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Functional Groups in Organic Chemistry

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Match the functional groups with their general formulas:

Alkyl = R- Hydroxyl = -OH Carbonyl = C=O Amino = -NH2

Match the functional groups with their polarity:

Hydroxyl = polar and hydrophilic Alkyl = non-polar and hydrophobic Carbonyl = polar and electrophilic Amino = basic and nucleophilic

Match the functional groups with their reactivity:

Aldehydes = undergoes oxidation, reduction, and condensation reactions Ketones = undergoes oxidation, reduction, and condensation reactions Carboxylic Acids = undergoes neutralization, esterification, and oxidation reactions Ethers = stable, unreactive

Match the compounds with their functional groups:

Methanol = Alcohols Diethyl ether = Ethers Formaldehyde = Aldehydes Acetone = Ketones

Match the functional groups with their physical properties:

Aldehydes = pungent odor, low boiling points Ketones = sweet or pungent odor, low boiling points Ethers = low boiling points, low polarity Carboxylic Acids = sour taste, corrosive

Match the functional groups with their chemical properties:

Alkyl = general-purpose programming Hydroxyl = polar and hydrophilic Carbonyl = electronegativity: oxygen pulls electrons, making carbon slightly positive Amino = basicity: acts as a base, accepting protons

Match the functional groups with their examples:

Alkyl = methyl (-CH3), ethyl (-C2H5), propyl (-C3H7) Hydroxyl = methanol (CH3OH), ethanol (C2H5OH) Carbonyl = formaldehyde (HCHO), acetone (C3H6O) Amino = methylamine (CH3NH2), aminoethane (C2H5NH2)

Match the functional groups with their characteristics:

Aldehydes = pungent odor, low boiling points, undergoes oxidation, reduction, and condensation reactions Ketones = sweet or pungent odor, low boiling points, undergoes oxidation, reduction, and condensation reactions Carboxylic Acids = sour taste, corrosive, undergoes neutralization, esterification, and oxidation reactions Ethers = low boiling points, low polarity, stable, unreactive

Study Notes

Functional Groups

Alkyl (R-)

  • A functional group consisting of a saturated hydrocarbon chain
  • General formula: R-
  • Examples: methyl (-CH3), ethyl (-C2H5), propyl (-C3H7)

Hydroxyl (-OH)

  • A functional group consisting of a hydrogen bonded to an oxygen atom
  • Found in alcohols and phenols
  • Polarity: polar and hydrophilic
  • Examples: methanol (CH3OH), ethanol (C2H5OH)

Carbonyl (C=O)

  • A functional group consisting of a carbon-oxygen double bond
  • Found in aldehydes, ketones, carboxylic acids, and esters
  • Electronegativity: oxygen pulls electrons, making carbon slightly positive
  • Examples: formaldehyde (HCHO), acetone (C3H6O)

Amino (-NH2)

  • A functional group consisting of a nitrogen bonded to two hydrogen atoms
  • Found in amines and amino acids
  • Basicity: acts as a base, accepting protons
  • Examples: methylamine (CH3NH2), aminoethane (C2H5NH2)

Alcohols (R-OH)

  • A functional group consisting of a hydroxyl group bonded to a carbon atom
  • Examples: methanol (CH3OH), ethanol (C2H5OH), glycerol (C3H8O3)
  • Physical properties: boiling point increases with molecular weight
  • Chemical properties: undergoes oxidation, esterification, and dehydration reactions

Ethers (R-O-R')

  • A functional group consisting of an oxygen bonded to two carbon atoms
  • Examples: diethyl ether (C2H5OC2H5), tetrahydrofuran (C4H8O)
  • Physical properties: low boiling points, low polarity
  • Chemical properties: stable, unreactive

Aldehydes (R-CHO)

  • A functional group consisting of a carbonyl bonded to a hydrogen atom
  • Examples: formaldehyde (HCHO), acetaldehyde (C2H4O)
  • Physical properties: pungent odor, low boiling points
  • Chemical properties: undergoes oxidation, reduction, and condensation reactions

Ketones (R-CO-R')

  • A functional group consisting of a carbonyl bonded to two carbon atoms
  • Examples: acetone (C3H6O), cyclohexanone (C6H10O)
  • Physical properties: sweet or pungent odor, low boiling points
  • Chemical properties: undergoes oxidation, reduction, and condensation reactions

Carboxylic Acids (R-COOH)

  • A functional group consisting of a carbonyl bonded to a hydroxyl group
  • Examples: formic acid (HCOOH), acetic acid (CH3COOH)
  • Physical properties: sour taste, corrosive
  • Chemical properties: undergoes neutralization, esterification, and oxidation reactions

Functional Groups

Alkyl (R-)

  • A saturated hydrocarbon chain with a general formula of R-
  • Examples include methyl (-CH3), ethyl (-C2H5), and propyl (-C3H7)

Hydroxyl (-OH)

  • A hydrogen bonded to an oxygen atom, making it polar and hydrophilic
  • Found in alcohols and phenols
  • Examples include methanol (CH3OH) and ethanol (C2H5OH)

Carbonyl (C=O)

  • A carbon-oxygen double bond, making carbon slightly positive due to oxygen's electronegativity
  • Found in aldehydes, ketones, carboxylic acids, and esters
  • Examples include formaldehyde (HCHO) and acetone (C3H6O)

Amino (-NH2)

  • A nitrogen bonded to two hydrogen atoms, making it a base that accepts protons
  • Found in amines and amino acids
  • Examples include methylamine (CH3NH2) and aminoethane (C2H5NH2)

Alcohols (R-OH)

  • A hydroxyl group bonded to a carbon atom, with boiling point increasing with molecular weight
  • Examples include methanol (CH3OH), ethanol (C2H5OH), and glycerol (C3H8O3)
  • Undergoes oxidation, esterification, and dehydration reactions

Ethers (R-O-R')

  • An oxygen bonded to two carbon atoms, with low boiling points and low polarity
  • Examples include diethyl ether (C2H5OC2H5) and tetrahydrofuran (C4H8O)
  • Stable and unreactive

Aldehydes (R-CHO)

  • A carbonyl bonded to a hydrogen atom, with pungent odor and low boiling points
  • Examples include formaldehyde (HCHO) and acetaldehyde (C2H4O)
  • Undergoes oxidation, reduction, and condensation reactions

Ketones (R-CO-R')

  • A carbonyl bonded to two carbon atoms, with sweet or pungent odor and low boiling points
  • Examples include acetone (C3H6O) and cyclohexanone (C6H10O)
  • Undergoes oxidation, reduction, and condensation reactions

Carboxylic Acids (R-COOH)

  • A carbonyl bonded to a hydroxyl group, with sour taste and corrosive properties
  • Examples include formic acid (HCOOH) and acetic acid (CH3COOH)
  • Undergoes neutralization, esterification, and oxidation reactions

This quiz covers the basics of functional groups in organic chemistry, including alkyl, hydroxyl, and carbonyl groups.

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