A gaseous mixture containing equal masses of He and CH4 is at a total pressure of 2 atm. Calculate the partial pressure of He. What will be the pressure exerted by a mixture of 3.2... A gaseous mixture containing equal masses of He and CH4 is at a total pressure of 2 atm. Calculate the partial pressure of He. What will be the pressure exerted by a mixture of 3.2 g of methane and 4.4 g of carbon dioxide contained in a 9 dm3 flask at 27 °C? What will be the pressure of the gaseous mixture when 0.5 L of H at 0.8 bar and 2.0 L of dioxygen at 0.7 bar are introduced in a vessel at 27 °C? Calculate the total pressure in a mixture of 8 g of dioxygen and 4 g of dihydrogen confined in a vessel of 1 dm3 at 27 °C. Calculate the total pressure in a mixture of 3 g of dinitrogen, 3.0 g of dthyrogen, and 8.0 g of dioxygen confined in vessel of 5 dm3 at 27 °C. What is the partial pressure of dihydrogen and dioxygen in a mixture that contains 20% by weight of dihydrogen? A neon-dioxygen mixture contains 70.6 g dioxygen and 167.5 g neon. If pressure of the mixture of gases in the cylinder is 25 bar. What is the partial pressure of dioxygen and neon in the mixture? 1 mole of a gas 'AB' dissociates to an extent of 10% at 127 °C according to AB ⟶ A + B. Occupies a volume of 4 x 10-4 m3. Find total pressure at this temp, assuming ideal gas behavior. A closed bulb of capacity 200 ml containing CH4, H2 and He at 300K. The ratio of partial pressures of CH4, H2 and He, respectively is 2 : 3 : 5. Calculate the ratio of their weights present in the container. Dalton's law of partial pressure will not hold good for which of the following mixture? 2 gm of H2 and 17 gm NH3 are placed in a 8.21 liter flask at 27 °C. The total pressure of the gas mixture is 4 atm, 5 atm, 6 atm or 3 atm? A balloon filled with N2O is pricked with a sharper point and plunged into a tank of SO2 under the same pressure and temperature. The balloon will be enlarged, shrink, collapse or remain unchanged? One mole of N2O4 at 300 K is kept in a closed container under 1 atm pressure. It is heated to 600 k when 20% by mass of N2O4 decomposes to 'NO2'(g). The resultant pressure is 1.2 atm, 2.4 atm, 2 atm or 1 atm?

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Understand the Problem

The question provides a series of numerical problems related to Dalton's Law of Partial Pressures, requiring calculations for partial pressures, total pressures, and gas behavior under specific conditions.

Answer

Partial pressure of He: $1.6$ atm; Partial pressure of CH₄: $0.4$ atm.
Answer for screen readers

Partial pressure of He is $1.6$ atm, and the partial pressure of CH₄ is $0.4$ atm for the first example at a total pressure of 2 atm.

Steps to Solve

  1. Identify the Problem and Given Information

We are given various scenarios under Dalton's Law and need to perform calculations related to partial and total pressures of gas mixtures.

  1. Calculate Partial Pressure of He and CH₄

For the first scenario with equal masses of He and CH₄ at a total pressure of 2 atm:

Let the mass of each gas be $m_{\text{He}}$ and $m_{\text{CH}_4}$.

Given the molar masses:

  • Molar mass of He = 4 g/mol
  • Molar mass of CH₄ = 16 g/mol

Using the relation for partial pressure:

$$ P_{\text{He}} = \frac{n_{\text{He}}}{n_{\text{total}}} \times P_{\text{total}} $$

and

$$ P_{\text{CH}4} = \frac{n{\text{CH}4}}{n{\text{total}}} \times P_{\text{total}} $$

  1. Compute Moles for Each Gas

Calculate the number of moles:

$$ n_{\text{He}} = \frac{m}{\text{Molar Mass of He}} = \frac{1}{4} \text{ mol} $$

$$ n_{\text{CH}_4} = \frac{m}{\text{Molar Mass of CH}_4} = \frac{1}{16} \text{ mol} $$

  1. Calculate Total Moles

Total moles $n_{\text{total}} = n_{\text{He}} + n_{\text{CH}_4} = \frac{1}{4} + \frac{1}{16} = \frac{4 + 1}{16} = \frac{5}{16}$ mol.

  1. Calculate Individual Partial Pressures

Using the total pressure of 2 atm:

$$ P_{\text{He}} = \frac{\frac{1}{4}}{\frac{5}{16}} \times 2 $$

$$ P_{\text{CH}_4} = \frac{\frac{1}{16}}{\frac{5}{16}} \times 2 $$

  1. Final Calculations

Calculate the individual pressures and round off if necessary to two decimal places.

  1. Review Answers for Other Scenarios

Repeat similar calculations for the remaining scenarios provided in the question.

Partial pressure of He is $1.6$ atm, and the partial pressure of CH₄ is $0.4$ atm for the first example at a total pressure of 2 atm.

More Information

Dalton's Law of Partial Pressures states that the total pressure exerted by a mixture of non-reacting gases is equal to the sum of the partial pressures of each individual gas.

Tips

  • Failing to properly convert masses to moles using the correct molar masses.
  • Misunderstanding the relationship between total pressure and individual partial pressures.

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