EEE 2408 Integrated Circuits Lecture 2 - Sand to Silicon PDF

Document Details

Kenyatta University

2024

EEC

Mr. Peter Karanja

Tags

semiconductor fabrication integrated circuits silicon wafers electronics engineering

Summary

This document is a lecture on the production of integrated circuits. It introduces the process of fabricating silicon wafers from sand, a key component in modern electronics. The lecture outlines various steps involved and the role of foundries in producing these chips.

Full Transcript

DEPARTMENT OF ELECTRICAL & ELECTRONICS ENGINEERING EEE 2408: Integrated Circuits Week 2 Facilitator: Mr. Peter Karanja Email: [email protected] LECTURE 2 FROM SAND TO SILICON EE...

DEPARTMENT OF ELECTRICAL & ELECTRONICS ENGINEERING EEE 2408: Integrated Circuits Week 2 Facilitator: Mr. Peter Karanja Email: [email protected] LECTURE 2 FROM SAND TO SILICON EEC 2408 – Integrated Circuits September 2024 PERSPECTIVE Foundries, also known as semiconductor fabrication plants or chip fabs, are highly specialized facilities where advanced microchips and integrated circuits (ICs) are manufactured. These plants play a critical role in the global tech ecosystem, as they produce the foundational components that power nearly all modern electronics, from smartphones and computers to medical devices and cars. The work carried out in foundries is essential for the development of cutting-edge technologies, making them the heart of the semiconductor industry. Inside a foundry, the production process is incredibly intricate and involves more than 300 individual steps, each requiring absolute precision. Engineers and technicians oversee the fabrication of microchips through processes like photolithography, etching, doping, and deposition. Each stage of manufacturing is carried out in ultra-clean environments, as even the smallest contamination can cause defects in these highly delicate components. The transformation of basic silicon into functioning chips that contain billions of transistors is a testament to the remarkable engineering and technological prowess present in these facilities. Foundries are home to some of the most advanced machinery in the world. Cutting-edge technologies are used to create chips at nanometer scales, pushing the boundaries of what is physically possible. Leading companies like Taiwan Semiconductor Manufacturing Company (TSMC), Intel, and Samsung Foundry are at the forefront of this industry, continuously innovating to develop smaller, faster, and more energy- efficient chips. These companies not only provide chips for consumer electronics but also contribute to industries like artificial intelligence, automotive, telecommunications, and more. The great work happening in these foundries shapes the future of technology. Engineers, scientists, and technicians work tirelessly to meet the growing global demand for semiconductors, driving innovation across multiple sectors. The importance of foundries in enabling advancements in computing power, connectivity, and energy efficiency cannot be overstated. Their role in advancing technological progress highlights the critical value of these facilities in our increasingly connected and digital world. It may seem an impossible transformation, but these fiendishly complex chips are made from nothing more glamorous than sand. Such a transformative feat isn’t simple. The production process requires more than 300 individual steps. Page | 2 EEC 2408 – Integrated Circuits September 2024 Fig 1. IC Fabrication Process In the lecture series that shall follow, we shall take an in-depth look at the manufacturing method and distill the whole process into the individual component stages. So, to find out how sandcastles become Core i7 & AMD processors, read on – and prepare to be amazed. Lecture Objectives In this first lecture we delve into the process of production of semiconductor wafers. Page | 3 EEC 2408 – Integrated Circuits September 2024 TABLE OF CONTENTS 1.0 INTRODUCTION: Silicon Wafers............................................................................................................. 5 1.1 PART 1: WAFER FABRICATION PROCESS......................................................................................... 7 1.1.1 STEP ONE: Converting sand to silicon.................................................................................................. 7 1.1.2 STEP TWO: Ingot Growth..................................................................................................................... 8 1.1.3 STEP THREE: Slicing............................................................................................................................ 9 1.1.4 STEP FOUR Cleaning.......................................................................................................................... 10 1.1.5 STEP FIVE: Polishing.......................................................................................................................... 10 1.1.6 STEP SIX: Packaging........................................................................................................................... 11 Page | 4 EEC 2408 – Integrated Circuits September 2024 1.0 INTRODUCTION: Silicon Wafers Silicon is often referred to as the "workhorse" of the semiconductor industry. Silicon, a metalloid with the symbol Si and atomic number 14, is the material of choice in the semiconductor industry due to its unique combination of properties and advantages. Why Silicon? 1. Electrical Properties: Silicon has an energy bandgap of approximately 1.1 electron volts (eV), which strikes a balance between insulating and conducting states. This characteristic allows it to effectively control electrical current and operate across a wide range of voltages and frequencies, making it ideal for semiconductor applications. 