Straighterline Chemistry Final Exam 2024

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134 Questions

Which of these elements is chemically similar to magnesium?

Calcium

What is the vapor pressure above a beaker containing a solution of NaCl that is made up of 250ml of water and 12g of NaCl?

23.4 mmHg

A smart phone has dimensions of 4.9 inches (height), 2.3 inches (width) and 8.0 millimeters (depth). What is the volume of the smart phone in cubic centimeters? (1 in = 2.54 cm)

58 cm3

What is the term used for findings that are summarized based on a pattern or trend?

Law

Which of the following is a tentative explanation for a set of observations?

Hypothesis

Plants use up copious amounts of which alkali metal, preventing most of it from being washed out to sea?

Potassium

Which of the following isotopes is likely to be the most stable?

Sn-50

What is the reducing agent in the following equation? Mg(s) + 2 HCl(aq) --> MgCl2(aq) + H2(g)

Mg

What is Avogadro's number?

The number of atoms in 12g of Carbon-12

What is the ratio of reactants and products in the chemical equation? NaOH + H2SO4 ==> Na2SO4 + H2O

2:1:1:2

Most nonmetallic elements are found in which block of the periodic table of elements?

P

Which arrangement accurately describes the standard entropy values for Na at different phases?

Na (s) < Na (l) < Na (g)

What element has been oxidized and what element has been reduced in the redox reaction shown? 3CuS + 8HNO3 ==> 3CuSO4 + 8NO + 4H20

Sulfur has been oxidized; nitrogen has been reduced

When iron ions react with water, is the iron ion acting like an acid or a base?

The iron ion is acting like an acid

Is either of the two major steps in the Haber-Bosch process considered an oxidation-reduction reaction?

Both of these steps are oxidation-reduction reactions

If the concentration of sulfuric acid is increased in a galvanic cell, will Ecell increase or decrease?

Ecell will decrease

Calculate the value of the standard Gibbs Free Energy change for the reaction CH3OH(l) + CO(g) --> CH3COOH(l). Is acetic acid thermodynamically stable compared with liquid water at standard conditions?

ΔG°rxn = -86.0 kJ; At standard conditions, acetic acid is less thermodynamically stable than water because it has a more negative value of ΔG°

What type of semiconductor would be produced by adding indium to silicon, and which element could produce the opposite type of semiconductor?

Doping silicon with indium produces a 'p-type' semiconductor; Adding arsenic to silicon would produce a 'p-type' semiconductor

What are atoms that have the same number of protons but different numbers of neutrons called?

Isotopes

Who proposed an atomic theory in 1808?

John Dalton

Who discovered the magnitude of the electron charge?

R.Millikan

What did E. Rutherford discover?

Nucleus

How are metals and non-metals separated in the periodic table?

Staircase

What are the horizontal rows in the periodic table called?

Periods

What is the reactant that is used up first in a chemical reaction called?

Limiting reagent

What is the term used to describe the concentration of a solution?

Molarity

What is the chemical formula of a compound determined from its molecular mass called?

Molecular Formula

A phase diagram is a diagram depicting the phases of a substance at different temperatures and pressures.

True

Phase change is a physical change involving a substance changing from one state of matter to another, such as liquid to gas.

True

Surface tension is the tendency of liquids to maximize their surface area.

False

Sublimation is a phase change involving a substance changing from solid directly to gas.

True

The solubility of ionic compounds in water is mainly determined by which of the following forces?

Ion-dipole

Solids can be divided into two categories, crystalline and...

Amorphous

The two types of close-packing are called cubic close-packing and...

Hexagonal

Three types of atomic solids are nonbonded, metallic, and...

Network covalent

Effusion is the transfer of gas through a small orifice into an evacuated chamber.

True

Kinetic molecular theory is a basic atomic model that describes the behavior of...

Gases

Boyle's law is a gas law that associates the product of the pressure and volume with the number of moles, temperature, and a universal proportionality constant.

True

Standard temperature and pressure are conditions defined as 0ºC and 1 atm.

True

The solubility of ionic compounds in water is mainly determined by which of the following forces?

Ion-dipole

An alloy is an example of a ... solution.

Solid-solid

The Tyndall effect is the effect whereby a colloidal solution interacts with electricity.

False

Raoult's law applies to a solution comprised of a non-volatile solute and is the relationship between the vapor pressure of the solution and the vapor pressure of the pure solvent.

True

Boiling point elevation is a colligative property that involves the increase in the boiling point of a solvent by the addition of a solute.

