Minerals in Porphyry Copper Deposits
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Minerals in Porphyry Copper Deposits

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What are the main minerals found in porphyry copper deposits?

  • Chalcopyrite and Bornite (correct)
  • Pyrite and Arsenopyrite
  • Galena and Sphalerite
  • Hematite and Magnetite
  • What is a characteristic feature of hydrothermal ore deposits that form due to magmatic activity?

  • They require the presence of a magma close to volcanic activity. (correct)
  • They contain only metallic minerals with no by-products.
  • They are always found far from volcanic activity.
  • They are formed exclusively at high grades.
  • Which of the following types of hydrothermal deposits lacks widespread or temporally related magmatic activity?

  • Deposits that develop independently of magmatic influence (correct)
  • Deposits associated with current volcanic activity
  • Deposits forming during regional magmatism
  • Deposits clustered near magmatic centers
  • What percentage of the world's copper is sourced from porphyry copper deposits?

    <p>70%</p> Signup and view all the answers

    Which process causes metals to crystallize from hydrothermal magmatic fluids?

    <p>Exsolution of volatiles and subsequent changes in the hydrothermal system</p> Signup and view all the answers

    What is the primary reason for the explosive activity at the surface of a kimberlite magma eruption?

    <p>The high volatile content of the magma.</p> Signup and view all the answers

    Which of the following best describes where diamonds are found in relation to the kimberlite magma?

    <p>Only within the diatreme.</p> Signup and view all the answers

    What structure serves as the primary channel for kimberlite melts to reach the surface?

    <p>A diatreme.</p> Signup and view all the answers

    How does the local geology affect the emplacement of a kimberlite diatreme?

    <p>It emplaces discordantly and vertically.</p> Signup and view all the answers

    What is the minimum depth at which kimberlite melts originate from mantle partial melting?

    <p>Greater than 150 km.</p> Signup and view all the answers

    What is a key characteristic of the fluids involved in hydrothermal mineral deposition?

    <p>They must be undersaturated in specific elements.</p> Signup and view all the answers

    What temperature must kimberlite magma typically exceed for significant geological activity?

    <blockquote> <p>900°C</p> </blockquote> Signup and view all the answers

    What secondary effect occurs when hot kimberlite magma interacts with groundwaters?

    <p>Water flashes to steam, causing explosive eruptions.</p> Signup and view all the answers

    What is the primary reason why most volatile components in magma do not become part of crystallizing minerals?

    <p>They accumulate in the residual melt during fractional crystallization.</p> Signup and view all the answers

    Which elements are concentrated in escaping magmatic-hydrothermal fluids?

    <p>Elements that are incompatible in crystallizing phases and highly soluble in brines.</p> Signup and view all the answers

    What factor does NOT influence the concentration of trace ore metals in an exsolved fluid from felsic magma?

    <p>Amount of sunlight exposure during crystallization.</p> Signup and view all the answers

    How does pressure affect the solubility of volatiles in a melt?

    <p>Solubility of volatiles decreases with a decrease in pressure.</p> Signup and view all the answers

    What is First Boiling in the context of magmatic processes?

    <p>Exsolution occurring due to decompression as the magma rises.</p> Signup and view all the answers

    What happens during Second Boiling in magmatic activity?

    <p>Exsolution occurs due to increased concentration of volatile elements in the melt.</p> Signup and view all the answers

    What is a hydrothermal magmatic brine?

    <p>A separate, immiscible fluid phase from exsolved volatile components.</p> Signup and view all the answers

    What role does fractional crystallization play in magmatic ore deposit formation?

    <p>It results in volatile accumulation in the residual melt.</p> Signup and view all the answers

    Which factor is least likely to affect the migration of magmatic-hydrothermal fluids into country rock?

    <p>Rate of cooling of the surrounding environment.</p> Signup and view all the answers

    What is NOT true about the concentration of metals during the process of exsolution?

    <p>The depth of exsolution does not affect metal concentration.</p> Signup and view all the answers

    What is a key factor that can lead to the dropping of metals from hydrothermal fluids?

    <p>Increase in temperature</p> Signup and view all the answers

    Which of the following scenarios could lead to hydrothermal alteration?

    <p>Fluid penetrating mineral-rich areas</p> Signup and view all the answers

    Which type of hydrothermal ore deposit forms closely associated with magmatic activity?

