Water Properties Chemistry PDF

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FluentHarmonica

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water chemistry molecular structure chemical bonding physical properties

Summary

This document provides a detailed explanation of the chemical properties of water. It covers topics such as the chemical formula, Lewis structure, VSEPR theory, and the unique properties of water. Water's intermolecular forces and its influence on physical properties like boiling and melting points are also discussed.

Full Transcript

Chemical Formula The chemical formula of water is H20, indicating that each molecule consists of two hydrogen (H) atoms and one oxygen (O) atom. Lewis Structure In the Lewis structure, the oxygen atom is represented in the center with two pairs of lone electrons and two single hydrogen atoms atta...

Chemical Formula The chemical formula of water is H20, indicating that each molecule consists of two hydrogen (H) atoms and one oxygen (O) atom. Lewis Structure In the Lewis structure, the oxygen atom is represented in the center with two pairs of lone electrons and two single hydrogen atoms attached. This illustrates the sharing of electrons in covalent bonds. Shared Electrons Shared electrons are the electrons involved in covalent bonds between the hydrogen and oxygen atoms. Each hydrogen shares one electron with oxygen, forming two O-H bonds. Lone Pairs Oxygen possesses two lone pairs of electrons which are not involved in bonding. These lone pairs influence the molecular shape by repelling bonded electron pairs. VSEPR Theory According to the Valence Shell Electron Pair Repulsion (VSEPR) theory, electron pairs around a central atom will arrange themselves as far apart as possible to minimize repulsion. Bent Shape Due to the two lone pairs, the water molecule adopts a bent shape instead of a linear structure. This shape is a direct result of the repulsion between lone pairs and bonding pairs. Bond Angle The bond angle in water is approximately 104.5 degrees. This angle reflects the impact of lone pair repulsion, which compresses the angle between the two O-H bonds from what would otherwise be a straight line. Summary The molecular structure of water, characterized by its H2O formula, Lewis structure, and VSEPR theory insights, leads to its bent shape and specific bond angle of 104.5 degrees, vital for its unique properties. Intermolecular forces are interactions between molecules that influence physical properties, such as boiling and melting points. Water exhibits unique forces due to its molecular characteristics. Identification of lons Water is a neutral molecule; therefore, it contains no ions. This lack of ionic bonding leads to different interaction types compared to ionic compounds. Polar Molecule Status Water is a polar molecule, meaning it has a partial positive charge on hydrogen atoms and a partial negative charge on the oxygen atom, resulting in significant interactions. Water's unique properties result from the strong intermolecular forces of attraction characterized by Hydrogen Bond 1. Some polar molecules have very high electronegativity differences. Most especially true for fluorine, oxygen, and nitrogen bonded to a hydrogen. This results to a high partial positive charge on hydrogen and a large partial negative charge for the more electronegative atom. Because of the very large dipole produced between the hydrogen atom of one molecule and the F, N, O of another molecule, a special name is given to this kind of force - hydrogen bond. Therefore, hydrogen bond is actually dipole-dipole in nature but for molecules containing O-H, H-F, and N-H, this force is called a hydrogen bond. The presence of H-bond also produces a higher boiling point than the ordinary dipole-dipole because it is a stronger intermolecular force. 1. 1. What about in its solid form? This more open structure of the solid form of water causes the ice to have smaller number of molecules packed in a given volume. This causes the mass to be lower, hence, the density of ice is lesser than the liquid water and, as a result, ice tloats on water. This also causes water in lakes to freeze from the top down. 1. 1.

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