Material Properties and Spectroscopy Quiz
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Questions and Answers

What property of a material is directly related to its effectiveness as a lens?

  • Thermal conductivity
  • Density
  • Refractive index (correct)
  • Transparency
  • Lead crystal is considered useful for lenses because it has a low refractive index.

    False

    What is the term for a material's ability to transmit light without absorbing or scattering it?

    Transparency

    A material that is free of internal interfaces and compositional differences is likely to be __________.

    <p>homogeneous</p> Signup and view all the answers

    Match the following properties with their definitions:

    <p>Refractive index = A measure of how much light bends when entering a material Direct piezoelectric effect = Electric polarization due to mechanical strain Reverse piezoelectric effect = Mechanical strain induced by an electric field Electrochemical properties = Behaviors of materials in corrosive environments</p> Signup and view all the answers

    Which type of bonding should be minimized to enhance transparency in materials?

    <p>Metallic bonds</p> Signup and view all the answers

    Piezoelectric materials can generate electrical charge when mechanically strained.

    <p>True</p> Signup and view all the answers

    What happens to a solid in the reverse piezoelectric effect?

    <p>It becomes strained when placed in an electric field.</p> Signup and view all the answers

    What type of analysis does Fourier Transform Infrared Spectroscopy (FTIR) primarily provide?

    <p>Vibrational analysis of chemical processes</p> Signup and view all the answers

    Scanning Electron Microscopy (SEM) can accurately analyze the surface chemistry of non-conductive materials without any modifications.

    <p>False</p> Signup and view all the answers

    What is a traditional shortcoming of Secondary Ion Mass Spectrometry (SIMS)?

    <p>Inability to perform quantitative analysis</p> Signup and view all the answers

    During SEM analysis, the intensity of secondary electron emission depends on the atomic composition of the sample and the __________ of the features under observation.

    <p>geometry</p> Signup and view all the answers

    How are molecular vibrations related to FTIR spectra?

    <p>They can directly relate to the symmetry of molecules.</p> Signup and view all the answers

    Match the following techniques with their primary function:

    <p>SIMS = Chemical composition analysis FTIR = Vibrational spectroscopy SEM = Surface imaging Quantitative analysis = Measurements of concentrations</p> Signup and view all the answers

    FTIR spectroscopy is not suitable for quantitative analysis.

    <p>False</p> Signup and view all the answers

    What is used to minimize negative charge accumulation in SEM analysis of non-conductive materials?

    <p>A thin, electrically grounded layer of metal</p> Signup and view all the answers

    Which of the following deformation modes are used in DMA for polymer measurements?

    <p>All of the above</p> Signup and view all the answers

    The loss tangent tanδ represents the ratio of loss modulus to storage modulus.

    <p>True</p> Signup and view all the answers

    What is the storage modulus (E') associated with?

    <p>Purely elastic component</p> Signup and view all the answers

    The tensile strength of CoCr Alloy is approximately _____ MPa.

    <p>735</p> Signup and view all the answers

    Match the following treatments with their strain at break:

    <p>DW Overnight = 0.37 Genipin = 0.55 EDC-NHS = 0.53 GTA = 0.55</p> Signup and view all the answers

    Which of the following materials has the highest elastic modulus?

    <p>Al2O3</p> Signup and view all the answers

    The wet treatment of reconstituted collagen fibers generally shows higher strain at break compared to the dry treatment.

    <p>False</p> Signup and view all the answers

    What property do the thermal properties dictate regarding materials?

    <p>Processing conditions</p> Signup and view all the answers

    The loss modulus (E'') is associated with the _____ component.

    <p>purely viscous</p> Signup and view all the answers

    Which treatment of reconstituted collagen fibers resulted in a strain at break of 0.40?

    <p>Genipin Wet</p> Signup and view all the answers

    Which method is most commonly used for measuring contact angles?

    <p>Static or Sessile Drop Method</p> Signup and view all the answers

    The receding contact angle can be obtained by adding fluid droplets onto the surface.

    <p>False</p> Signup and view all the answers

    What is the purpose of the Wilhelmy plate method?

    <p>To test double-sided samples in temperature-controlled conditions.</p> Signup and view all the answers

    The __________ method is specifically useful for measuring contact angles of tubular materials.

    <p>Capillary Rise</p> Signup and view all the answers

    In the static or sessile drop method, a plateau in contact angle indicates what?

    <p>The advancing contact angle is constant.</p> Signup and view all the answers

    Match the contact angle measurement methods with their specific applications:

    <p>Sessile or Static Drop Method = General measurement of contact angle Wilhelmy Plate Method = Double-sided samples under controlled temperature Captive Air Bubble Method = Contact angles with an air bubble in a bath Capillary Rise Method = Measurement of tubular materials</p> Signup and view all the answers

    Temperature sensitivity of a surface does not affect the use of contact angle methods.

