solvation, each molecule is surrounded by solvent molecules.
  • Solvents do not appear in dissolving equations.
  • Ionic solids separate into ions (e.g., NH₄NO₃ → NH₄⁺(aq) + NO₃⁻(aq)).
  • Covalent solids just separate between molecules (e.g., C₆H₁₂O₆(s) → C₆H₁₂O₆(aq)).

Definitions

  • Undersaturated: A solution containing less than the maximum amount of solute that can be dissolved (dissolving > crystallization).
  • Saturated: A solution containing the maximum amount of solute that can be dissolved (dissolving = crystallization).
  • Supersaturated: A solution containing more than the maximum amount of solute under special conditions, but crystallization does not occur.

Factors Affecting Solubility

  • Nature of Solute and Solvent ("Like Dissolves Like"):
    • Substances with similar intermolecular forces dissolve each other more readily.
    • Polar substances dissolve polar substances, and nonpolar substances dissolve nonpolar substances.
  • Temperature:
    • Generally, the solubility of a solid or liquid solute increases with temperature. (e.g., sugar in hot tea vs. cold tea).
    • Solubility of gases decreases with increasing temperature.
    • Particles with more kinetic energy can escape the solution more quickly (e.g., cold pop vs. warm pop).
  • Pressure:
    • Only applies to solutions of gases in liquids.
    • Henry's Law: The solubility of a gas in a liquid is directly proportional to the pressure of the gas above the liquid.

Rate of Dissolving

  • Surface Area: Increasing surface area increases solute-solvent collisions, leading to faster dissolving (e.g., dissolving a cube of sugar vs. a teaspoon of sugar).
  • Amount of Solute Already Dissolved: As a solution approaches saturation, dissolving becomes slower.
  • Equilibrium: Dissolving and crystallization occur at the same rate in a saturated solution. This is called equilibrium.
  • Solubility: The maximum amount of a solute that can dissolve in a given amount of solvent at a specific temperature.

Colligative Properties

  • Colligative properties depend on the concentration of solute particles (number), not the type of solute.
  • Vapor Pressure Reduction: Solute particles interfere with evaporation, lowering the vapor pressure of a solution.
  • Boiling Point Elevation: Increased pressure requires a higher temperature for boiling.
  • Freezing Point Depression: Solute particles disrupt the formation of the solid phase, lowering the freezing point of a solution.

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Test your knowledge on the solubility unit, covering key concepts such as ionic and covalent solvation, dissociation, and hydration. This quiz will challenge your understanding of how different types of compounds interact with solvents and the definitions of supersaturated, saturated, and undersaturated solutions.

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