Podcast
Questions and Answers
What does a small change in pH represent on the pH scale?
What does a small change in pH represent on the pH scale?
- No significant change in acidity
- A minor change in ion concentration
- A large change in H+ concentration (correct)
- An inverse change in alkalinity
What are solutions that resist changes to pH known as?
What are solutions that resist changes to pH known as?
- Acidic solutions
- Buffers (correct)
- Alkaline solutions
- Solvents
What type of capacity do fluids in living organisms and seawater exhibit?
What type of capacity do fluids in living organisms and seawater exhibit?
- Conductive capacity
- Buffering capacity (correct)
- Absorptive capacity
- Evaporative capacity
Where are acid soils typically found?
Where are acid soils typically found?
Where are alkaline soils generally located?
Where are alkaline soils generally located?
What effect does rainfall typically have on soil pH?
What effect does rainfall typically have on soil pH?
What factor contributes to the acidophilic nature of Thiobacillus ferrooxidans?
What factor contributes to the acidophilic nature of Thiobacillus ferrooxidans?
What characteristic of Acid Mine Drainage (AMD) is commonly associated with Thiobacillus ferrooxidans?
What characteristic of Acid Mine Drainage (AMD) is commonly associated with Thiobacillus ferrooxidans?
What is the oxidation state change of iron in the reaction of pyrite oxidation?
What is the oxidation state change of iron in the reaction of pyrite oxidation?
Which environment is primarily responsible for accelerating the oxidation of pyrite?
Which environment is primarily responsible for accelerating the oxidation of pyrite?
What role do microbes like Thiobacillus ferrooxidans play in the oxidation of pyrite?
What role do microbes like Thiobacillus ferrooxidans play in the oxidation of pyrite?
In which type of geological formation is pyrite most commonly found?
In which type of geological formation is pyrite most commonly found?
What is produced in large quantities as a result of the oxidation of pyrite?
What is produced in large quantities as a result of the oxidation of pyrite?
What is the effect of acid mine drainage on local water sources?
What is the effect of acid mine drainage on local water sources?
What is the primary oxidizing agent in the oxidation of pyrite?
What is the primary oxidizing agent in the oxidation of pyrite?
What environmentally harmful phenomenon can result from the mining of pyrite-rich coal seams?
What environmentally harmful phenomenon can result from the mining of pyrite-rich coal seams?
What is the most notable property of silica as an inorganic coating?
What is the most notable property of silica as an inorganic coating?
What is released from rock due to acid mine drainage?
What is released from rock due to acid mine drainage?
Which of the following ecological impacts is caused by acid mine drainage?
Which of the following ecological impacts is caused by acid mine drainage?
What is a common physical property of gold?
What is a common physical property of gold?
Gold is typically bonded to which of the following metals?
Gold is typically bonded to which of the following metals?
What role does cyanide play in the process of gold extraction?
What role does cyanide play in the process of gold extraction?
At what temperature does the smelting process typically occur?
At what temperature does the smelting process typically occur?
What term is used for impurities in the smelting process?
What term is used for impurities in the smelting process?
What is the geological name for a rusty exposure of rock?
What is the geological name for a rusty exposure of rock?
What is the natural pH range for most plants?
What is the natural pH range for most plants?
Why do sulfide minerals like pyrite underwater not weather significantly?
Why do sulfide minerals like pyrite underwater not weather significantly?
Which of the following is NOT a treatment for acid mine drainage?
Which of the following is NOT a treatment for acid mine drainage?
Which method is effective in delaying oxidation related to acid mine drainage?
Which method is effective in delaying oxidation related to acid mine drainage?
What is a limitation of using wet cover as a treatment for acid mine drainage?
What is a limitation of using wet cover as a treatment for acid mine drainage?
Which approach is NOT suitable for long-term effectiveness against acid mine drainage?
Which approach is NOT suitable for long-term effectiveness against acid mine drainage?
What is a potential drawback of using bactericides in treating acid mine drainage?
What is a potential drawback of using bactericides in treating acid mine drainage?
What is the primary characteristic of the pH scale?
What is the primary characteristic of the pH scale?
Where are acid soils predominantly located?
Where are acid soils predominantly located?
What effect does rainfall have on soil pH?
What effect does rainfall have on soil pH?
