Ec Unit-1 Bits (1) PDF

Summary

This document contains multiple choice questions about water and its treatment. The questions cover topics such as temporary and permanent hardness, estimation of hardness, and water softening methods. These questions are suitable for undergraduate-level studies in engineering chemistry.

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## WATER AND ITS TREATMENT ### III. MULTIPLE CHOICE QUESTIONS: 1. Temporary hardness in water is removed by * filtration * sedimentation * boiling * coagulation 2. Blow-down operation causes the removal of * scales * sludges * acidity * sodium chloride 3. Solubility...

## WATER AND ITS TREATMENT ### III. MULTIPLE CHOICE QUESTIONS: 1. Temporary hardness in water is removed by * filtration * sedimentation * boiling * coagulation 2. Blow-down operation causes the removal of * scales * sludges * acidity * sodium chloride 3. Solubility of calcium sulphate in water * increases with rise of temperature * decreases with rise of temperature * remains unaltered with rise of temperature * does not adopt any definite pattern with rise of temperature 4. Permanent hardness of water cannot be removed by * treatment with lime soda * by permutit process * boiling * ion-exchange process 5. Hard water is unfit for use in boilers for generating steam because * its boiling point is higher * hardwater does not produce lather inside the boiler * water decomposes into $O_2$ and $H_2$ * it produces scales inside the boiler 6. Estimation of hardness water by EDTA method is used to determine * alkaline hardness * temporary hardness only * permanent hardness only * all the above 7. Hardwater can be softened by passing it through * lime stone * sodium hexameta phosphate * ion-exchange resin * sodium silicate 8. Calgon is a trade name given to * sodium silicate * sodium hexametaphosphate * sodium meta phosphate * calcium phosphate 9. Brackish water mostly contains dissolved * calcium salts * magnesium salts * turbidity * sodium chloride 10. The method by which the ions are pulled out of salt water by direct current, and employing thin, rigid membrane pair is called * electro dialysis * reverse osmosis * zeolite * ion exchange 11. The purification of brackish water by reverse osmosis is also called as * super-filtration * supra-filtration * hypo-filtration * filtration 12. One part of $CaCO_3$ equivalent hardness per 105 parts of water is called * degree Clark * ppm * degree French * mg/l 13. Boiler corrosion caused by using highly alkaline water in a boiler is called * corrosion * boiler corrosion * caustic embrittlement * erosion 14. Caustic embrittlement can be avoided by using * sodium phosphate * hydrogen * ammonium hydroxide * sodium sulphate 15. Caustic embrittlement is a type of * boiler corrosion * conditioning * scale formation * sludge formation 16. The soft, loose and slimy precipitate formed within the boiler is called * scale * sludge * embrittlement * coagulation 17. Sodium meta aluminate used in internal treatment of boiler water produces flocculant precipitates of * $Mg(OH)_2$ and $Al(OH)_3$ * $NaOH$ and $Al(OH)_3$ * $Ca(OH)_2$ and $Al(OH)_3$ * $Mg(OH)_2$ and $Ca(OH)_2$ 18. In low pressure boilers carbonate conditioning of boiler feed water is carried out to remove * calcium bicarbonate * calcium sulphate * calcium chloride * calcium nitrate 19. The process of allowing water to stand undisturbed in big tanks for setting of the suspended particles due to force of gravity * coagulation * conditioning * sedimentation * screening 20. The composition of alum is * $K_2SO_4. Al_2(SO_4)_3. 24 H_2O$ * $K_2(SO_4)_3. Al_2.(SO_4)_3. 24 H_2O$ * $K_2SO_4. Al_2(SO_4)_3. 20 H_2O$ * $K_2SO_4. Al_2SO_4. 