True

Colligative properties are concerned with the type of particles and not their number.

False

When a solid is dissolved in water and forms a solution that conducts electricity, the solid is called a(n)...

Electrolyte

Two dissolved ions in hard water are Mg2+ and...

Ca2+

When a solid comes out of a solution, the solid is called a(n)...

Precipitate

Acid-base reactions are also called...

Neutralization

Who defined an acid as a proton donor and a base as a hydroxide donor?

Arrhenius

A reaction where electrons are transferred from one reactant to another is called a...

Redox or oxidation-reduction

What is the term for the phenomenon where two electrons in the same orbital must have opposite spins?

Pauli exclusion principle

How many electrons can p-orbitals hold at most?

Six

How many electrons can d orbitals hold at most?

Ten

What is the actual nuclear charge minus the charge from the core electrons called?

Effective nuclear charge

Unreactive gases that have a full valence shell of electrons are known as...

Noble gases

A reduction in atomic radii caused by the 4f electrons being close to the nucleus is called...

Lanthanide contraction

What are the two particles that compose the nucleus?

Neutrons and Protons

What is the charge of a proton?

positive

What is the charge of a neutron?

neutral

What is the charge of an electron?

negative

Are protons and electrons equal in charge?

equal

What is a derived unit?

A unit defined by a combination of SI units

Who proposed the Atomic Theory in 1803?

John Dalton

Who discovered the nucleus?

Ernest Rutherford

Who discovered the magnitude of the electron charge?

R.Millikan

Who proposed the "plum pudding" model of the atom?

JJ Thomson

What is Raoult's Law?

relationship between the vapor pressure of a solution and the vapor pressure of the pure solvent

Define Boiling Point Elevation.

the difference in temperature between the boiling point of a solution and the boiling point of the pure solvent

Which two ions are dissolved in hard water?

Mg2+ and Ca2+

What is the definition of a Precipitate?

When a solid comes out of a solution

What are Acid-base reactions also called?

neutralization reactions

How did Arrhenius define acids and bases?

Defined acids as proton donors and bases as hydroxide donors

What is Redox or Oxidation-Reduction?

reaction where electrons are transferred from one reactant to another

Define Orbital.

plot of the wavefunction squared that gives the probability map of the electron's position

What is Wavelength?

the distance between the wave peaks and troughs

What is Amplitude?

the magnitude of a wave; in sound, the primary determinant of loudness

What is a Node?

Point in wavefunction where the electron cannot be found

What is an Emission Spectrum?

radiation that is emitted by atoms

What determines an atom's electron configuration?

specific orbitals that electrons occupy

Explain the Pauli Exclusion Principle.

Two electrons in the same orbital must have opposite spins

Define Valence Electrons.

Electrons on the outermost energy level of an atom

What is the element essential for plant growth?

potassium

What do Group 1A elements have in terms of charge?

1+

What do Group 2A elements have in terms of charge?

2+

What do Group 3A elements have in terms of charge?

3+

What do Group 4A elements have in terms of charge?

4-

What do Group 5A elements have in terms of charge?

3-

What do Group 6A elements have in terms of charge?

2-

What do Group 7A elements have in terms of charge?

1-

What is the formula for Zinc Iodide?

ZnI2

What is done to the formula if a cation and anion have different charge values?

Swap the charge numbers and put them as subscripts

What is the name of NF3?

Nitrogen Trifluoride

What is the name of N2O4?

Dinitrogen Tetroxide

What is the molecular formula for Carbon Disulfide?

CS2

What is the molecular formula for Dinitrogen Trioxide?

N2O3

What is the molecular formula for Sulfur Tetrafluoride?

SF4

What is the molecular formula for Tetraphosphorus Decasulfide?

P4S10

What is the empirical formula for C6H12O6?

CH2O

All elements fall into one of the following groups: ____, ____, ____

metal, nonmetal, metalloid

What does the mass number equal to?

number of protons + number of neutrons

What is the number below an element on the periodic table?

Atomic Weight

What is the number above an element on the periodic table?

Atomic Number

What are Alpha rays?

Positively charged particles that are deflected away from the positively charged plate

What are Beta rays?

Electrons that are deflected away from the negatively charged plate

What are Gamma rays?

high energy radiation that have no charge and are unaffected by external electric or magnetic fields

What are Strong Acids?