Which statement about buffers is true?
Which statement about buffers is true?
Where are alkaline soils primarily found?
Where are alkaline soils primarily found?
What natural pH range is most suitable for plant growth?
What natural pH range is most suitable for plant growth?
Which of the following statements is incorrect regarding sulfide minerals submerged underwater?
Which of the following statements is incorrect regarding sulfide minerals submerged underwater?
What was the consequence of the 2000 Baia Mare cyanide spill?
What was the consequence of the 2000 Baia Mare cyanide spill?
What is the LC50 for inhalation of gaseous hydrogen cyanide?
What is the LC50 for inhalation of gaseous hydrogen cyanide?
Why has cyanide been banned for gold extraction in certain regions?
Why has cyanide been banned for gold extraction in certain regions?
What is one requirement imposed by the European Union after the Baia Mare cyanide spill?
What is one requirement imposed by the European Union after the Baia Mare cyanide spill?
What health effect occurs due to cyanide exposure?
What health effect occurs due to cyanide exposure?
What was a significant impact of cyanide on the ecosystem after the Baia Mare spill?
What was a significant impact of cyanide on the ecosystem after the Baia Mare spill?
What is the LC50 value for cyanide absorption through the skin and eyes?
What is the LC50 value for cyanide absorption through the skin and eyes?
Which two parties were involved in the joint venture responsible for the cyanide spill?
Which two parties were involved in the joint venture responsible for the cyanide spill?
Flashcards
Logarithmic nature of pH scale
Logarithmic nature of pH scale
A small change in pH value represents a significant change in the concentration of H+ ions.
What are buffers?
What are buffers?
Substances that resist changes in pH by absorbing excess H+ ions.
Buffering Capacity
Buffering Capacity
The ability of a solution to resist changes in pH.
Where are acid soils found?
Where are acid soils found?
Acidic soil is common in areas with high rainfall and poor buffering capacity.
Signup and view all the flashcards
Where are alkaline soils found?
Where are alkaline soils found?
Alkaline soils are common in areas with low rainfall and high mineral content.
Signup and view all the flashcards
What effect does rainfall have on soil pH?
What effect does rainfall have on soil pH?
Rainfall can lower the pH of soil over time, making it more acidic.
Signup and view all the flashcards
Pyrite Oxidation
Pyrite Oxidation
The chemical process where pyrite reacts with oxygen and water, producing hydrogen ions (H+) and contributing to acid mine drainage.
Signup and view all the flashcards
Pyrite
Pyrite
A mineral composed of iron sulfide (FeS2) with a characteristic brassy yellow color.
Signup and view all the flashcards
Ferric Hydroxide
Ferric Hydroxide
The chemical compound formed during pyrite oxidation, often found as a yellow-orange precipitate.
Signup and view all the flashcards
Acid Mine Drainage (AMD)
Acid Mine Drainage (AMD)
Acidic water runoff from mines, often caused by the oxidation of pyrite in the surrounding rocks.
Signup and view all the flashcards
Thiobacillus ferrooxidans
Thiobacillus ferrooxidans
A type of bacteria that accelerates the oxidation of pyrite, greatly increasing the production of acid mine drainage.
Signup and view all the flashcards
Gold Cyanidation
Gold Cyanidation
The process of extracting gold using cyanide, often used in mining operations.
Signup and view all the flashcards
Baia Mare Cyanide Spill
Baia Mare Cyanide Spill
A major cyanide spill that occurred in Romania, highlighting the risks associated with gold mining.
Signup and view all the flashcards
Preventing Acid Mine Drainage
Preventing Acid Mine Drainage
A strategy to reduce or eliminate acid mine drainage by preventing the contact of pyrite with oxygen and water.
Signup and view all the flashcards
What is the pH scale?
What is the pH scale?
A measure of the acidity or alkalinity of a solution. It is logarithmic, meaning a small change in pH represents a large change in hydrogen ion concentration.
Signup and view all the flashcards
What is the pH of clean rainwater and why?
What is the pH of clean rainwater and why?
Rainwater naturally combines with carbon dioxide in the atmosphere to form carbonic acid, which makes it slightly acidic. This results in a pH range of 5.6 to 5.7 for clean rainwater.
Signup and view all the flashcards
Where are acid soils commonly found?