    <p>Porphyry deposits</p> Signup and view all the answers

    What does 'hydrothermal alteration' typically signify in geological processes?

    <p>Dissolution of minerals by hydrothermal fluids</p> Signup and view all the answers

    Which component is NOT part of a hydrothermal system's summary?

    <p>Mineral crystallization</p> Signup and view all the answers

    In which areas are mafic magmatism typically found?

    <p>Shallow oceanic crust</p> Signup and view all the answers

    Which of the following types of deposits lack widespread magmatic activity?

    <p>Deposits without temporal magmatic relation</p> Signup and view all the answers

    What is a primary mechanism leading to metal remobilization in hydrothermal systems?

    <p>Chemical alteration due to fluid interaction</p> Signup and view all the answers

    Which change would likely NOT affect the equilibrium conditions of hydrothermal fluids?

    <p>Introduction of external geological formations</p> Signup and view all the answers

    Which of the following factors is crucial for the transport of metals in hydrothermal systems?

    <p>Presence of ligands in the fluid</p> Signup and view all the answers

    What is the primary process by which ore elements concentrate in magmatic systems?

    <p>Accumulation in magma chambers</p> Signup and view all the answers

    Which of the following accurately describes kimberlites?

    <p>Low density and alkaline, volatile-rich ultramafic rocks</p> Signup and view all the answers

    Which mineral is predominantly found in kimberlite?

    <p>Olivine</p> Signup and view all the answers

    What characterizes the texture of kimberlite in hand specimens?

    <p>Inequigranular with fragmented minerals in a fine-grained ground mass</p> Signup and view all the answers

    What results from the alteration of olivine in kimberlite upon reaching the Earth's surface?

    <p>Liberation of diamonds</p> Signup and view all the answers

    What is one of the main features of primary magmatic diamond deposits in kimberlites?

    <p>Diamonds are brought to the Earth's surface by kimberlite melts</p> Signup and view all the answers

    Which process does not contribute to the formation of ore deposits in magmatic systems?

    <p>Sedimentation of mineral-rich water</p> Signup and view all the answers

    What type of magma forms from larger degrees of partial melting of mantle peridotite?

    <p>Basaltic magma</p> Signup and view all the answers

    Which mineral is often found altered in kimberlite to form serpentine?

    <p>Olivine</p> Signup and view all the answers

    What does the term 'serpentinisation' refer to in kimberlite geology?

    <p>The transformation of olivine to serpentine</p> Signup and view all the answers

    Study Notes

    Ore Deposit Formation in Magmatic Systems

    • Five processes for ore formation in magmatic systems are identified:
      • Concentration of ore elements due to low degrees of partial melting.
      • Accumulation and concentration of ore minerals in magma chambers during progressive crystallization and fractionation of mafic and ultramafic magmas (e.g., chromitite deposits).
      • Separation of immiscible melts in a magma chamber (e.g., Ni-Cu-PGE sulfide deposits).
      • Extreme fractionation during progressive crystallization of a magma
      • Incorporation of a mineral that occurs at a specific depth in the Earth into an ultramafic melt (e.g., primary magmatic diamond deposits in kimberlites).

    Kimberlites

    • Kimberlites are alkaline, volatile-rich potassic, low-density ultramafic rocks.
    • They form from small degrees of partial melts of carbonate-bearing and hydrous mantle peridotite.
    • Larger degrees of partial melting would result in a basaltic magma.
    • They are important because they can host diamonds.
    • Kimberlites have an inequigranular texture with fragmented minerals and clasts in a fine-grained groundmass.
    • Main minerals in kimberlites include olivine (often altered to serpentine), diopside, pyrope garnet, enstatite, ilmenite, and chromite.
    • Alteration of olivine to serpentine promotes diamond liberation from the kimberlite host rock.
    • Diamonds are accidental passengers in kimberlite melts, meaning they do not form during kimberlite melt crystallization.
    • Historically, diamonds were mined from secondary alluvial deposits, such as river environments before kimberlites were discovered.
    • Primary magmatic diamond deposits are mainly found in Precambrian terranes/cratons, particularly within the Archean.
    • Major diamond-producing countries include Russia, Canada, Botswana, Angola, and South Africa.