HCl, HBr, HI, HNO3, H2SO4, HClO4, HClO3, HSO4

What is the formula for the mass of an Electron?

charge/(charge/mass)

What is the charge of Element+?

Minus one electron

What is the charge of Element-?

plus one electron

What should be done if a cation and anion have different values in their charge for the formula?

Swap the charge numbers and put them as subscripts

What does 'Mono' represent?

1

What does 'Di' represent?

2

What does 'Tri' represent?

3

What does 'Tetra' represent?

4

What does 'Penta' represent?

5

What is the scientific name for NF3?

Nitrogen Trifluoride

What is the proper name for N2O4?

Dinitrogen Tetroxide

What is the molecular formula for Carbon Disulfide?

CS2

What is the molecular formula of Dinitrogen Trioxide?

N2O3

What is the molecular formula for Sulfur Tetrafluoride?

SF4

What is the molecular formula for Tetraphosphorus Decasulfide?

P4S10

What is the empirical formula for C6H12O6?

CH2O

Calculate the number of moles in 47.51 g of Al2O3.

0.4660 mol

Known to form complexes with platinum that inhibit the growth of cancerous cells, what is the systematic name for [CoCl3(H2O)]-?

Aquatrichlorocobaltate(II)

In K4[Fe(CN)6], how many 3d electrons does the iron atom have?

6

Write the formula for diamminedichloroethylenediaminecobalt(III) bromide.

[CoCl2(en)(NH3)2]Br

In the complex ion [Co(en)2Br2]+, what is the oxidation number of Co?

+3

In which type of isomerism is there restricted rotation around a bond?

Geometrical isomers

What name is given to a compound containing a -CONH2 group?

Amide

Bromination of benzene (C6H6) occurs by substitution rather than addition.

True

The density of a substance is an intensive property.

True

The rusting of a piece of iron under environmental conditions is a physical change.

False

77 K is colder than 4 K.

False

Study Notes

Here are the study notes:

Chemistry

  • StraighterLine Chemistry Final Exam 2024-2025

Elements and Compounds

  • Calcium is chemically similar to magnesium.
  • Iron(III) ion has an electron configuration of [Ar]3d5.
  • Phosphorus has a hybridization of sp3 in the PCl4+ cation.

Atomic Structure

  • Effective nuclear charge is less than the actual nuclear charge due to shielding.
  • Electron configuration of an element with ns2np1 outermost electrons is in group 3A.

Molecular Geometry

  • Molecular geometry of ammonia (NH3) is trigonal pyramidal.
  • AB5 molecules with one lone pair on the central atom have a square pyramidal molecular geometry.

Stoichiometry

  • Mass of one copper atom is 1.055 × 10-22 g.
  • Percent sulfur in iron(III) sulfate is 24%.
  • Micrograms in 65.3 kg is 6.53 × 1010 μg.

Chemical Bonding

  • CS2 is a covalent compound.
  • Molecular geometry of a molecule with one lone pair on the central atom is trigonal pyramidal.

Periodic Table

  • Electron configuration of gold is [Xe]4f145d106s1.
  • Characteristics of isotopes were described.
  • Atomic mass unit is a unit of mass equal to one-twelfth the mass of a carbon-12 atom.

Spectroscopy

  • Emission spectra can be used to identify unknown atoms.
  • Different types of spectra were described.

Acids and Bases

  • A strong acid is H2SO4.
  • Equilibrium constant for the autoionization of water at 25°C is 1.0 × 10-14.
  • Amphiprotic species include Al2O3.

Gases

  • Conditions of STP are 273.15 K and 760 torr.
  • Van der Waals equation was described, including the constants a and b.

Intermolecular Forces

  • Hydrogen bonding occurs in CH3CH2OH.
  • Dispersion forces are stronger in krypton than in argon.
  • Types of intermolecular forces were described.

Solubility and Solutions

  • Henry's law states that the solubility of a gas in a liquid is proportional to the pressure of the gas over the solution.
  • An unsaturated solution is one that contains less solute than it has the capacity to dissolve.
  • Solubility of a gas in a liquid is affected by pressure, temperature, and nature of the solute and solvent.Here are the study notes:

Selective Precipitation

  • The principle of selective precipitation is used to identify the types of ions present in a solution.
  • It is also known as qualitative analysis.

Acid-Base Indicators

  • Methyl red is a common acid-base indicator.
  • It has a Ka equal to 6.3 × 10-6.
  • The un-ionized form of methyl red is red, and its anionic form is yellow.
  • At a pH of 7.8, a methyl red solution would be yellow.

