Physical Properties of Ionic Compounds

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Questions and Answers

What is the arrangement of ions in ionic compounds called?

  • Ionic grid
  • Crystal lattice (correct)
  • Molecular structure
  • Covalent form

What accounts for the high melting and boiling points of ionic compounds?

  • Strong covalent bonds
  • Weak van der Waals forces
  • Low ionization energies
  • Strong electrostatic forces (correct)

Which statement about the crystal forms of ionic compounds is true?

  • They vary between different ionic compounds. (correct)
  • They all have the same crystal structure.
  • They cannot form geometric shapes.
  • They only form in solid states.

What type of energy is primarily involved in holding the ions in a crystal lattice together?

<p>Electrostatic energy (D)</p> Signup and view all the answers

What observable physical change can indicate the melting of an ionic compound?

<p>Bubbling and steam production (A)</p> Signup and view all the answers

In what state do ionic compounds conduct electricity?

<p>In aqueous solution (A)</p> Signup and view all the answers

What term describes ionic substances that can conduct electricity when dissolved in water?

<p>Electrolytes (A)</p> Signup and view all the answers

Why do solid ionic compounds not conduct electricity?

<p>Their ions are fixed in place. (D)</p> Signup and view all the answers

What is a characteristic property of ionic compounds in solid form?

<p>They behave as electrical insulators. (B)</p> Signup and view all the answers

What happens to cations and anions when ionic compounds dissolve in water?

<p>They are dissociated and free to move. (D)</p> Signup and view all the answers

What is a characteristic of covalent compounds concerning their melting and boiling points?

<p>They tend to have low melting and boiling points. (A)</p> Signup and view all the answers

Why are covalent compounds often found in gas or liquid form at room temperature?

<p>Their intermolecular forces are relatively weak, making them soft and flexible. (A)</p> Signup and view all the answers

What is a characteristic property of ionic compounds?

<p>They form crystalline structures. (A)</p> Signup and view all the answers

What explains the softness and flexibility of covalent compounds?

<p>Covalent bonds are relatively flexible and easy to break. (D)</p> Signup and view all the answers

Ionic compounds generally dissolve well in which type of solvent?

<p>Water (C)</p> Signup and view all the answers

How do intermolecular forces in covalent compounds compare to those in ionic compounds?

<p>They are generally weaker than those in ionic compounds. (B)</p> Signup and view all the answers

What phase of matter is least likely to be represented by covalent compounds at room temperature?

<p>Plasma (A)</p> Signup and view all the answers

Which of the following statements about the electrical conductivity of ionic compounds is true?

<p>Ionic compounds conduct electricity when dissolved in water. (D)</p> Signup and view all the answers

How do ionic compounds typically respond to heat?

<p>They melt without breaking down. (A)</p> Signup and view all the answers

What describes the texture of solid ionic compounds?

<p>They have a brittle crystalline structure. (B)</p> Signup and view all the answers

What causes ionic compounds to be hard?

<p>Strong electrostatic attraction between ions (B)</p> Signup and view all the answers

What happens to ionic compounds when pressure is applied?

<p>Same charge ions move closer and repel each other (C)</p> Signup and view all the answers

Why are ionic compounds described as brittle?

<p>Applying force disrupts the ionic structure (A)</p> Signup and view all the answers

What characteristic of ionic compounds is illustrated by a broken chocolate bar?

<p>Brittleness (C)</p> Signup and view all the answers

What contributes to the rigidity of solid ionic compounds?

<p>Strong ionic bonds and structured lattice (B)</p> Signup and view all the answers

What characteristic is generally associated with covalent compounds?

<p>Poor electrical conductivity (C)</p> Signup and view all the answers

Which of the following properties is NOT commonly seen in covalent compounds?

<p>Good ionic conduction (B)</p> Signup and view all the answers

Covalent compounds typically exist in which of the following states at room temperature?

<p>Both solid and liquid (C)</p> Signup and view all the answers

How do the intermolecular forces in covalent compounds usually compare to those in ionic compounds?

<p>Weaker in covalent compounds (A)</p> Signup and view all the answers

Which of the following describes the conductivity of covalent compounds?

<p>They do not conduct electricity in any state. (C)</p> Signup and view all the answers

What defines the polarity of covalent molecules?

