Properties and Changes in Chemistry
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Questions and Answers

Which of the following describes a chemical property?

  • The boiling point of a substance.
  • Whether a substance will react with another substance. (correct)
  • The mass of a substance.
  • The colour of a substance.
  • Which of these observations is considered qualitative?

  • The volume of gas produced was 50 mL
  • The solution turned a shade of blue. (correct)
  • The temperature of the water increased by 10 degrees Celsius.
  • The mass of the precipitate was 12 grams.
  • What is the correct name for the ionic compound $FeSe$?

  • Iron selenide
  • Iron(I) selenide
  • Iron monoselenide
  • Iron(II) selenide (correct)
  • What is the correct formula for the compound formed between Magnesium and the polyatomic ion hydroxide?

    <p>$Mg(OH)_2$</p> Signup and view all the answers

    What would the name of $H_3PO_4$ be, based on the naming rules for acids?

    <p>Phosphoric acid</p> Signup and view all the answers

    Which of the following is an example of a hydrate?

    <p>$CuSO_4 \cdot 5H_2O$</p> Signup and view all the answers

    In an atom, where is the majority of mass concentrated?

    <p>In the nucleus.</p> Signup and view all the answers

    Which of the following is an example of extensive physical property?

    <p>Volume</p> Signup and view all the answers

    What type of chemical reaction is represented by the general equation $A + BC \rightarrow AC + B$?

    <p>Single replacement</p> Signup and view all the answers

    In a balanced chemical equation, which numbers are adjusted to ensure the same number of atoms on both sides of the equation?

    <p>Coefficients</p> Signup and view all the answers

    In an exothermic reaction, how does the energy stored in the products compare to the energy stored in the reactants?

    <p>The energy in the products is less than the reactants.</p> Signup and view all the answers

    What is the enthalpy change ($\Delta H$) for an endothermic reaction?

    <p>Positive</p> Signup and view all the answers

    Which of the following must be converted to moles before conducting stoichiometric calculations?

    <p>All of the above</p> Signup and view all the answers

    Which term describes the reactant that is completely consumed during a chemical reaction?

    <p>Limiting reactant</p> Signup and view all the answers

    How is percent yield calculated in a chemical reaction?

    <p>Experimental yield / Theoretical yield * 100%</p> Signup and view all the answers

    If a solution has a pH of 5, how many times less acidic is it than a solution with a pH of 2?

    <p>1000</p> Signup and view all the answers

    If a reaction's percent yield is greater than 100%, what is a likely cause?

    <p>The final product was not completely dry</p> Signup and view all the answers

    What is a key difference between ionic and molecular solutions in water?

    <p>Ionic solutions break apart into ions, allowing them to conduct electricity and molecular solutions do not</p> Signup and view all the answers

    Which of the following is NOT a necessary piece of data to record during a titration?

    <p>The temperature of the reactants</p> Signup and view all the answers

    Which of the following describes a substance that does not dissolve easily in water, and may form a precipitate?

    <p>Low soluble compound</p> Signup and view all the answers

    When should a trial be rejected during a titration experiment?

    <p>If the difference between a trial is more than double the other difference.</p> Signup and view all the answers

    Which of the following is considered a polar solvent?

    <p>Water</p> Signup and view all the answers

    What is represented in a net ionic equation?

    <p>Only ions that undergo a reaction</p> Signup and view all the answers

    According to the Arrhenius theory, what ion do acids release in water?

    <p>Hydrogen ($H^+$) or Hydronium ($H_3O^+$)</p> Signup and view all the answers

    What type of substances dissolve best in non-polar solvents?

    <p>Non-polar substances</p> Signup and view all the answers

    Which of following is NOT a characteristic of a base from Arhenius theory?

    <p>Turns blue litmus paper red</p> Signup and view all the answers

    What is the primary focus of organic chemistry?

    <p>The study of carbon-based molecules</p> Signup and view all the answers

    What does a lower pH value indicate on the pH scale?

    <p>More acidic</p> Signup and view all the answers

    How many bonds can a carbon atom form?

