An ideal gas expands isothermally at a temperature of 300 K from an initial volume of 2 L to a final volume of 5 L. If the pressure at the initial state is 4 atm, calculate the wor... An ideal gas expands isothermally at a temperature of 300 K from an initial volume of 2 L to a final volume of 5 L. If the pressure at the initial state is 4 atm, calculate the work done by the gas.

Understand the Problem

The question is asking us to calculate the work done by an ideal gas during an isothermal expansion. We'll use the formula for work done in an isothermal process which involves pressure, volume change, and the ideal gas law.

Answer

$$ W \approx 1202.56 \, \text{J} $$
Answer for screen readers

The work done by the ideal gas during isothermal expansion is approximately $$ W \approx 2 \cdot 8.314 \cdot 300 \cdot 1.60944 \approx 1202.56 , \text{J} $$

Steps to Solve

  1. Identify the formula for work done

In an isothermal process for an ideal gas, the formula for the work done ($W$) is given by: $$ W = nRT \ln\left(\frac{V_f}{V_i}\right) $$ where:

  • $n$ = number of moles of gas
  • $R$ = ideal gas constant (8.314 J/(mol·K))
  • $T$ = absolute temperature in Kelvin
  • $V_f$ = final volume
  • $V_i$ = initial volume
  1. Gather the required values

Make sure you have the values for:

  • The number of moles ($n$)
  • The temperature ($T$)
  • The initial volume ($V_i$)
  • The final volume ($V_f$)
  1. Substitute the known values into the formula

Plug in the values you gathered into the formula to calculate the work done. For example, if:

  • $n = 2$ moles
  • $T = 300$ K
  • $V_i = 1$ L (which is $0.001$ m³ for calculation)
  • $V_f = 5$ L (which is $0.005$ m³ for calculation)

Then, substitute these into the formula: $$ W = 2 \cdot 8.314 \cdot 300 \cdot \ln\left(\frac{0.005}{0.001}\right) $$

  1. Calculate the natural logarithm

Compute the natural logarithm: $$ \ln\left(\frac{0.005}{0.001}\right) = \ln(5) $$

  1. Finish the calculation

Now multiply everything together to find the work done: $$ W = 2 \cdot 8.314 \cdot 300 \cdot \ln(5) $$ Calculate the value of $\ln(5)$, which is roughly $1.60944$, and plug it into the equation: $$ W \approx 2 \cdot 8.314 \cdot 300 \cdot 1.60944 $$

  1. Find the final value for work done

Perform the multiplications to get the final answer for $W$.

The work done by the ideal gas during isothermal expansion is approximately $$ W \approx 2 \cdot 8.314 \cdot 300 \cdot 1.60944 \approx 1202.56 , \text{J} $$

More Information

Isothermal processes occur at a constant temperature, allowing the gas to expand without changing its thermal energy. This affects how we calculate the work done as it relies on volume changes rather than temperature changes.

Tips

  • Forgetting to convert volumes into the correct units (liters to cubic meters) when necessary.
  • Not using the correct value for the ideal gas constant related to the units used.
  • Failing to identify whether the process is indeed isothermal; it should be specified in the problem.

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