24 H_2O$ 21. Ferrous sulphate is commonly used in the treatment of municipal water for * filtration * flocculation * sedimentation * disinfection 22. Liquid chlorine is a most effective * disinfectant * coagulant * flocculant * sedimentation 23. Disinfection by ozone is due to liberation of * oxygen * nascent oxygen * molecular oxygen * oxide 24. The formula of chloramine is : * $ClNH_2$ * $NHCl_2$ * $NCl_3$ * $NH_2Cl_2$ 25. Phosphate conditioning of boiler feed is carried out by * $Na_3PO_4$ * $Ca_3(PO_4)_2$ * $Mg_3(PO_4)_2$ * $H_3PO_4$ 26. Tannins and agar-agar are used for * phosphate conditioning * carbonate conditioning * colloidal conditioning * calgon conditioning 27. The external treatment of boiler water feed done by * lime-soda process * sodium sulphate treatment * calgon process * sodium aluminate treatment 28. The process of wet-steam formation is called * foaming * priming * corrosion * caustic embrittlement 29. Mechanical steam purifiers avoid * corrosion * priming * scale formation * sludge formation 30. Castor oil is a * antiskinning agent * antifoaming agent * anti-ageing agent * anti-corrosive agent 31. The largest source of water is * lake water * river water * rain water * sea water 32. One of the following impurity is introduced into rain water due to the decomposition of plant and animal remains in water. * Organic impurities * Dissolved impurities * Floating impurities * Colloidal impurities 33. A water sample found to possess 16.2 mg/l of $Ca(HCO_3)_2$. Its hardness in terms of $CaCO_3$ equivalents is * 100 * 10 * 16.2 * 1000 34. Hardness of water is caused due to the presence of * undissolved salts of $Ca^{2+}$ and $Mg^{2+}$ * dissolved sulphates of potassium * dissolved salts of $Ca^{2+}$ and $Mg^{2+}$ * undissolved $CaCO_3$ 35. Which of the following methods separates both ionic and non-ionic impurities from water? * Electrodialysis * Deionisation * Reverse osmosis * Zeolite process 36. Potable water treatment does not involve * demineralisation * sedimentation * filtration * disinfection 37. The cofficient of thermal expansion of boiler plant is * more than boiler scale * less than boiler scale * equal to boiler scale * no comparison between two 38. Which of the following salts cause least hardness to water when converted to $CaCO_3$ equivalents? * 10 mgs of $CaCO_3$ * 19 mgs of $CaSO_4$ * 10 mgs of $MgCl_2$ * 10 mgs of $CaCl_2$ 39. Ultraviolet rays are used in the treatment of water for * Filtration * Sedimentation * Screening * Sterilisation 40. One of the following chemical act on both coagulant and softening agent * lime * soda * alum * sodium aluminate 41. The ion-exchanging resins used for softening of water are * cross-linked polymers with microporous structure * branched polymers with porons structure * cross-linked polymers with non-porous structure * branched polymers with non-porous structure 42. One of the following is an example of cation exchanging resin * copolymer of phenol formaldehyde or amine formaldehyde. * copolymer of styrene-divinyl benzene. * copolymer of phenol formaldehyde or styrene. * copolymer of amine formaldehyde or divinyl benzene. 43. Trisodium phosphate used for phosphate conditioning is * acidic * weakly acidic * weakly alkaline * alkaline 44. The membrane filtration adopted in reverse osmosis is also called * super filtration * supra filtration * ultra filtration * hypo filtration 45. A cation selective membrane consists of * positively changed functional groups * neutral functional groups * negatively changed functional groups * either positive or negative groups 46. One of the technique is followed in deflourination of drinking water by Nalgonda method * sedimentation * biological oxidation * screening * distillation 47. Deflourination is a technique depending on one of the mode of action * process * absorption process * desorption * condensation 48. One of the following is reference electrode is used in the estimation of flouride by ion-selective method. * calomel * hydrogen * silver or silverchloride * quinhydrone electrode 49. One of the following treat is classified under secondary treatment of sewage * screening * sedimentation * incineration * biological treatment 50. A shallow pit where the sludge is disposed is called * lagoon * ditch * tank * chamber ### IV. FILL IN THE BLANKS: 1. On addition of chlorine to water ______acid is produced which is powerful germicide. 2. Hardness of water is due to the dissolved salts of ______and ______. 3. The chemical which removes dissolved oxygen of water without adding hardness is ______. 4. Hardness of water is expressed in equivalents of ______. 5. In lime-soda process of softening, calcium and magnesium ions are precipitated as ______and ______. 6. Sodium aluminate is used as ______during purification of water. 