    <p>4</p> Signup and view all the answers

    What suffix do all alkanes end with?

    <p>-ane</p> Signup and view all the answers

    What is the pH of a neutral solution at room temperature?

    <p>7</p> Signup and view all the answers

    If you had substituent groups containing a Bromine and a Chlorine, how would the names be written?

    <p>Bromo, then Chloro</p> Signup and view all the answers

    What are organic compounds with the same formula but different structures called?

    <p>Isomers</p> Signup and view all the answers

    Which best describes structural isomers?

    <p>Same chemical formula, different connections between atoms</p> Signup and view all the answers

    What is the primary goal of 'atom economy' in green chemistry?

    <p>To minimize waste by using as many atoms as possible in a reaction</p> Signup and view all the answers

    Which of the following is an example of 'design for energy efficiency' in green chemistry?

    <p>Using reactions at room temperature and neutral pressure.</p> Signup and view all the answers

    How does catalysis contribute to green chemistry?

    <p>By improving the efficiency and effectiveness of reactions</p> Signup and view all the answers

    Which of the following best describes the relationship between atomic number and the periodic table?

    <p>The periodic table is arranged by increasing atomic number.</p> Signup and view all the answers

    What does the principle of 'design for degradation' aim to achieve in green chemistry?

    <p>To make chemicals break down in the environment after use</p> Signup and view all the answers

    What is the mass of an atom with 15 protons, 16 neutrons, and 15 electrons?

    <p>31 amu</p> Signup and view all the answers

    What do isotopes of an element always have in common?

    <p>The same number of protons.</p> Signup and view all the answers

    Which of the following electron configurations is correct for a neutral vanadium (V) atom, which has 23 electrons?

    <p>1s² 2s² 2p⁶ 3s² 3p⁶ 4s² 3d³</p> Signup and view all the answers

    What is the correct electron configuration for the N³⁻ ion?

    <p>1s² 2s² 2p⁶</p> Signup and view all the answers

    Which subshells are considered to be the valence shell in most cases?

    <p>s and p orbitals</p> Signup and view all the answers

    According to the octet rule, most atoms are most stable when they have how many electrons in their valence shell?

    <p>8</p> Signup and view all the answers

    What type of bond is formed when electrons are shared equally between two atoms?

    <p>True Covalent Bond</p> Signup and view all the answers

    Which of these intermolecular forces is the strongest?

    <p>Hydrogen Bonding</p> Signup and view all the answers

    Which of the following is NOT a shape that can be associated with polar molecules?

    <p>Linear</p> Signup and view all the answers

    How does electronegativity difference affect the type of chemical bond formed?

    <p>Large electronegativity differences lead to ionic bonds.</p> Signup and view all the answers

    What causes London dispersion forces?

    <p>Fluctuations in electron density</p> Signup and view all the answers

    What is the correct electron configuration for Mn²⁺ ion?

    <p>[Ar] 4s⁰ 3d⁵</p> Signup and view all the answers

    Which of the following elements is an exception to the typical filling order of electron orbitals?

    <p>Chromium</p> Signup and view all the answers

    What is the formula for calculating the number of bonds an atom will form?

    <p>(# electrons wanted - #electrons present)/2</p> Signup and view all the answers

    Which of the following correctly describes the relationship between intermolecular forces and the state of a substance at a given temperature?

    <p>Stronger intermolecular forces favor the liquid or solid state.</p> Signup and view all the answers

    If a measurement is taken and the reading falls directly on a marked line on a ruler, how should it be recorded?

    <p>Record the value to the line and add a trailing '0'.</p> Signup and view all the answers

    A student performs a calculation involving measurements. The original measurements have 3 and 4 significant figures, respectively. According to significant figure rules, how many significant figures should the answer have IF the operation was multiplication?

    <p>3</p> Signup and view all the answers

    What is the correct scientific notation for 0.0006070?

    <p>$6.070 \times 10^{-4}$</p> Signup and view all the answers

    Which of the following is considered an intensive property?

