What is the definition of hyperconjugation?

Understand the Problem

The question is asking for a definition of hyperconjugation, a concept in chemistry related to molecular interactions and stability. We will provide a concise and clear explanation of this term.

Answer

The delocalization of electrons from a σ-bond to an adjacent empty or partially filled p orbital, increasing molecule stability.

In organic chemistry, hyperconjugation refers to the delocalization of electrons from a σ-bond (usually C-H or C-C) to an adjacent empty or partially filled p orbital, or a π orbital, resulting in increased stability of the molecule.

Answer for screen readers

In organic chemistry, hyperconjugation refers to the delocalization of electrons from a σ-bond (usually C-H or C-C) to an adjacent empty or partially filled p orbital, or a π orbital, resulting in increased stability of the molecule.

More Information

Hyperconjugation can also be described as a type of resonance involving σ bonds that increases the stability of carbocations, radicals, and alkenes.

Tips

A common mistake is to confuse hyperconjugation with regular resonance, which typically involves π bonds rather than σ bonds.

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