Where are acid soils commonly found?
Typically found in environments with heavy rainfall and decomposing organic matter, such as rainforests and jungles.
Signup and view all the flashcards
Where are alkaline soils commonly found?
Where are alkaline soils commonly found?
Often found in drier regions with low rainfall, such as deserts, where weathering processes lead to the accumulation of alkaline minerals.
Signup and view all the flashcards
What is the natural pH range for most plants?
What is the natural pH range for most plants?
The natural pH range for most plants is acidic, typically between 5.5 and 7.
Signup and view all the flashcards
Why do sulfide minerals like pyrite not weather significantly underwater?
Why do sulfide minerals like pyrite not weather significantly underwater?
The weathering of sulfide minerals like pyrite occurs in the presence of oxygen and water. When these minerals are submerged underwater, they are sheltered from oxygen, significantly slowing down the weathering process.
Signup and view all the flashcards
What is the geological term for a rusty exposure of rock?
What is the geological term for a rusty exposure of rock?
A visible manifestation of geological weathering processes. It is characterized by reddish or yellowish hues caused by the presence of iron oxide compounds, commonly formed through the oxidation of sulfide minerals.
Signup and view all the flashcards
What is silica's importance in inorganic coatings?
What is silica's importance in inorganic coatings?
Silica is a material used in inorganic coatings and is valued for its stability, acid resistance, and longevity.
Signup and view all the flashcards
What causes acid mine drainage?
What causes acid mine drainage?
Acid mine drainage happens when sulphides in exposed rocks react with air and water.
Signup and view all the flashcards
Where does acid mine drainage travel?
Where does acid mine drainage travel?
Acid mine drainage can contaminate nearby water sources like streams, rivers, lakes, and groundwater.
Signup and view all the flashcards
What are the effects of acid mine drainage on the environment?
What are the effects of acid mine drainage on the environment?
Acid mine drainage negatively affects the physical, chemical, and biological aspects of aquatic environments.
Signup and view all the flashcards
What are some physical properties of gold?
What are some physical properties of gold?
Gold is soft and malleable, meaning it can be hammered into thin sheets or drawn into thin wires.
Signup and view all the flashcards
What metals is gold often bonded to?
What metals is gold often bonded to?
Gold is often found combined with other metals, like silver.
Signup and view all the flashcards
What is the role of cyanide in gold processing?
What is the role of cyanide in gold processing?
Cyanide is used in gold processing to extract gold by dissolving it from other metals and leaching it into the surrounding water.
Signup and view all the flashcards
What are impurities in the smelting process called?
What are impurities in the smelting process called?
Impurities remaining after the melting process are called slag.
Signup and view all the flashcards
Plant pH Range
Plant pH Range
The natural pH range for most plants is slightly acidic, ranging from 5.5 to 7.
Signup and view all the flashcards
Weathering of Sulfide Minerals in Water
Weathering of Sulfide Minerals in Water
Sulfide minerals like pyrite, when submerged in water, will not weather significantly due to the lack of oxygen. Oxygen is essential for the oxidation reaction that leads to weathering.
Signup and view all the flashcards
What is gossan?
What is gossan?
Gossan is a rusty-colored rock, often found at the surface, formed by the weathering of sulfide minerals like pyrite.
Signup and view all the flashcards
What is Acid Mine Drainage (AMD)?
What is Acid Mine Drainage (AMD)?
Acid Mine Drainage (AMD) is the acidic water draining from mines, often contaminated with heavy metals, caused by the oxidation of sulfide minerals.
Signup and view all the flashcards
AMD Treatments
AMD Treatments
Some treatments for Acid Mine Drainage (AMD) include adding buffers like limestone to neutralize acidity, limiting exposed rock, compacting acid-generating rock, and covering the rock with sealing layers.
Signup and view all the flashcards
Dry Cover for AMD Prevention
Dry Cover for AMD Prevention
Dry cover methods involve creating a layer of material over the sulfide-bearing waste to prevent oxidation and AMD. These methods usually include a layer of plastic liners.
Signup and view all the flashcards
Wet Cover for AMD Prevention
Wet Cover for AMD Prevention
Wet cover methods for AMD prevention involve completely submerging the sulfide-bearing waste in water to prevent oxidation, but require high maintenance costs.