    <p>Density</p> Signup and view all the answers

    In a graph examining the relationship between the mass and volume of a substance, what does the slope of the line of best fit represent?

    <p>The density of the substance.</p> Signup and view all the answers

    How many molecules are present in 2.5 moles of a substance?

    <p>$1.505 \times 10^{24}$ molecules</p> Signup and view all the answers

    How many atoms of oxygen are present in 0.25 moles of $O_2$?

    <p>$0.50 \times 6.02 \times 10^{23}$ atoms</p> Signup and view all the answers

    What is the molar mass of $H_2SO_4$?

    <p>98 g/mol</p> Signup and view all the answers

    What volume does 2 moles of an ideal gas occupy at STP?

    <p>44.8 L</p> Signup and view all the answers

    How many moles of $CH_2O$ are present in 60g of $CH_2O$? (Molar mass of $CH_2O = 30 g/mol$)

    <p>2 mol</p> Signup and view all the answers

    What is the mass of 0.5 moles of NaCl? (Molar mass of NaCl = 58.5 g/mol)

    <p>29.25 g</p> Signup and view all the answers

    What is the concentration, in molarity, of a solution containing 0.5 moles of solute in 500 mL of solution?

    <p>1.0 M</p> Signup and view all the answers

    Which of the following is an example of a synthesis reaction?

    <p>$H_2 + Cl_2 \rightarrow 2HCl$</p> Signup and view all the answers

    Which one of these is a base unit in the metric system?

    <p>grams</p> Signup and view all the answers

    Study Notes

    Properties, Changes, and Observations

    • Physical change: A change in form or shape, but not chemical makeup.
    • Chemical change: A change where a new substance or molecule forms. Indicators include color change, bubble formation, temperature change, combustion.
    • Physical property: A feature describing how a substance exists at a given temperature (e.g., color, texture).
    • Chemical property: A feature describing how a substance reacts (e.g., flammability, reactivity with acids).
    • Intensive property: A property that remains consistent regardless of the amount of substance.
    • Extensive property: A property that changes with the amount of substance.
    • Observation: The basis of science; noting and recording what is seen, heard, smelled, felt, or tasted. Focus on what happens, not why.
    • Qualitative observation: Descriptive (color, feel, size).
    • Quantitative observation: Based on numbers.

    Naming and Formulas for Ionic Compounds

    • Ionic compound formulas: Determine charges of ions, then balance the charges. Example: Li₂O, FeSe, Mg(OH)₂
    • Ionic compound names: Name the cation first, indicate oxidation state if multivalent, then name the anion. If the anion is a polyatomic ion, do not change the ending. If the anion is a single element, change the ending to "-ide."

    Acids

    • Acids: Compounds releasing hydrogen ions (H⁺) in solution (aqueous state).
    • Acid formulas: Often start with "H" or end in "COOH."
    • Acid naming (no oxygen): Hydro- + root name + -ic acid (e.g., H₂S – hydrosulfuric acid)
    • Acid naming (with oxygens): Root name of polyatomic ion, "-ate" ending becomes "-ic acid," "-ite" ending becomes "-ous acid" (e.g., H₂SO₄ – sulfuric acid, H₂SO₃ – sulfurous acid).

    Hydrates

    • Hydrates: Compounds trapping water in their crystal structure (e.g., NiCl₂ • 2H₂O – Nickel(II) chloride dihydrate).

    Atoms

    • Atom: Tiny piece of matter, comprising a nucleus and electron cloud.
    • Nucleus: Dense center containing protons and neutrons.
    • Proton: Particle with +1 charge and 1 amu mass, determining the element.
    • Neutron: Particle with neutral charge and 1 amu mass.
    • Electron cloud: Space where electrons are found, virtually no mass, -1 charge.
    • Atomic number: Number of protons.
    • Atomic mass/mass number: Number of protons + neutrons (whole number).
    • Neutral atom: Protons = electrons.
    • Ion: Charged particle, electron loss or gain.
    • Isotope: Atoms of same element, different number of neutrons.
    • Atomic Orbital: Spaces around an atom where electrons are likely to be found.

