If the ratio of specific heat of a gas at constant pressure to that at constant volume is γ, what is the change in internal energy of a mass of gas when the volume changes from V t... If the ratio of specific heat of a gas at constant pressure to that at constant volume is γ, what is the change in internal energy of a mass of gas when the volume changes from V to 2V under constant pressure p?

Understand the Problem

The question is asking for the change in internal energy of a gas when its volume changes at constant pressure. The problem involves thermodynamic concepts, specifically relating to the specific heat capacity of gases and internal energy changes.

Answer

$$ \Delta U = n C_p \Delta T - P \Delta V $$
Answer for screen readers

The change in internal energy is given by the equation:
$$ \Delta U = n C_p \Delta T - P \Delta V $$

Steps to Solve

  1. Identify the Formula
    To find the change in internal energy ($\Delta U$) of a gas at constant pressure, we use the first law of thermodynamics. The formula is:
    $$ \Delta U = Q - W $$
    Where $Q$ is the heat added to the system and $W$ is the work done by the system.

  2. Calculate Work Done
    At constant pressure, the work done by the gas when it expands or contracts is given by the formula:
    $$ W = P \Delta V $$
    Where $P$ is the pressure and $\Delta V$ is the change in volume.

  3. Calculate Heat Added
    For an ideal gas at constant pressure, the heat added can be calculated using the specific heat capacity at constant pressure ($C_p$) and the change in temperature ($\Delta T$):
    $$ Q = n C_p \Delta T $$
    Where $n$ is the number of moles of gas.

  4. Combine the Equations
    Substituting the expressions for $Q$ and $W$ into the first law of thermodynamics gives us:
    $$ \Delta U = n C_p \Delta T - P \Delta V $$

  5. Final Expression
    Depending on the problem specifics, values for $n$, $C_p$, $\Delta T$, $P$, and $\Delta V$ can then be substituted into the equation to find $\Delta U$.

The change in internal energy is given by the equation:
$$ \Delta U = n C_p \Delta T - P \Delta V $$

More Information

The relationship between internal energy, heat, and work done highlights the energy conservation principle in thermodynamics. Changes in volume at constant pressure are crucial in understanding gas behavior.

Tips

  • Forgetting to convert units to match (e.g., pressure in Pascals and volume in cubic meters).
  • Not using the correct formulas for heat or work in constant pressure situations.
  • Confusing the signs of work and heat in the first law of thermodynamics.

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