Acid Mine Drainage and Sulfide Minerals
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Acid Mine Drainage and Sulfide Minerals

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Questions and Answers

What is the primary environmental issue caused by Acid Mine Drainage (AMD)?

  • Improvement of soil quality
  • Leaching of heavy metals into water sources (correct)
  • Enhancement of aquatic life growth
  • Increase in biodiversity in aquatic ecosystems
  • Which of the following sulfide minerals is not mentioned in the context of Acid Mine Drainage?

  • Pyrite
  • Chalcopyrite
  • Quartz (correct)
  • Galena
  • What role do certain bacteria play in the process of Acid Mine Drainage?

  • Bacteria neutralize the produced sulfuric acid
  • Bacteria can catalyze the oxidation of sulfide minerals (correct)
  • Bacteria clean up heavy metal contaminants
  • Bacteria inhibit the oxidation process of sulfide minerals
  • Which of the following processes does not contribute to the generation of sulfuric acid in the oxidation of iron sulfide?

    <p>Bacterial activation of Fe3+</p> Signup and view all the answers

    What is a consequence of the acidic water produced by Acid Mine Drainage?

    <p>Degradation of ecosystems</p> Signup and view all the answers

    Which environmental condition is primarily responsible for the oxidation of sulfide minerals leading to Acid Mine Drainage?

    <p>Presence of oxygen and water</p> Signup and view all the answers

    What primary problem did the Summitville Mine face due to its mining process?

    <p>Exposure of sulfide minerals to oxygen</p> Signup and view all the answers

    What are the two main electron acceptors in the oxidation process of iron sulfide?

    <p>O2 and Fe3+</p> Signup and view all the answers

    Which method was employed at the Bjørndalen Mine to mitigate acid mine drainage?

    <p>Installation of passive bioreactors with organic materials</p> Signup and view all the answers

    What effect does the contamination from Acid Mine Drainage typically have on aquatic life?

    <p>Harm to aquatic organisms</p> Signup and view all the answers

    What was the main purpose of the bioreactors used at Lily Mine?

    <p>To neutralize acid mine drainage and remove heavy metals</p> Signup and view all the answers

    What is a key characteristic of acid mine drainage that impacts ecosystems?

    <p>It can introduce heavy metals into waterways</p> Signup and view all the answers

    Which bacteria type was specifically utilized in the Summitville Mine's bioreactor for AMD treatment?

    <p>Sulfate-reducing bacteria</p> Signup and view all the answers

    What environmental issue did the Nelson Tunnel face as a result of historical mining activities?

    <p>Severe acid mine drainage</p> Signup and view all the answers

    What common outcome is associated with exposure of sulfide-bearing rocks in mining sites?

    <p>Formation of acid mine drainage</p> Signup and view all the answers

    What was the primary mineral extraction focus of the Wheal Jane Mine?

    <p>Gold and copper</p> Signup and view all the answers

    What is the primary role of Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans in the process of acid mine drainage?

    <p>They oxidize ferrous iron to ferric iron.</p> Signup and view all the answers

    What is a significant consequence of the positive feedback loop created by the oxidation of sulfide minerals?

    <p>Increase in the oxidation of sulfide minerals.</p> Signup and view all the answers

    Which of the following components is essential for the design of bioreactors used in AMD treatment?

    <p>Temperature and pH control.</p> Signup and view all the answers

    What challenge is often faced when managing bioreactors for AMD treatment?

    <p>Stable pH and temperature fluctuations.</p> Signup and view all the answers

    What is a key limitation affecting the scalability of bioreactors for AMD treatment?

    <p>Site-specific needs for customization.</p> Signup and view all the answers

    What is formed when ferrous iron is oxidized in aerated streams due to the presence of oxygen?

    <p>Iron hydroxide.</p> Signup and view all the answers

    Which of the following reactions contributes directly to the production of sulfuric acid in AMD?

    <p>2Fe2+ + 3O2 + 6H2O → 4Fe(OH)3 + 2H+.</p> Signup and view all the answers

    What type of bacteria are primarily involved in the oxidation of iron sulfide in AMD?

    <p>Acidophilic bacteria.</p> Signup and view all the answers

    Study Notes

    Acid Mine Drainage (AMD)

    • Environmental problem caused by surface mining operations
    • Leads to leaching of heavy metals into water sources
    • Caused by bacterial and spontaneous oxidation of sulfide minerals

    Sulfide Minerals

    • Minerals containing sulfur as a major component
    • Examples include pyrite (FeS₂), chalcopyrite (CuFeS₂), galena (PbS), sphalerite (ZnS), and molybdenite (MoS₂)

    Oxidation of Iron Sulfide

    • The oxidation of FeS₂ is a combination of chemically and bacterially catalyzed reactions
    • Two electron acceptors participate in the process: O₂ & Fe³⁺

    Bacterial Oxidation

    • Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans are bacteria that play a crucial role in AMD
    • These bacteria oxidize ferrous iron (Fe²⁺) to ferric iron (Fe³⁺)
    • The ferric iron reacts with sulfide minerals, such as pyrite, to produce sulfuric acid (H₂SO₄)
    • This process creates a positive feedback loop, where the increased acidity from sulfuric acid leads to further oxidation of sulfide minerals, accelerating AMD

    Bioreactors

    • Closed container with arrangements for aeration, agitation, temperature and pH control, and a drain or overflow vent to remove waste biomass of cultured microorganisms along with their products

    Challenges of Using Bioreactors

    • Careful management of environmental conditions is needed to ensure optimal microbial activity and metal recovery
    • Fluctuations in pH, temperature, and nutrients can hinder efficiency

    Limitations of Using Bioreactors

    • Bioreactor scalability for AMD treatment is limited by factors like microbial interactions and site-specific needs
    • This can hinder their widespread use in mining due to the need for customized designs

    Case Studies of AMD

    • Wheal Jane Mine (England)

      • Primarily known for gold and copper extraction
      • Uses water treatment systems, mine reclamation, environmental rehabilitation, and monitoring
    • Summitville Mine (Colorado)

      • Large-scale gold mine
      • Mining process exposed sulfide minerals to oxygen, creating AMD
      • Bioreactor using sulfate-reducing bacteria was introduced to treat the acid-laden waters contaminated with metals such as copper and zinc
    • Bjørndalen Mine (Norway)

      • Historically used for mining various metals
      • Waste rock and exposed ores contributed to AMD
      • Passive bioreactors with organic materials were used to encourage sulfate-reducing bacteria to precipitate metals out of the AMD, neutralizing the water
    • Lily Mine (South Africa)

      • Gold mine faced significant AMD issues
      • Bioreactors using microbial processes were deployed to neutralize the AMD and remove heavy metals like iron and manganese from the water
    • Nelson Tunnel / Commodore Waste Rock Pile (Colorado)

      • Part of a historic silver mining operation
      • Exposed sulfide minerals led to severe AMD

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    Description

    This quiz focuses on acid mine drainage (AMD), a significant environmental problem caused by mining activities. It explores the role of sulfide minerals and specific bacteria in the oxidation processes, detailing their impact on water sources and metal leaching.

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