    Diamond Production

    • Estimated diamond production in 2021, by country, is presented in a pie chart.
    • Additional data on diamond production for specific countries (e.g., Botswana, Russia, Australia, South Africa, Canada) are available for additional years (e.g., 2008, 2009). Note that values are in the thousands of carats, a unit used for precious stone weight.

    Kimberlite Plumbing System

    • Kimberlite melts originate from a substantial depth (>150 km).
    • They reach the surface as volcanic eruptions via diatremes (volcanic pipes).
    • They can also occur as diatremes, pipes, dykes, and sills, and less commonly as volcanic tuffs.
    • Diatremes form to ~1 km depth from the root system.
    • The high volatile content in the magma at ~1 km depth results in eruptive "blowout"
    • Interaction of hot kimberlite magma (>900°C) with groundwater triggers explosive activity, forming crater facies at the surface
    • Diamonds are transported upward by the melt.
    • The kimberlite (including diamond) is only within the diatreme, not in the surrounding rocks.
    • Emplacement is discordant with the local geology, typically as a vertical pipe, dyke, or sill.

    Morphology of Kimberlite Bodies/Pipes

    • World-wide kimberlite bodies and pipes are typically small (<1000 m diameter) and characterized as diatremes.
    • They consist of volcanic pipes filled with broken volcanic fragments (volcanic breccia).
    • They are divided into 2 parts:
      • Volcaniclastic kimberlite, or fragmental rocks
      • Hypabyssal kimberlite, or non-fragmental rocks

    Kimberlite Eruption

    • Kimberlites have magmatic plumbing systems at depth, which can be cylindrical (pipe), planar vertical (dyke), or planar horizontal (sill).
    • The high volatile content in the magma at shallow levels causes an eruptive "blowout" leading to a volcanic crater.
    • Fluid eruption is driven by the interaction of the magma with surface water.
    • Many kimberlite complexes display multiple eruption stages that have evolved over millions of years.
    • Kimberlites often appear in clusters

    Global Distribution of Primary Magmatic Diamond Deposits

    • Deposits are concentrated in Archean crustal blocks of Precambrian terranes/cratons.
    • Specific locations are mapped on a global distribution diagram.

    Two Types of Kimberlites

    •  Group 1 kimberlites are widespread, dominated by olivine, and intruded 80-90 million years ago. They have low percentages of matrix calcite, apatite, and diopside.

    • Group 2 (orangites) kimberlites are restricted to southern Africa, characterized by megacrysts of phlogopite (mica) with lesser olivine and mica-olivine groundmass. They have high percentages of matrix calcite, apatite and diopside and intruded 120 to 200 Ma

    Different Types of Kimberlite Pipes

    • Volcaniclastic kimberlite (VK), characterized by fragmental rocks
    • Hypabyssal kimberlite (HK), characterized by non-fragmental rocks

    Pegmatites

    • Pegmatites are felsic igneous rocks with very coarse-grained crystals.
    • Crystals form from a felsic melt during the late stages of fractional crystallization when the melt is rich in incompatible elements and volatiles.
    • Main minerals in pegmatites are quartz, K-feldspar, micas (biotite and muscovite), and rare minerals rich in lithophile elements and/or volatiles (e.g. beryl, tourmaline, apatite, Li-minerals).
    • Pegmatites are enriched in lithophile, incompatible elements and volatiles from granite crystallization.
    • They can be mined for industrial minerals (quartz, feldspar), minor metals (e.g. Be, Ta, Nb, Sn-W, Cs, Li), and uranium.

    Economic Rare-Element Pegmatites

    • Economic rare-element pegmatites are subdivided into two groups depending on the presence of rare metals - LCT (Li, Cs, Ta) types and NYF (Nb, Y, F) types.
    • The dominant process for concentration of elements of interest in pegmatites is the last stages of fractional crystallisation.
    • Pegmatites are some of the most fractionated felsic igneous rocks.
    • The source of rare metals in pegmatites is from pre-existing continental crust.

    Granites and Volatiles

    • Most granitic melts are hydrous (3-6 wt% H20 and >1000 ppm CO2).
    • When a granitic melt ascends toward the surface and cools down, rock-forming minerals crystallize.
    • The solubility of H₂O in silicate melt decreases with decreasing pressure, and the residual felsic melt becomes progressively more hydrated and enriched in incompatible elements and volatiles.
    • Compatible and non-volatile elements enter the common rock-forming silicates during crystallisation.
    • Non-volatile elements concentrate in the residual melt.
    • Incompatible volatile elements concentrate, and this leads to extreme concentrations of incompatible elements (e.g. Cs, Li, Nb, Ta) and volatiles in residual felsic melts.
    • During crystallisation the volatiles and H₂O concentrate into a magmatic fluid phase (liquid or vapour). These magmatic fluids will be important for the formation of hydrothermal ore deposits.