2. Abundance and Cost: Silicon is the second most abundant element in the Earth's crust, making up about 27.7% by weight. It primarily exists as silicon dioxide (SiO₂) and silicates. Its plentiful availability ensures a stable and cost-effective supply, reducing raw material costs compared to rarer semiconductors like gallium arsenide (GaAs). 3. Mature Processing Technology: The semiconductor industry has developed highly refined and efficient processing techniques for silicon, including the Czochralski method for crystal growth and photolithography for wafer patterning. These mature technologies enable high-quality production and reliable semiconductor devices. 4. Thermal Stability: Silicon maintains its performance and structural integrity over a wide range of temperatures. Its high thermal conductivity aids in heat dissipation, which is essential for the reliability and longevity of electronic components. 5. Oxide Formation: Silicon forms a stable, high-quality layer of silicon dioxide (SiO₂) when exposed to oxygen. This insulating layer is crucial for fabricating transistors and integrated circuits, providing excellent electrical insulation and dielectric properties. 6. Scalability and Integration: The properties of silicon support the integration of billions of transistors on a single chip, facilitating the production of complex and high-performance microprocessors and memory devices. This scalability is vital for advancing technology and enhancing computing power. 7. Established Supply Chain: The global supply chain for silicon is well-established, encompassing every stage from raw material extraction to wafer fabrication and device assembly. This infrastructure supports the high-volume production required for various consumer electronics and industrial applications. Page | 5 EEC 2408 – Integrated Circuits September 2024 Silicon wafers are the cornerstone of the semiconductor industry, serving as the substrate for fabricating integrated circuits and other semiconductor devices. These thin, flat discs of silicon are essential in the production of a vast array of electronic components, including microprocessors, memory chips, and sensors. The wafers can be of different sizes from 1 inch (25.4 mm) up to 300 mm for a thickness of the order of 0.7 mm. The trend is to use the largest wafers possible to be able to burn more chips simultaneously and limit losses on the edge of the plate, resulting in increased production at a lower cost. We print integrated circuits, transistors, and power semiconductors on these tight grid wafers to put as much as possible on a single silicon or semiconductor wafer. Page | 6 EEC 2408 – Integrated Circuits September 2024 1.1 PART 1: WAFER FABRICATION PROCESS 1.1.1 STEP ONE: Converting sand to silicon Before a semiconductor can be built, silicon must turn into a wafer. This begins with the growth of a silicon ingot. A single silicon crystal consists of atoms arranged in a three-dimensional periodic pattern that extends throughout the material. A polysilicon crystal is formed by many small single crystals with different orientations, which alone, cannot be used for semiconductor devices. Sand is composed of silica (also known as silicon dioxide SiO2) and is the starting point for making a processor. Sand used in the building industry is often yellow, orange or red due to impurities, but the type chosen in the manufacture of silicon is a purer form known as silica sand, which is usually recovered by quarrying. The starting material for Si manufacture is quartzite (SiO2) or sand. The ore is reduced to Si by mixing with coke and heating in a submerged electrode arc furnace. The SiO2 reacts with excess C to first form SiC. At high temperature (2,000°C), the SiC reduces SiO2 to form Si. The overall reaction is given By SiC (s) + SiO2 (s) → Si (l) + SiO (g) + CO (g)………………………..(1) The Si(l) formed is removed from the bottom of the furnace. This is the Metallurgical grade Silicon (MGS) and is around 98% pure. This is not nearly pure enough for semiconductor manufacture. The next task is to refine the Metallurgical grade Silicon (MGS) further to Electronic Grade Silicon (EGS). One of the techniques for converting MGS to EGS is called the Seimens process. In this process the Si is reacted with HCl gas to form tricholorosilane, which is in gaseous form. Si (s) + 3HCl (g) → SiHCl3 (g) + H2 (g) ………………………..(2) The reaction is performed in a fluidized-bed reactor at temperatures around 300oC (550oF). Trichlorosilane (SiHCl3), although shown as a gas in Eq. 2, is a liquid at room temperature. Its low boiling point of 32oC (90oF) permits it to be separated from the leftover impurities of MGS by fractional distillation. The final step in the process is reduction of the purified Trichlorosilane by means of hydrogen gas. The process is carried out at temperatures up to 1000oC (1800oF), and a simplified equation of the reaction can be written as follows: 2SiHCl3 (g) + 2H2 (g) → 2Si (s) + 6HCl (g) ………………………..