Quick Quiz on Carbohydrates and Haworth Projections

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Questions and Answers

How many different forms of a D-monosaccharide are present, at equilibrium, in an aqueous solution of the monosaccharide?

  • two
  • three (correct)
  • one
  • no correct response

Which of the following structures represents a beta-monosaccharide?

  • CH2OH HO -OOH OH OH OH HO OH (correct)
  • CH2OH HO - OOH OH OH OH
  • HOCH2 OH OH OH
  • no correct response

Which carbon atom, by number, is the anomeric carbon atom in the structure CH2OH -OOH?

  • carbon 4 (correct)
  • no correct response
  • carbon 2
  • carbon 3

The cyclic forms of an aldohexose are based on a ring system containing:

<p>5 C atoms and 1 O atom (D)</p> Signup and view all the answers

Which of the following types of monosaccharides have cyclic forms that involve a five-membered ring?

<p>aldopentoses and ketohexoses (C)</p> Signup and view all the answers

Who was Walter Norman Haworth and what was his contribution to chemistry?

<p>Walter Norman Haworth was a British carbohydrate chemist who developed Haworth projection formulas, helped determine the structures of cyclic forms of glucose, synthesized vitamin C, and was a co-recipient of the 1937 Nobel Prize in Chemistry.</p> Signup and view all the answers

A Haworth projection formula specifies the three-dimensional structure of a cyclic form of a ______.

<p>monosaccharide</p> Signup and view all the answers

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Study Notes

Quick Quiz on Carbohydrates

  • Equilibrium in aqueous solutions of D-monosaccharides presents three different forms.
  • The structure representing a beta-monosaccharide includes CH2OH, HO, -OOH, and OH groups.
  • The anomeric carbon in the specified structure is carbon 4.
  • The cyclic forms of an aldohexose consist of a ring system made up of 5 carbon atoms and 1 oxygen atom.
  • Aldopentoses and ketohexoses have cyclic forms that utilize a five-membered ring.

Walter Norman Haworth

  • Walter Norman Haworth (1883-1950) was a British carbohydrate chemist and developer of Haworth projection formulas.
  • He contributed significantly to the understanding of cyclic glucose structures.
  • First to synthesize vitamin C.
  • Shared the 1937 Nobel Prize in Chemistry for his work.

Haworth Projection Formulas

  • Ability to convert Fischer projection formulas to Haworth projection formulas is essential.
  • Haworth projection formulas provide a two-dimensional representation indicating the three-dimensional structure of cyclic monosaccharides.
  • In Haworth projections, the hemiacetal ring is viewed "edge on", with the oxygen atom positioned differently depending on ring size: at the upper right for six-membered rings and at the top for five-membered rings.

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