Organic Chemistry II: Liquid-Liquid Extraction
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Questions and Answers

Liquid-liquid extraction is also known as ______ extraction

solvent

Solutes are separated based on their different solubilities in different ______

liquids

The process of liquid-liquid extraction is suitable for thermally ______ and high-boiling compounds

labile

An organic ______ is added to the aqueous solution containing solutes in liquid-liquid extraction

<p>solvent</p> Signup and view all the answers

Compound A is soluble in ______ and insoluble in water

<p>ether</p> Signup and view all the answers

Study Notes

Liquid-Liquid Extraction

  • Liquid-liquid extraction, also known as solvent extraction, is a separation process that involves the transfer of a solute from one solvent to another, with the two solvents being immiscible.

Separation Principle

  • Separation is based on the different solubilities of solutes in different liquids.
  • The original solution is transferred to another liquid solution, separating the substances that constitute the original solution.

Advantages

  • Simple process
  • Low cost
  • Suitable for thermally labile and high-boiling compounds

Disadvantages

  • Time-consuming process
  • Tedious
  • Environmental concerns

Liquid-Liquid Extraction Steps

  • Add an organic solvent to an aqueous solution containing solutes, forming two immiscible layers.
  • Mix the layers by moderately shaking, then stop the process for a few minutes to allow the layers to separate.
  • Separate the layers.

Separation Using a Separation Funnel

  • Can be used to separate immiscible liquids.

Example: Separation of Organic Compound A and Inorganic Salt B

  • Compound A is soluble in ether and insoluble in water.
  • Compound B is soluble in water and insoluble in ether.
  • Steps for separation:
    • Add ether to the mixture containing A and B, forming two immiscible layers.
    • Mix the layers, then stop the process to allow separation.
    • Separate the ether layer containing A from the water layer containing B.

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Description

This quiz covers the concept of liquid-liquid extraction, a separation process that transfers solutes from one solvent to another. It involves the transfer of solutes based on their different solubilities in different liquids.

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