Summary

This document discusses nuclear reactions, covering both chemical and nuclear reactions, including the concepts of atomic nuclei, nuclear equations, and nuclear stability. It explains the fundamental difference between chemical and nuclear changes and introduces the basic principles of nuclear chemistry.

Full Transcript

NUCLEAR REACTIONS Nuclear Chemistry  The study of the structure of atomic nuclei and the changes they undergo. SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS Nuclear Reactions  The “ordinary chemical reactions”...

NUCLEAR REACTIONS Nuclear Chemistry  The study of the structure of atomic nuclei and the changes they undergo. SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS Nuclear Reactions  The “ordinary chemical reactions” discussed from the previous lessons involve changes in the outer electronic structures of atoms or molecules. In contrast, nuclear reactions result from the changes taking place within the atomic nuclei. SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS Atomic Nuclei The atomic nuclei are represented by symbols such as: SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS Nuclear Equations  In a chemical reaction, we write the symbols for various chemical elements but in a nuclear reaction, we must also explicitly indicate protons, neutrons, and electrons that are produced during the course of nuclear fission or fusion reaction. While writing the nuclear equation, we have to mention the numbers of protons and neutrons present in all the elements. SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS Nuclear Equations The following points need to be considered while writing nuclear equations.  A nuclear equation must be balanced.  The symbol for an atom or atomic particle should include the symbol of the element, the atomic number and mass number.  The mass number of atom (which is used to describe the number of protons and neutrons) should be attached at the upper left of the symbol.  The atomic number of atom (which is used to describe the number of protons in the nucleus) should be attached at the lower left of the symbol. SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS Examples of Balanced Nuclear Equations NOTE! The nuclear equation must be balanced with respect to nuclear charge (atomic number) and nucleus mass (mass number). SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS NUCLEAR STABILITY  Nuclear Stability is a concept that helps to identify the stability of an isotope. The two main factors that determine nuclear stability are the neutron/proton ratio and the total number of nucleons in the nucleus.  Nuclear stability refers to the tendency of a nucleus of an atom to decay, which means to change into something else.  Isotopes of atoms with unstable nuclei are called radioisotopes. SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS NUCLEAR STABILITY  Isotope Stability The graph of stable elements is commonly referred to as the Band (or Belt) of Stability. The graph consists of a y-axis labeled neutrons, an x-axis labeled protons, and a nuclei. At the higher end (upper right) of the band of stability lies the radionuclides that decay via alpha decay, below is positron emission or electron capture, above is beta emissions and elements beyond the atomic number of 83 are only unstable radioactive elements. Stable nuclei with atomic numbers up to about 20 have an neutron:proton ratio of about 1:1 (solid line). SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS NUCLEAR STABILITY NUCLEAR STABILITY  An isotope is an element that has same atomic number but different atomic mass compared to the periodic table. Every element has a proton, neutron, and electron. The number of protons is equal to the atomic number, and the number of electrons is equal the protons, unless it is an ion. To determine the number of neutrons in an element you subtract the atomic number from the atomic mass of the element. Atomic mass is represented as (A) and atomic number is represented as (Z) and neutrons are represented as (N). A= N+ Z SEA – GENERAL ENGINEERING DEPARTMENT CHEMISTRY FOR ENGINEERS NUCLEAR STABILITY  The principal factor for determining whether a nucleus is stable is the neutron to proton ratio. Elements with (Z

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