Lec 2 | Six-membered ring system
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Questions and Answers

What are some examples of three-membered heterocyclic rings mentioned in the text?

  • Epoxides and carbonyl groups
  • Aziridines and alkenes
  • Carboxylic acids and alcohols
  • Epoxides and aziridines (correct)
  • Which type of compounds are resistant toward alkali but easily cleaved by acid according to the text?

  • Esters formed with dihydropyran (correct)
  • Amines formed with sulfonium ions
  • Alkenes formed with halonium ions
  • Alcohols formed with epoxides
  • What is a common method mentioned in the text to mask carboxyl groups?

  • Reaction with dihydropyran (correct)
  • Reaction with chlorophyll
  • Reaction with THP esters
  • Reaction with halonium ions
  • What biological compounds are highlighted as being heterocyclic in the text?

    <p>Carbohydrates and chlorophyll</p> Signup and view all the answers

    In biological systems, which compounds are described as making leaves green and blood red?

    <p>Chlorophyll and hemin</p> Signup and view all the answers

    What is emphasized as the ultimate determinant of heredity according to the text?

    <p>The sequence of attachment of heterocyclic rings to nucleic acids</p> Signup and view all the answers

    Which kind of compounds contain rings made up of more than one kind of atom?

    <p>Heterocyclic compounds</p> Signup and view all the answers

    In heterocyclic compounds, what are the most commonly found atoms in addition to carbon?

    <p>Nitrogen, Oxygen, or Sulfur</p> Signup and view all the answers

    What do heteroatoms in a heterocyclic compound generally receive in terms of numbering the ring positions?

    <p>The lowest possible numbers</p> Signup and view all the answers

    Which of the following is an example of a cyclic anhydride encountered in heterocyclic compounds?

    <p>Succinic anhydride</p> Signup and view all the answers

    What type of compounds are lactones and lactams classified as in heterocyclic chemistry?

    <p>Cyclic esters and cyclic amides</p> Signup and view all the answers

    Which solvent is mentioned as an example of a cyclic acetal of dihydroxy alcohols?

    <p>$ ext{C}<em>4 ext{H}</em>{10} ext{O}_2$</p> Signup and view all the answers

    Which term describes rings made up only of carbon atoms in cyclic compounds?

    <p>Homocyclic</p> Signup and view all the answers

    Which heteroatoms are commonly found in rings of heterocyclic compounds?

    <p>Oxygen and Sulfur</p> Signup and view all the answers

    What do heteroatoms typically receive in the numbering of ring positions in heterocyclic compounds?

    <p>Lowest possible numbers</p> Signup and view all the answers

    Which type of compounds are succinic anhydride and phthalimide examples of?

    <p>Cyclic Anhydrides</p> Signup and view all the answers

    What is the chemistry of cyclic esters and cyclic amides essentially similar to?

    <p>Open chain analogs</p> Signup and view all the answers

    Which compound is emphasized in the text as being a cyclic acetal of dihydroxy alcohols?

    <p>Dioxane</p> Signup and view all the answers

    Which statement about heterocyclic intermediates is true according to the text?

    <p>They are being increasingly utilized as temporary protecting groups in organic synthesis.</p> Signup and view all the answers

    What is the significance of heterocyclic compounds in biological systems as highlighted in the text?

    <p>All of the above.</p> Signup and view all the answers

    Which statement about the reactivity of three-membered heterocyclic rings is correct according to the text?

    <p>They are highly reactive due to the presence of ring strain.</p> Signup and view all the answers

    Which type of heterocyclic compound is mentioned as being resistant to base but easily cleaved by acid?

    <p>Tetrahydropyranyl (THP) esters</p> Signup and view all the answers

    Which of the following heterocyclic compounds is NOT mentioned in the text as an example?

    <p>$\beta$-Lactams</p> Signup and view all the answers

    What is the purpose of masking carboxyl groups with dihydropyran as mentioned in the text?

    <p>To protect the carboxyl group during synthetic transformations.</p> Signup and view all the answers

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