(3) Page | 7 EEC 2408 – Integrated Circuits September 2024 The product of this reaction is electronic grade silicon—nearly 100% pure Si. 1.1.2 STEP TWO: Ingot Growth Although pure to a very high degree, raw electronic-grade silicon has a polycrystalline structure. In other words, it’s made up of lots of small silicon crystals, with defects called grain boundaries between them. Because these anomalies affect local electronic behaviour, polycrystalline silicon is unsuitable for semiconductor manufacturing. To turn it into a usable material, the silicon must be turned into single crystals that have a regular atomic structure. This transformation is achieved through the Czochralski Process and the Float zone technique. Fig 1. Czochralski Process To grow an ingot, the first step is to heat the silicon to 1500°C, which is above the melting point of silicon (1412°C). Once the polycrystalline and dopant combination has been liquified, a single silicon crystal, the seed, is positioned on top of the melt, barely touching the surface. The seed has the same crystal orientation required in the finished ingot. Page | 8 EEC 2408 – Integrated Circuits September 2024 To achieve doping uniformity, the seed crystal and the crucible of molten silicon rotate in opposite directions. Once the system reaches proper conditions for crystal growth, the seed crystal slowly lifts out of the melt. Growth begins with a rapid pulling of the seed crystal. This minimizes the number of crystal defects within the seed at the beginning of the growing process. After this, the pull speed reduces to allow the diameter of the crystal to increase. When the desired diameter is obtained, the growth conditions are stabilized to maintain the diameter. As the seed is slowly lifts above the melt, the surface tension between the seed and the melt causes a thin film of the silicon to adhere to the seed and then to cool. While cooling, the atoms in the melted silicon orient themselves to the crystal structure of the seed. The final solidified Si obtained is the single crystal ingot. A 450 mm wafer ingot can be as heavy as 800 kg. A picture of a such an ingot is show in figure 2. 1.1.3 STEP THREE: Slicing Integrated circuits are approximately linear, which is to say that they’re formed on the surface of the silicon. To maximize the surface area of silicon available for making chips, the boule is sliced up into discs called wafers. Fig 2. Slicing of Ingot into wafers After passing a number of inspections, the ingot proceeds to slicing. Because of the silicon’s hardness, a diamond edge saw carefully slices the silicon wafers so they are slightly thicker than the target specification. The diamond edge saw also helps to minimize damage to the wafers, thickness variation, and bow and warp defects. Page | 9 EEC 2408 – Integrated Circuits September 2024 After the wafers have been sliced, the lapping process begins. Lapping the wafer removes saw marks and surface defects from the front and backside of the wafer. It also thins the wafer and helps to relieve stress accumulated in the wafer from the slicing process. After lapping the silicon wafers, they go through an etching and cleaning process. Sodium hydroxide or acetic and nitric acids alleviate any microscopic cracks and/or surface damage that may have come about during lapping. The nitric acid oxides the surfaces to give a thin layer of silicon dioxide which the hydrofluoric acid immediately dissolves away to leave a clean silicon surface – and the acetic acid controls the reaction rate. A critical edge grinding procedure takes place to round the edges, drastically reducing the probability of breakage in the remaining steps of manufacturing and later when device manufacturers use the wafers. After rounding the edges, depending on the end user’s specification, oftentimes the edges will go through an extra polishing step, improving overall cleanliness and further reducing breakage up to 400%. 1.1.4 STEP FOUR Cleaning The final and most crucial step in the manufacturing process is polishing the wafer. This process takes place in a clean room. Clean rooms have a rating system that ranges from Class 1 to Class 10,000. The rating corresponds to the number of impurity particles per cubic foot. These particles are not visible to the naked eye and in an uncontrolled atmosphere, such as a living room or office, the particle count would likely be 5 million per cubic foot. To help maintain this level of cleanliness, the workers must wear clean room suits that cover their body from head to toe and do not collect or carry any particles. They also stand under a fan that blows away any small particles that might have accumulated before entering the room. 1.1.5 STEP FIVE: Polishing Most prime grade silicon wafers go through 2-3 stages of polishing, using progressively finer slurries or polishing compounds. The majority of the time, wafers are polished on the front side only, excluding 300mm wafers which are double side polished. Polishing produces a mirror finish. The polish also distinguishes which side to use for device fabrication. This surface must be free of topography, micro-cracks, scratches, and residual work damage. The polishing process occurs in two steps, which are stock removal and final chemical mechanical polish (CMP). Both processes use polishing pads and polishing slurry. The stock removal process removes a very thin layer of silicon and is necessary to produce a wafer surface that is damage-free. On the other hand, the final polish does not remove any material. During the stock removal process, a haze forms on the surface of the wafer, so an extra polishing step gives the wafer a mirror finish. After polishing, the silicon wafers proceed to a final cleaning stage that uses a long series of clean baths. This process removes surface particles, trace metals, and residues. Oftentimes a backside scrub is done to remove even the smallest particle. Page | 10 EEC 2408 – Integrated Circuits September 2024 1.1.6 STEP SIX: Packaging Once the wafers complete the final cleaning step, engineers sort them by specification and inspect them under high intensity lights or laser-scanning systems. This detects unwanted particles or other defects that may have occurred during fabrication. All wafers that meet the proper specifications are packaged in cassettes and sealed with tape. The wafers ship in a vacuum-sealed plastic bag with an airtight foil outer bag. This ensures that no particles or moisture enters the cassette upon leaving the clean room. Page | 11

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