<p>The differences in the electronegativity of the bonded atoms (A)</p> Signup and view all the answers

Which of the following is an example of a polar covalent compound?

<p>Dichloromethane (CHâ‚‚Clâ‚‚) (A)</p> Signup and view all the answers

Covalent compounds can be classified into which two categories?

<p>Polar and Nonpolar (D)</p> Signup and view all the answers

Which of the following statements about covalent compounds is incorrect?

<p>They can only be nonpolar. (A)</p> Signup and view all the answers

In the context of covalent compounds, what is true about nonpolar molecules?

<p>They have a symmetrical distribution of electron density. (C)</p> Signup and view all the answers

What does the electronegativity value represent for an element?

<p>The tendency of an atom to attract electrons (B)</p> Signup and view all the answers

Which of the following elements has the lowest electronegativity value?

<p>Lithium (Li) (A)</p> Signup and view all the answers

Electronegativity values are typically rounded to how many decimal places?

<p>One decimal place (D)</p> Signup and view all the answers

Which group of elements would likely have higher electronegativity values?

<p>Halogens (B)</p> Signup and view all the answers

Which of the following is represented by the symbol 'F' in the electronegativity table?

<p>Fluorine (C)</p> Signup and view all the answers

What determines if a bond is polar or nonpolar?

<p>Electronegativity difference (B)</p> Signup and view all the answers

How does electronegativity change across a period in the periodic table?

<p>It increases (B)</p> Signup and view all the answers

What type of bond forms when electrons are shared equally between two atoms?

<p>Nonpolar covalent bond (D)</p> Signup and view all the answers

What happens to electronegativity as you move down a group in the periodic table?

<p>It decreases (D)</p> Signup and view all the answers

What characterizes a polar covalent bond?

<p>Unequal sharing of electrons (B)</p> Signup and view all the answers

What is a key characteristic of the flammability of covalent compounds compared to ionic compounds?

<p>Covalent compounds are significantly more flammable than ionic compounds. (A)</p> Signup and view all the answers

What products are formed when a covalent compound undergoes combustion?

<p>Carbon dioxide and water (D)</p> Signup and view all the answers

Why do covalent compounds not conduct electricity when dissolved in water?

<p>They do not dissociate into ions. (A)</p> Signup and view all the answers

Which statement is true regarding the conductivity of covalent compounds?

<p>Covalent compounds do not conduct electricity when dissolved in water. (A)</p> Signup and view all the answers

Which of the following best describes the behavior of covalent compounds in combustion reactions?

<p>They release energy when reacting with oxygen. (C)</p> Signup and view all the answers

Flashcards

Electrical Conductivity of Ionic Compounds (liquid)

When ionic compounds dissolve in water, the ions separate and can carry current, making the solution conductive.

Electrical Conductivity of Ionic Compounds (solid)

Solid ionic compounds do not conduct electricity; they are insulators.

Electrolyte

An ionic substance that conducts electricity when dissolved in water.

Insulator

A material that does not allow electric current to flow easily.

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Dissociation of ions

Separation of cations and anions when an ionic compound dissolves in water.

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Ionic Compounds

Substances formed by ions held together by electrostatic forces.

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Physical Properties

Characteristics that can be observed without changing the substance's identity.

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High Melting Points

Ionic compounds typically require significant energy to break the strong bonds.

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Solubility in Polar Solvents

Ionic compounds tend to dissolve easily in water or other polar solvents.

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Electrical Conductivity

Ionic compounds conduct electricity when molten or dissolved.

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Ionic compound hardness

Solid ionic compounds are hard because of strong electrostatic attraction between ions.

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Ionic compound brittleness

Ionic compounds break easily when pressure/force is applied.

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Electrostatic attraction

The strong force that holds ions together in an ionic compound.

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Electrostatic repulsion

The force that pushes ions with the same charge apart.

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Brittleness in ionic compounds

The tendency of ionic compounds to break under stress due to repulsion of like charges.

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Covalent Compounds

Molecules formed by sharing electrons between atoms.

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Melting point

The temperature at which a solid changes to a liquid.

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Boiling point

The temperature at which a liquid changes to a gas.

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Solubility

The ability of a substance to dissolve in a solvent.