Signup and view all the flashcards
Limitations of AMD Treatments
Limitations of AMD Treatments
While various AMD treatments are used to delay or prevent oxidation, they all have limitations. Physical barriers like wet or dry covers offer short-term effectiveness, while bactericides are toxic and only work on fresh tailings. Chemical barriers are effective but expensive.
Signup and view all the flashcards
Cyanide
Cyanide
A chemical compound used in gold mining that can be highly toxic to aquatic life and humans.
Signup and view all the flashcards
LC50
LC50
The minimum concentration of a substance that is lethal to 50% of the exposed population.
Signup and view all the flashcards
Biodegradable
Biodegradable
The ability of a substance to break down naturally in the environment.
Signup and view all the flashcards
Cellular Suffocation
Cellular Suffocation
The inability for cells to use oxygen effectively, often caused by cyanide poisoning.
Signup and view all the flashcards
Absorption Through Eyes and Skin
Absorption Through Eyes and Skin
The process by which a substance is absorbed through the eyes or skin.
Signup and view all the flashcards
Oxidation
Oxidation
The chemical breakdown of a compound by reacting with oxygen, often producing acidic byproducts.
Signup and view all the flashcardsStudy Notes
Acid Mine Drainage
- Pyrite Oxidation: A chemical reaction where pyrite (FeS₂) reacts with oxygen and water, producing ferric hydroxide, sulfuric acid, and hydrogen ions. The chemical formula is 4FeS₂ + 15O₂ + 14H₂O → 4Fe(OH)₃ + 8SO₄²⁻ + 16H⁺
- Pyrite Locations: Pyrite is commonly found in shales, often interbedded with coal seams, particularly those formed in marine coastal swamps.
- Microbial Action: Bacteria like Thiobacillus ferrooxidans accelerate pyrite oxidation. This process dramatically increases the rate of oxidation by 1,000,000x compared to oxygen alone. These bacteria convert insoluble metals to their soluble state and are highly acidophilic (pH 1.5 to 2.0).
- Acid Mine Drainage Prevention: Methods to prevent acid mine drainage include buffer materials like limestone, limiting exposed rock areas, compacting acid-generating rock, and covering the rock with sealing layers. Water cover (flooding) and inorganic/organic coatings are also mentioned as possible solutions.
- pH Scale: The pH scale is logarithmic, meaning a small change in pH represents a large change in H⁺ concentration.
- Buffer Solutions: Solutions that resist changes to pH are called buffers. They act like sponges, absorbing excess H⁺.
- Natural pH Range for Plants: Most plants have an acidic pH range between 5.5 and 7.
- What is Gossan? The geological name for a rusty exposure of rock is gossan.
- Impact of Rainfall: Rainfall combines with atmospheric CO₂ to form a weak acid (H₂CO₃). Clean rainwater has a pH of 5.6-5.7.
- Gold Cyanidation: Cyanide is used in 90% of gold production. Cyanide dissolves gold from its ores. The chemical formula for gold dissolution is: 4Au(s) + 8NaCN(aq) + O₂(g) + 2H₂O(l) → 4NaAu(CN)₂ + 4NaOH(aq).
- Cyanide Remediation: Cyanide remediation involves oxidizing cyanide (CN⁻) to OCN⁻, then converting OCN⁻ into HCO₃⁻ and NH₃.
- Cyanide Spills: Infamous cyanide spills include the 2000 Baia Mare spill in Romania, which polluted the Tisza and Danube rivers, killing numerous fish.
- Health Effects of Cyanide: Cyanide is highly toxic. Inhalation, ingestion, or skin/eye absorption can cause respiratory arrest and other severe health problems.
Gold Extraction and Processing
- Gold Properties: Gold is a soft, malleable metal that can be pounded thin, drawn into wire, and shaped into various forms. It does not rust or tarnish.
- Gold Bonding: Gold frequently occurs bonded to other metals such as silver.
- Cyanide in Gold Processing: Cyanide helps extract gold from other metals and leach it into the surrounding water.
- Smelter Temperature: The smelting process typically takes place at 1600 degrees Celsius.
- Impurities in Smelting: Impurities in the smelting process are called slag.
Studying That Suits You
Use AI to generate personalized quizzes and flashcards to suit your learning preferences.