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Which form of D-glucose predominates in solution due to reduced steric hindrances?

  • Furanose form
  • Boat form
  • Chair form
  • Pyranose form (correct)
  • What is the ratio of β to α anomer conformations for D-glucose in an equilibrium solution?

  • 1:1
  • 2:1 (correct)
  • 1:2
  • 3:2
  • Which of the following best describes why D-glucose is an important fuel for most organisms?

  • It is exclusively used by aerobic organisms for energy.
  • It forms from nucleic acids and is readily available.
  • It is the only fuel used by brain and red blood cells in non-starvation conditions. (correct)
  • It is highly reactive and interacts with all cells.
  • Which statement about reducing sugars is correct?

    <p>All monosaccharides can adopt linear structures and are thus reducing sugars.</p> Signup and view all the answers

    What happens during mutarotation of cyclic sugars?

    <p>The sugar changes its specific rotation while reaching an equilibrium.</p> Signup and view all the answers

    Which form of glucose does not react with oxidizing agents?

    <p>Non-reducing sugars</p> Signup and view all the answers

    What is true about the chair and boat forms of β-D-glucose?

    <p>The chair form is more stable due to its less steric hindrance.</p> Signup and view all the answers

    Which of the following sugars is a known reducing sugar?

    <p>Fructose</p> Signup and view all the answers

    What is the empirical formula for carbohydrates?

    <p>(CH2O)n</p> Signup and view all the answers

    Which of the following describes the structural classification of monosaccharides?

    <p>They can be classified based on the number of carbon atoms and the type of most oxidized group.</p> Signup and view all the answers

    What is a constitutional isomer?

    <p>Molecules with identical molecular formulas that differ in how the atoms are ordered.</p> Signup and view all the answers

    How many carbon atoms can monosaccharides contain?

    <p>3 to 7</p> Signup and view all the answers

    Which type of monosaccharide is classified as a pentose?

    <p>A monosaccharide with five carbon atoms.</p> Signup and view all the answers

    What term is used to describe sugars that differ in configuration only at a single asymmetric center?

    <p>Epimers</p> Signup and view all the answers

    What happens to an aldehyde when it reacts with an alcohol?

    <p>It forms a hemiacetal.</p> Signup and view all the answers

    What is the role of the anomeric carbon in glucose?

    <p>It becomes an asymmetric center upon cyclic formation.</p> Signup and view all the answers

    Which of the following terms refers to diastereoisomers that are not mirror images of each other?

    <p>Diastereoisomers</p> Signup and view all the answers

    What type of cyclic structure is formed by sugars that resemble furan?

    <p>Furanose</p> Signup and view all the answers

    Study Notes

    Carbohydrates and Glycoproteins

    • Carbohydrates are carbon-based molecules with a high proportion of hydroxyl groups.
    • Their empirical formula is (CH2O)n, but they can have additional groups or modifications.
    • They are better described as polyhydroxy aldehydes and ketones.
    • Monosaccharides are the simplest carbohydrates and consist of three to seven carbons.
    • They are also called simple sugars.

    Monosaccharide Nomenclature

    • Nomenclature is based on carbon chain length:
      • Three carbons: trioses
      • Four carbons: tetroses
      • Five carbons: pentoses
      • Six carbons: hexoses
      • Seven carbons: heptoses
    • Nomenclature is also based on the identity of the most oxidized group:
      • Keto group: ketose
      • Aldehyde group: aldose

    Isomers

    • Constitutional Isomers: Molecules with identical molecular formulas but differ in the order of their atoms.
    • Stereoisomers: Molecules that differ in spatial arrangement but not bonding order.
      • They have either D or L configuration.
      • Can be enantiomers (mirror images of each other) or diastereoisomers (not mirror images of each other).
      • The number of possible stereoisomers is 2n, where n is the number of asymmetric carbon atoms.

    Common Monosaccharides

    • Epimers: Sugars that are diastereoisomers differing in configuration only at a single asymmetric center.

    Cyclic Forms of Monosaccharides

    • Most monosaccharides exist primarily in their ring forms.
    • An aldehyde can react with an alcohol to form a hemiacetal.
    • A ketone can react with an alcohol to form a hemiketal.

    Pyranose Formation

    • Occurs when a six-membered ring is formed.
    • Named after the compound pyran.

    Furanose Formation

    • Occurs when a five-membered ring is formed.
    • Named after the compound furan.

    Anomers of Glucose

    • Anomer: A diastereoisomeric form of sugars that forms when a cyclic hemiacetal forms and an additional asymmetric center is created.
    • In glucose, C-1 (the anomeric carbon atom) becomes an asymmetric center, forming two ring structures:
      • α-D-glucopyranose: Hydroxyl group attached to C-1 is on the opposite side of the ring as C-6.
      • β-D-glucopyranose: Hydroxyl group attached to C-1 is on the same side of the ring as C-6.

    D-Fructose Ring Structures

    • C-2 is the anomeric carbon atom.
    • The pyranose form predominates in solution due to reduced steric hindrances.
    • The furanose form predominates in fructose derivatives.

    Chair and Boat Forms of β-D-Glucose

    • The chair form predominates because all axial positions are occupied by hydrogens.
    • The boat form is disfavored because it is sterically hindered.

    D-Glucose as a Fuel

    • Blood Sugar: D-glucose circulating in the blood.
    • Used as the sole fuel by the brain (in non-starvation conditions) and red blood cells.
    • Potential reasons why D-glucose is an important fuel:
      • Glucose is formed from formaldehyde under prebiotic conditions and may have been available as a fuel source for primitive biochemical systems.
      • It is relatively inert.
      • The most stable ring structure is β-D-glucopyranose.

    Solutions of Glucose

    • Two anomeric forms (α and β) are in equilibrium that passes through the open-chain form.
    • The β anomer is more stable in solution.

    Reducing Sugars

    • Reducing Sugars: Sugars that react with oxidizing agents.
      • All monosaccharides can adopt linear structures in solution.
    • Non-Reducing Sugars: Sugars that do not react with oxidizing agents.
    • Fehling's solution: Solutions of Cu2+ used to test for the presence of reducing sugars.

    Mutarotation

    • The change in the specific rotation of a cyclic sugar as it reaches an equilibrium between its alpha and beta anomeric forms.

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