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Crystal Lattice

A regular, geometric arrangement of ions in an ionic compound. Different compounds have different lattice structures.

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Electrostatic Force

The strong attraction between oppositely charged ions in a crystal lattice, holding them together.

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High Boiling Point

Similar to melting, breaking the ionic bonds to turn a solid into a gas requires a lot of energy, resulting in high boiling points.

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Why are ionic compounds hard?

Ionic compounds are hard due to the strong electrostatic forces holding the ions in a rigid crystal lattice.

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Polar Covalent Bond

A covalent bond where electrons are shared unequally, resulting in a slightly positive and slightly negative end of the molecule.

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Nonpolar Covalent Bond

A covalent bond where electrons are shared equally between atoms, resulting in no overall charge separation.

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Electronegativity

The ability of an atom in a molecule to attract shared electrons towards itself.

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Polar Molecule

A molecule that has a positive and negative end due to unequal sharing of electrons in its covalent bonds.

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Nonpolar Molecule

A molecule where electrons are shared equally, resulting in no overall charge separation.

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Covalent Compounds: Melting/Boiling Points

Covalent compounds often have low melting and boiling points because the intermolecular forces (attraction between molecules) are weak, even though the covalent bonds within the molecules are strong.

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Covalent Compounds: Flexibility

Covalent compounds are often soft and flexible because the bonds between atoms are relatively easy to break. This allows molecules to slide past each other.

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Covalent Compounds: States at Room Temp

Covalent compounds are often found as gases, liquids, or soft solids at room temperature due to their weak intermolecular forces.

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Intermolecular Forces

These are the forces of attraction between molecules in a covalent compound. They are weaker than the covalent bonds within the molecules.

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Why Low Melting/Boiling Points?

The weak intermolecular forces in covalent compounds require less energy to overcome, leading to lower melting and boiling points compared to compounds with strong intermolecular forces.

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Electronegativity Trend

Electronegativity increases across a period and decreases down a group on the periodic table.

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How to Predict Bond Type

Compare the electronegativity values of the atoms involved. A large difference indicates a polar covalent bond, while a small difference suggests a nonpolar covalent bond.

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Periodic Table Trend

Electronegativity generally increases across a period (from left to right) and decreases down a group (from top to bottom) on the periodic table.

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What does a high EN value mean?

A high electronegativity value indicates that an atom strongly attracts electrons in a covalent bond. This leads to a more polar bond.

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What does a low EN value mean?

A low electronegativity value indicates that an atom weakly attracts electrons in a covalent bond. This leads to a less polar bond.

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EN and Bond Types

The difference in electronegativity values between two bonded atoms determines the type of bond (ionic, polar covalent, nonpolar covalent).

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Flammability of Covalent Compounds

Covalent compounds tend to be more flammable than ionic compounds because they react with oxygen to produce energy, releasing carbon dioxide and water.

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Combustion reaction

A chemical reaction that releases energy when a substance reacts with oxygen, typically producing carbon dioxide and water.

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Why are covalent compounds non-conductive in solution?

Covalent compounds dissolve as molecules, not ions. Since they don't have free-moving charged particles, they can't conduct electricity.

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How do covalent compounds differ from ionic compounds in conductivity?

Ionic compounds conduct electricity when dissolved because they form ions. Covalent compounds don't form ions, so they don't conduct.

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What's the key difference in how covalent and ionic compounds dissolve?

Covalent compounds dissolve as molecules, maintaining their original structure. Ionic compounds break apart into ions.

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Study Notes

Physical Properties of Ionic Compounds

  • Ionic compounds form crystals
  • Ions are arranged in a regular, geometric structure called a crystal lattice
  • Different ionic compounds have different crystal forms
  • Ionic compounds have high melting and boiling points
  • Ions in a crystal lattice are closely packed together
  • Close packing creates a strong electrostatic force of attraction between the ions
  • Ionic compounds are hard and brittle
  • Applying pressure or mechanical force causes ions with the same charge to move closer, resulting in electrostatic repulsion
  • When ionic compounds are dissolved in water (liquid form), they form an aqueous solution
  • The cations and anions are dissociated, or separated, and are free to conduct electricity through the solution
  • These ionic substances that conduct electricity are referred to as electrolytes
  • Solid form ionic compounds do not conduct electricity, instead they are good insulators

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