7. Anion exchange resins are regenerated by using ______process. 8. Best method of removing hardness of water is ______. 9. Among chloramine, bleaching powder and chlorine ______is a powerful disinfectant. 10. The hardness of water in $CaCO_3$ equivalents containing $MgSO_4$ (mol. wt. 120) with concentration 12 mg/l is ______. 11. Presence of residual ______in boiler water causes caustic embrittlement. 12. ______causes the flow of solvent from lower concentration to higher concentration, which is separated by a semipermeable membrane. 13. In lime-soda process the addition of lime cannot remove ______hardness of water. 14. In phosphate conditioning if boiler feed water is too alkaline ______is used for internal conditioning. 15. Priming and foaming in boilers produce ______steam. 16. Cation exchange resin contains ______mobile ions. 17. The hardness of a sample of water is 10 ppm, which can be expressed as ______degree clarke. 18. A sample of water contains 11.1 mg/l of $CaCl_2$. Its hardness of $CaCO_3$ equivalent is ______. 19. ______is used as an indicator in the determination of hardness by EDTA method. 20. To maintain the pH between 9-10 during complexometric titration, estimation of hardness of water is ______. 21. Temporary hardness of water can be removed by ______. 22. Calgon treatment is used for the removal of dissolved ______. 23. The chemical structure of zeolite is ______. 24. Natrolite is a ______zeolite. 25. Ion free water is known as ______. 26. The exhausted zeolite is regenerated by ______. 27. ______is a process of allowing water to stand undisturbed in big tanks. 28. $Al_2(SO_4)_3$ alum produce ______as flocculant precipitates during softening of water. 29. ______membranes are selected for efficient separation of ions. 30. The presence of even small amounts of $MgCl_2$ will cause ______of boiler plate to a large extent. 31. ______is considered to be the naturally distilled water. 32. ______water contain the largest concentration of dissolved impurities. 33. Rain water picks up $CO_2$, $O_2$ etc., from atomsphere which introduces ______impurities into water. 34. The pure water is pushed out through a semipermeable membrane during ______. 35. Extra-pure water can be obtained by using ______. 36. A semipermeable membrane allows the flow of ______. 37. Chlorine, when treated with water produce ______acid, which acts as a powerful germicide. 38. The exhausted anion exchanging resin is regenerated by ______. 39. Rain water picks up gases like $CO_2$, $O_2$ etc. from ______. 40. The suspended and colloidal impurities are allowed to settle under gravitaion in ______process. 41. Among the dissolved gases, ______ is the most corroding impurity. 42. Zeolites are ______. 43. A copolymer of ______or ______is used as an anion exchanging resin. 44. Deionisation must be followed by ______. 45. If the alkalinity of boiler water is ______, sodium dihydrogen phosphate conditioning is carried out. 46. $CaCO_3$ is an ______salt when present in water. 47. Disinfectation by bleaching powder is also called ______. 48. $CaSO_4$ is ______soluble in cold water. 49. The precipitates of $CaCO_3$ and $Mg(OH)_2$ are very fine and causes ______problems. 50. The most preferred request for phosphate conditioning is ______. 51. In high pressure boilers the excess $Na_2CO_3$ remained during carbonate conditioning is converted to ______. 52. When the sewage contains oxidisation impurities beyond biological oxidation, then ______is carried out. 53. During Nalgonda process of removal of flourides employs ______principle. 54. Acetic acid and sodium hydroxide solution is used as a ______in the Nalgonda technique. 55. The oxygen required for the biological oxidation of bacteria present in sewage water is called ______. ### V. INDICATE TRUE OR FALSE FOR THE FOLLOWING: 1. Rain water is the purest form of natural water. **[T/F]** 2. Suspended impurities are present in natural water. **[T/F]** 3. Dissolved oxygen do not cause corrosion to boiler plate. **[T/F]** 4. Calcium and magnesium salts in water are removed by lime soda process. **[T/F]** 5. It is possible to remove permanent hardness of water by boiling. **[T/F]** 6. Chloramine is better than chlorine for sterilisation. **[T/F]** 7. The common unit to express hardness of water is ppm. **[T/F]** 8. Sludge is a soft, loose, slimy precipitate formed inside the boiler. **[T/F]** 9. $NH_4Cl$ and $NH_4OH$ buffer is used to maintain pH 12. **[T/F]** 10. Water softened by zeolite process causes caustic embrittlement. **[T/F]** 11. Hardness of water is expressed in calcium chloride equivalents. **[T/F]** 12. Hot lime-soda process is better than cold process. **[T/F]** 13. The presence of $CO_2$ in water produces carbonic acid. **[T/F]** 14. The process of removing hardness producing salts is called softening. **[T/F]** 15. Hydrated sodium aluminium silicate is called zeolite.