Acid Mine Drainage and Sulfide Minerals

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Questions and Answers

What is the primary environmental issue caused by Acid Mine Drainage (AMD)?

  • Improvement of soil quality
  • Leaching of heavy metals into water sources (correct)
  • Enhancement of aquatic life growth
  • Increase in biodiversity in aquatic ecosystems

Which of the following sulfide minerals is not mentioned in the context of Acid Mine Drainage?

  • Pyrite
  • Chalcopyrite
  • Quartz (correct)
  • Galena

What role do certain bacteria play in the process of Acid Mine Drainage?

  • Bacteria neutralize the produced sulfuric acid
  • Bacteria can catalyze the oxidation of sulfide minerals (correct)
  • Bacteria clean up heavy metal contaminants
  • Bacteria inhibit the oxidation process of sulfide minerals

Which of the following processes does not contribute to the generation of sulfuric acid in the oxidation of iron sulfide?

<p>Bacterial activation of Fe3+ (A)</p> Signup and view all the answers

What is a consequence of the acidic water produced by Acid Mine Drainage?

<p>Degradation of ecosystems (D)</p> Signup and view all the answers

Which environmental condition is primarily responsible for the oxidation of sulfide minerals leading to Acid Mine Drainage?

<p>Presence of oxygen and water (B)</p> Signup and view all the answers

What primary problem did the Summitville Mine face due to its mining process?

<p>Exposure of sulfide minerals to oxygen (D)</p> Signup and view all the answers

What are the two main electron acceptors in the oxidation process of iron sulfide?

<p>O2 and Fe3+ (D)</p> Signup and view all the answers

Which method was employed at the Bjørndalen Mine to mitigate acid mine drainage?

<p>Installation of passive bioreactors with organic materials (D)</p> Signup and view all the answers

What effect does the contamination from Acid Mine Drainage typically have on aquatic life?

<p>Harm to aquatic organisms (B)</p> Signup and view all the answers

What was the main purpose of the bioreactors used at Lily Mine?

<p>To neutralize acid mine drainage and remove heavy metals (D)</p> Signup and view all the answers

What is a key characteristic of acid mine drainage that impacts ecosystems?

<p>It can introduce heavy metals into waterways (C)</p> Signup and view all the answers

Which bacteria type was specifically utilized in the Summitville Mine's bioreactor for AMD treatment?

<p>Sulfate-reducing bacteria (A)</p> Signup and view all the answers

What environmental issue did the Nelson Tunnel face as a result of historical mining activities?

<p>Severe acid mine drainage (B)</p> Signup and view all the answers

What common outcome is associated with exposure of sulfide-bearing rocks in mining sites?

<p>Formation of acid mine drainage (C)</p> Signup and view all the answers

What was the primary mineral extraction focus of the Wheal Jane Mine?

<p>Gold and copper (A)</p> Signup and view all the answers

What is the primary role of Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans in the process of acid mine drainage?

<p>They oxidize ferrous iron to ferric iron. (C)</p> Signup and view all the answers

What is a significant consequence of the positive feedback loop created by the oxidation of sulfide minerals?

<p>Increase in the oxidation of sulfide minerals. (A)</p> Signup and view all the answers

Which of the following components is essential for the design of bioreactors used in AMD treatment?

<p>Temperature and pH control. (B)</p> Signup and view all the answers

What challenge is often faced when managing bioreactors for AMD treatment?

<p>Stable pH and temperature fluctuations. (A)</p> Signup and view all the answers

What is a key limitation affecting the scalability of bioreactors for AMD treatment?

<p>Site-specific needs for customization. (B)</p> Signup and view all the answers

What is formed when ferrous iron is oxidized in aerated streams due to the presence of oxygen?

<p>Iron hydroxide. (C)</p> Signup and view all the answers

Which of the following reactions contributes directly to the production of sulfuric acid in AMD?

<p>2Fe2+ + 3O2 + 6H2O → 4Fe(OH)3 + 2H+. (B)</p> Signup and view all the answers

What type of bacteria are primarily involved in the oxidation of iron sulfide in AMD?

<p>Acidophilic bacteria. (C)</p> Signup and view all the answers

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Study Notes

Acid Mine Drainage (AMD)

  • Environmental problem caused by surface mining operations
  • Leads to leaching of heavy metals into water sources
  • Caused by bacterial and spontaneous oxidation of sulfide minerals

Sulfide Minerals

  • Minerals containing sulfur as a major component
  • Examples include pyrite (FeS₂), chalcopyrite (CuFeS₂), galena (PbS), sphalerite (ZnS), and molybdenite (MoS₂)

Oxidation of Iron Sulfide

  • The oxidation of FeS₂ is a combination of chemically and bacterially catalyzed reactions
  • Two electron acceptors participate in the process: O₂ & Fe³⁺

Bacterial Oxidation

  • Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans are bacteria that play a crucial role in AMD
  • These bacteria oxidize ferrous iron (Fe²⁺) to ferric iron (Fe³⁺)
  • The ferric iron reacts with sulfide minerals, such as pyrite, to produce sulfuric acid (H₂SO₄)
  • This process creates a positive feedback loop, where the increased acidity from sulfuric acid leads to further oxidation of sulfide minerals, accelerating AMD

Bioreactors

  • Closed container with arrangements for aeration, agitation, temperature and pH control, and a drain or overflow vent to remove waste biomass of cultured microorganisms along with their products

Challenges of Using Bioreactors

  • Careful management of environmental conditions is needed to ensure optimal microbial activity and metal recovery
  • Fluctuations in pH, temperature, and nutrients can hinder efficiency

Limitations of Using Bioreactors

  • Bioreactor scalability for AMD treatment is limited by factors like microbial interactions and site-specific needs
  • This can hinder their widespread use in mining due to the need for customized designs

Case Studies of AMD

  • Wheal Jane Mine (England)

    • Primarily known for gold and copper extraction
    • Uses water treatment systems, mine reclamation, environmental rehabilitation, and monitoring
  • Summitville Mine (Colorado)

    • Large-scale gold mine
    • Mining process exposed sulfide minerals to oxygen, creating AMD
    • Bioreactor using sulfate-reducing bacteria was introduced to treat the acid-laden waters contaminated with metals such as copper and zinc
  • Bjørndalen Mine (Norway)

    • Historically used for mining various metals
    • Waste rock and exposed ores contributed to AMD
    • Passive bioreactors with organic materials were used to encourage sulfate-reducing bacteria to precipitate metals out of the AMD, neutralizing the water
  • Lily Mine (South Africa)

    • Gold mine faced significant AMD issues
    • Bioreactors using microbial processes were deployed to neutralize the AMD and remove heavy metals like iron and manganese from the water
  • Nelson Tunnel / Commodore Waste Rock Pile (Colorado)

    • Part of a historic silver mining operation
    • Exposed sulfide minerals led to severe AMD

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