Titration

  • When a strong acid is titrated with a weak base, the pH at the equivalence point is less than 7.0.
  • A spontaneous endothermic reaction always causes the surroundings to get colder.

Nuclear Chemistry

  • 123I is used to image the brain.
  • Nuclear power plants do not pollute the air with SO2, soot, and fly-ash.
  • Californium-249 is used to obtain dubnium-260.
  • Sr-92 is used to obtain an isotope with atomic number 121 and mass number 299.

Coordination Compounds

  • The name given to a compound containing a -CONH2 group is an amide.
  • Bromination of benzene occurs by substitution rather than addition.
  • The rusting of a piece of iron under environmental conditions is a chemical change.
  • Lewis theorized the octet rule to describe chemical bonding where atoms lose, gain, or share electrons in order to achieve a noble gas configuration.

Physical Chemistry

  • Matter is anything that has mass and occupies space.
  • Atomic size decreases across a period due to an increase in the effective nuclear charge (Zeff).
  • The radii of ions are not always smaller than the radii of the corresponding atoms of the same element.

General Chemistry

  • The correct formula for the dibromobis(oxalato)cobaltate(III) ion is not [Co(C2O4)Br2]3+.
  • The maximum oxidation state of an element in the first transition series never exceeds its group number.
  • In complexes of transition metals, the maximum coordination number of the metal is not equal to its number of d electrons.
  • A complex ion that undergoes a very slow exchange reaction is called an inert complex.

Isotopes and Radioactivity

  • Sn-50 is the most stable isotope among F-21, Kr-77, Po-210, and Sn-50.
  • Ernest Rutherford disproved J.J. Thomson's plum-pudding model of the atom by showing that positive matter is concentrated in the central core.
  • Avogadro's number is the number of atoms in 12g of Carbon-12.

Let me know if you'd like me to reorganize or clarify any of these points!### Acid-Base Reactions

  • Iron ions can act as acids or bases, depending on the definition used (Brønsted-Lowry, Lewis, or Arrhenius)
  • In the reaction Fe3+(aq) + 3H2O(l) → Fe(OH)3(s) + 3H+(aq), the iron ion is acting as an acid, accepting a pair of electrons from the oxygen

The Haber-Bosch Process

  • The Haber-Bosch process is used to produce ammonia (NH3) from nitrogen and hydrogen
  • The process involves two steps:
  • CH4(g) + H2O(g) → 2H2(g) + CO(g)
  • 3H2(g) + N2(g) → 2NH3(g)
  • Both steps are oxidation-reduction reactions

Galvanic Cells

  • The galvanic cell involves two half-reactions:
  • HSO4-(aq) + Pb(s) → H+(aq) + PbSO4(s) + 2e- (Eo = +0.35 V)
  • PbO2(s) + 3H+(aq) + HSO4-(aq) + 2e- → PbSO4(s) + 2H2O(l) (Eo = +1.46 V)
  • Increasing the concentration of sulfuric acid will increase the Ecell of the galvanic cell

Thermodynamics

  • The standard Gibbs Free Energy change (ΔG°rxn) can be calculated for a reaction
  • In the reaction CH3OH(l) + CO(g) → CH3COOH(l), ΔG°rxn = -86.0 kJ
  • Acetic acid is less thermodynamically stable than water at standard conditions

Enzyme Activity

  • Enzyme activity can be inhibited by the product of the reaction binding to the active site on the enzyme
  • This inhibition can be biologically useful in preventing over-production of the product

Semiconductors

  • Doping silicon with indium produces a p-type semiconductor
  • The indium has fewer valence electrons than silicon, producing positively charged "holes" in the electron structure

Atomic Theory

  • Isotopes are atoms of the same element that have different numbers of neutrons
  • The nucleus of an atom is composed of protons and neutrons
  • The charge of a proton is positive, while the charge of a neutron is neutral

Phase Changes

  • Sublimation is a phase change involving a substance changing from solid directly to gas
  • A phase diagram is a diagram depicting the phases of a substance at different temperatures and pressures

Solutions

  • The solubility of ionic compounds in water is mainly determined by ion-dipole forces
  • An alloy is an example of a solid-solid solution
  • Molarity is a concentration term that uses the volume of a solution

This quiz is based on the final exam questions and answers of Straighterline Chemistry course, covering various topics in chemistry. It's a comprehensive assessment of chemistry knowledge, suitable for students looking to pass with an A+ grade.

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