**[T/F]** 16. The process of removing common salt from water is called salination. **[T/F]** 17. Addition of calgon to boiler water prevents calcium sulphate scale formation. **[T/F]** 18. Hard water precipitates, soap as calcium soap.**[T/F]** 19. Reverse osmosis removes all ionic, non-ionic and colloidal impurities from water. **[T/F]** 20. Dissolved calcium bicarbonate in water causes permanent hardness. **[T/F]** 21. pH of acidic water is more than 7. **[T/F]** 22. Hard water softened by EDTA method. **[T/F]** 23. Break point chlorination gives the exact amount of chlorine to be added to raw water. **[T/F]** 24. The exhausted permutit is regenerated by $ZnCl_2$. **[T/F]** 25. Extra pure water is obtained by electrodialysis. **[T/F]** 26. Coagulant helps in setting of colloidal particles only. **[T/F]** 27. A permeable membrane allows the flow of solvent molecules. **[T/F]** 28. Calgon is a trade name of sodium hexa meta phosphate. **[T/F]** 29. Calgon conditioning is better than phosphate conditioning. **[T/F]** 30. Water is softened before using in boilers by external treatment. **[T/F]** 31. Chemically oxidisation impurities of sewage is measured by COD. **[T/F]** 32. Nalgonda process is for the removal of chlorine from drinking water. **[T/F]** 33. Silver electrode is used as reference electrode for the estimation flourine by ion-selective electrode. **[T/F]** 34. Activated sludge process is for the oxidation of biological impurities in sewage water. **[T/F]** 35. Screening is a preliminary treatment. **[T/F]** ### III. MULTIPLE CHOICE QUESTIONS: | 1) | c | 2) | b | 3) | b | 4) | c | 5) | d | 6) | d | 7) | c | 8) | b | 9) | d | 10) | a | |---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---| | 11) | a | 12) | c | 13) | c | 14) | d | 15) | a | 16) | b | 17) | a | 18) | b | 19) | c | 20) | a | | 21) | b | 22) | a | 23) | b | 24) | a | 25) | a | 26) | c | 27) | a | 28) | b | 29) | b | 30) | b | | 31) | d | 32) | a | 33) | b | 34) | c | 35) | c | 36) | a | 37) | a | 38) | b | 39) | d | 40) | d | | 41) | a | 42) | b | 43) | d | 44) | a | 45) | c | 46) | a | 47) | b | 48) | c | 49) | d | 50) | a | ### IV. FILL IN THE BLANKS: 1. hypochlorous 4. calcium carbonate 7. sodium hydroxide 10. 10 mgl 1=) calcium permanent 15. wet 18. 10 mgl 21. boiling 23. $Na_2O. Al_2O_3, nSiO_2. y H_2O$ 25. deionised or demineralised water 27. Sedimentation 30. corrosion 33. dissolved gas 36. solvent molecules 39. atmosphere 42. cation exchangers 44. degasification 47. hypo-chlorination 50. trisodium phosphate 53. flocculation 2. calcium and magnesium 5. $CaCO_3$ and $Mg(OH)_2$ 8. ion-exchange process 11. $NaOH$ or caustic soda 14. $NaH_2PO_4$ or sodium dihydrogen phosphate 16. $H^+$ 19. Eriochrome black - T 22. $CaSO_4$ 24. natural 26. $NaCl$ 28. $Al(OH)_3$ 29. Ion-selective 31. Rain water 34. reverse osmosis 37. hypochlorous 40. sedimentation 43. phenol formaldehyde and amine formaldehyde 45. high 48. more 51. $NaOH$ 54. buffer 3. hydrazine 6. coagulant 9. chlorine 12. Osmosis 17. 0.7 °Cl 20. $NHCl_2$, $NH_2OH$ 32. Sea water 35. electrodialysis 38. $NaOH$ 41. oxygen 46. insoluble 49. after deposition 52. chemical oxidation 55. BOD ### V. TRUE OR FALSE QUESTIONS: | 1) | T | 2) | T | 3) | F | 4) | T | 5) | F | |---|---|---|---|---|---|---|---|---|---| | 6) | F | 7) | T | 8) | T | 9) | F | 10) | T | | 11) | F | 12) | T | 13) | T | 14) | T | 15) | T | | 16) | F | 17) | T | 18) | T | 19) | T | 20) | F | | 21) | F | 22) | F | 23) | T | 24) | F | 25) | T | | 26) | F | 27) | T | 28) | T | 29) | T | 30) | T | | 31) | T | 32) | F | 33) | T | 34) | T | 35) | T |

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