    Electron Configurations

    • Electron configurations: Electrons fill orbitals from lowest to highest energy levels.
    • Degenerate orbitals: Orbitals with the same energy.
    • Shell Filling Order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p ...
    • Electron configuration notation: Shows which subshells contain electrons (e.g., Carbon: 1s²2s²2p²).
    • Core notation: Using noble gas symbol to represent inner electrons (e.g., Manganese: [Ar] 4s²3d⁵).

    Ions

    • Valence electrons are removed/added first, then s electrons, then d electrons for positive ions.
    • Negative ions add electrons. This changes their electron configuration.

    Bonds

    • Covalent bonds: Electrons shared between atoms.
    • Polar covalent bonds: Unequal sharing of electrons due to electronegativity differences.
    • Ionic bonds: Complete transfer of electrons.
    • Electronegativity: Ability to attract electrons.

    Molecular Forces

    • Intermolecular forces: Forces holding molecules together in liquids and solids.
    • Dipole-dipole forces: Attraction between polar molecules.
    • Hydrogen bonding: Special dipole-dipole force in molecules with H-O, H-N, or H-F bonds.
    • London dispersion forces: Temporary dipoles in all molecules due to electron cloud fluctuations.

    Measurement and Significant Figures

    • Measurement Uncertainty: All measurements have some degree of uncertainty; estimate the last digit reported.
    • Significant Figures: Indicate how well a number is known. Rules for determining significant figures

    Moles

    • Mole: Unit for counting atoms/molecules (Avogadro's number = 6.02 x 10²³).
    • Molar mass: Mass of 1 mole of a substance, found on the periodic table.
    • Molar mass conversion: Use for converting between moles and grams.
    • Molar volume (STP): 22.4 L/mol for any gas at standard temperature and pressure (STP).

    Solution Concentration

    • Concentration: Amount of solute per unit volume (e.g., molarity = moles/liter).
    • Dilution: Changing the concentration of a solution by adding more solvent.

    Chemical Reactions

    • Chemical Reactions: Breaking and forming of bonds, changing chemical potential energy.
    • Reaction Types: Synthesis, decomposition, single replacement, double replacement, neutralization, combustion.
    • Chemical Equations: Balancing equations to maintain atom conservation.
    • Exothermic reaction: Energy released as a product (enthalpy is Negative).
    • Endothermic reaction: Energy absorbed as a reactant (enthalpy is Positive).
    • Stoichiometry: Using balanced equations to calculate reactant/product ratios.
    • Limiting Reactant: Reactant used up first, controls product yield.
    • Percent Yield: Comparing actual yield to theoretical yield.

    Solution Properties

    • Aqueous Solutions: Substances dissolved in water.
    • Ionic Solutions: Dissolve into separate ions and conduct electricity.
    • Molecular Solutions: Do not form ions, do not conduct electricity easily.
    • Solubility: Ability of a substance to dissolve in a solvent.
    • Precipitate: Insoluble solid formed in a reaction of different aqueous solutions.

    pH and Titration

    • pH Scale: Logarithmic scale measuring acidity (0-14). Lower pH means more acidic.
    • Titration: Analytical technique to precisely determine the concentration of a solution.

    Organic Chemistry

    • Organic Chemistry: Study of carbon-based molecules.
    • Alkanes: Carbon chains with single bonds.
    • Substituent groups: Groups attached to the main carbon chain.
    • Isomers: Molecules with the same formula, different structures. (structural, geometric, optical isomers)
    • Alkenes: Carbon chains with at least one double bond.

    Green Chemistry Principles

    • Waste Prevention: Minimize waste generation.
    • Atom Economy: Maximize use of atoms in the reaction.
    • Less Hazardous Chemical Synthesis: Use less hazardous reagents.
    • Safer Chemicals Design: Design less toxic chemicals.
    • Safe Solvents and Auxiliaries: Use less hazardous solvents.
    • Energy Efficiency: Minimize energy consumption.

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