    <p>False</p> Signup and view all the answers

    What measurement follows the advancing contact angle experiment?

    <p>Receding contact angle measurement.</p> Signup and view all the answers

    What is one of the primary medical uses of non-fouling surfaces (NFSs)?

    <p>Blood-compatible materials</p> Signup and view all the answers

    NFSs can be used to enhance the foreign-body reaction in implanted devices.

    <p>False</p> Signup and view all the answers

    Name one application of NFSs in non-medical uses.

    <p>Biofouling-resistant heat exchangers or ship hulls</p> Signup and view all the answers

    NFSs can minimize nonspecific protein adsorption and maximize __________ binding.

    <p>specific</p> Signup and view all the answers

    Which of the following surfaces is used as an anchor group for self-assembled monolayers?

    <p>Thiol</p> Signup and view all the answers

    Match the following applications with their function:

    <p>Biosensors = Specific binding maximization Implanted devices = Reduction of foreign-body reaction Urinary catheters = Blood compatibility Affinity separation processes = Non-fouling properties</p> Signup and view all the answers

    NFSs are effective in reducing the nonspecific adsorption of proteins.

    <p>True</p> Signup and view all the answers

    What characteristic of NFSs helps in simplifying device removal?

    <p>Reduction of foreign-body reaction</p> Signup and view all the answers

    Which mechanotransduction pathway is involved in cell responses to substrate elasticity?

    <p>FAK pathway</p> Signup and view all the answers

    Cells respond to substrate stiffness through activation of ROCK signaling pathways.

    <p>True</p> Signup and view all the answers

    What does the term 'P' represent in the figure symbols?

    <p>Planar</p> Signup and view all the answers

    Non-fouling surfaces are also known as __________ surfaces.

    <p>protein-resistant</p> Signup and view all the answers

    What was the lowest PDMS substrate stiffness measured in the examples?

    <p>50 kPa</p> Signup and view all the answers

    Cells can sense matrix elasticity at a molecular scale level.

    <p>True</p> Signup and view all the answers

    Name one cellular function that is controlled by mechanotransduction signaling pathways.

    <p>Adhesion</p> Signup and view all the answers

    The ________ kPa substrate stiffness corresponds to the samples with collagen type I coating.

    <p>1000</p> Signup and view all the answers

    Match the following collagen coating conditions with their respective surface roughness:

    <p>P - Col = 2.1 µm G - Col = 94 nm P + Col = 2.5 µm G + Col = 78 nm</p> Signup and view all the answers

    What role do non-fouling surfaces serve in biomaterials?

    <p>Resist protein and cell adhesion</p> Signup and view all the answers

    The roughness of a surface can affect cellular functions such as migration.

    <p>True</p> Signup and view all the answers

    What is the primary purpose of scanning probe microscopy modes in biomaterials?

    <p>Surface characterization</p> Signup and view all the answers

    Cells sense substrate elasticity through __________.

    <p>mechanotransduction</p> Signup and view all the answers

    Which cellular function is not controlled by mechanotransduction signaling pathways?

    <p>Respiration</p> Signup and view all the answers

    Study Notes

    Bulk & Surface Properties of Biomaterials

    • Biomaterials are substances used in medical implants
    • Surface properties are critical for cell interaction, affecting initial response to implantation
    • Bulk properties are important for long-term performance, such as mechanical properties during implantation
    • Surface properties, such as roughness, wettability, and chemical composition, affect the interaction with cells, tissues, biofluids. Key factors include how cells interact, how foreign matter triggers a response, and how surfaces readily contaminate leading to implant failure
    • Bulk properties, including mechanical properties, thermal properties, and electrochemical properties, are essential for long-term implant performance
    • Specific mechanical loading situations (e.g., tensile, compression, shear, torsion, bending/flexure) are used to evaluate material behavior under different conditions and to determine parameters like tensile strength, stress at break, modulus, and strain
    • Dynamic Mechanical Analysis (DMA) is used to measure viscoelastic properties, such as storage modulus, loss modulus, and loss tangent, related to the temperature dependency
    • Thermal gravimetric analysis(TGA) measures changes in mass during heating, evaluating transition behavior
    • Differential scanning calorimetry (DSC) measures thermal transitions, identifying onset and peak temperatures during denaturation, important for estimating the temperature at which a polymer melts
    • Wet state DSC is recommended for biomaterials for better in vivo reflection
    • Surface properties such as wettability (measured via contact angle), and how deep the surface is are key
    • Important methods for surface characterization include contact angles, XPS, Auger analysis, SIMS, FTIR-ATR, STM, SEM
    • Multiple methods are available to examine surface properties and to predict how the interface will interact and affect the material

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    Description

    Test your knowledge on the properties of materials and their applications in optics and spectroscopy. This quiz covers key concepts such as refractive index, transparency, bonding types, and advanced analytical techniques. Explore fundamental principles and practical implications in material science.

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