    Rare Metal Enrichment by Fractionation of a Felsic Melt

    • Residual felsic melt becomes progressively more saturated in H20 and enriched with incompatible elements and volatiles.
    • The aqueous residual felsic melt leaves the granite intrusion and migrates into the country rock.
    • Mineral crystallisation occurs as the melt cools, continuously richer in incompatible elements and volatiles.
    • Zoning occurs in crystallisation moving outward from the original granitic intrusion.

    Pegmatites & Rare Metals Genetic Model

    • The source of rare metals in pegmatites is pre-existing continental crust.
    • Metals are transported to the surface in dissolved incompatible lithophile elements in granitic magmas
    • Extreme fractional crystallisation leads to extreme enrichment in incompatible (Ta-Nb-Li-Cs) and volatile elements (H-Cl-F-B-P).
    • The trap is the pegmatite body where crystals have unusual chemistry and size.
    • Crystallisation of minerals proceeds by progressive enrichment with increasing distance from the source.

    Hydrothermal Ore Deposits

    • Hydrothermal ore deposits result from the transport of metals in hydrothermal fluids (aqueous fluids).
    • Fluids can originate from depth or the Earth's surface.
    • Some important fluids sources are diagenetic, metamorphic and magmatic fluids, meteoric water and connate water.
    • The dissolving and transport of elements is often facilitated by ligands.
    • Solubility of metals is greater in fluids with ligands.
    • Fluids need to be undersaturated in a certain element to allow the dissolution or leaching of metals from rocks. The fluid needs to become oversaturated of a certain element to induce the precipitation of metals.
    • The fluids, metal concentration and the geochemical conditions of the fluid drive the processes of mineral precipitation.

    Important hydrothermal mineral deposits

    • The physical and chemical characteristics control the formation of these fluids.

    • Various types of hydrothermal systems.

    • Three main types of hydrothermal ore deposits:

      • Deposits closely associated with magmatic activity
      • Deposits formed during periods of regional magmatism and tectonism, but not clustered near magmatic centers
      • Deposits lacking widespread or temporally related magmatic activity
    • Main requirements for the formation of hydrothermal ore deposits.

    • Source for the ore components

    • Process for transporting the elements to the ore deposits site and allowing appropriate concentrations

    • Depositional mechanism to fix the elements in the ore body as ore minerals and associated gangue - geological process, which preserves the ore

    Alteration

    • Hydrothermal fluids cause mineralogical, chemical, and textural changes in the country rocks, often referred to as alteration.
    • The alteration often extends over a large area compared to the ore body.
    • Temperature, pressure, fluid composition, permeability of the host rocks, host-rock composition, fluid/rock ratio control the alteration.
    • The alteration is often mineralogically and chemically zoned, and recognising the zoning patterns can be important for exploration.

    Veins, Breccias and Alteration

    • Vein formation is associated with mineral deposition in fractures.
    • Veining can involve a single or multiple generations.
    • Breccias form from fragmentation of rock due to a pressure or collapse gradient.
    • Alteration involves mineralogical and chemical changes induced in the host rock from hydrothermal fluids.

    Classification of Epithermal Deposits

    • High-sulfidation (HS): characterised by oxidized sulfur species (SO2, SO42−, HSO4−) and magmatic fluids.

    • Low-sulfidation (LS): characterized by reduced sulfur species (HS−, H2S) and meteoric fluids.


    Types of Ore Deposits

    • Porphyry Copper: large-tonnage low-grade copper deposits associated with felsic intrusions, often related to subduction zones.
    • Epithermal Gold: shallow-level gold deposits commonly found in island arcs and continental arcs, associated with hydrothermal fluid flow from volcanic systems.

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    This quiz explores the essential characteristics and mineral composition of porphyry copper deposits, as well as the processes involved in their formation. Test your knowledge on hydrothermal ore deposits and their relation to magmatic activity. Ideal for geology students and enthusiasts!

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