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Questions and Answers
What is the composition of the anode and cathode in a Nickel-Cadmium (NICAD) battery?
What is the composition of the anode and cathode in a Nickel-Cadmium (NICAD) battery?
The anode is cadmium and the cathode is nickel oxide (NiO2).
What is the electrolyte in a Nickel-Cadmium (NICAD) battery?
What is the electrolyte in a Nickel-Cadmium (NICAD) battery?
The electrolyte is a solution of KOH.
What is the cell voltage of a Nickel-Cadmium (NICAD) battery?
What is the cell voltage of a Nickel-Cadmium (NICAD) battery?
The cell voltage is fairly constant at about 1.4 volts.
What is the working principle of a Nickel-Cadmium (NICAD) battery during discharging?
What is the working principle of a Nickel-Cadmium (NICAD) battery during discharging?
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What is the overall reaction during charging of a Nickel-cadmium battery?
What is the overall reaction during charging of a Nickel-cadmium battery?
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What are the advantages of a Nickel-cadmium battery?
What are the advantages of a Nickel-cadmium battery?
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What are the disadvantages of a Nickel-cadmium battery?
What are the disadvantages of a Nickel-cadmium battery?
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How can the Nickel-cadmium battery be recharged?
How can the Nickel-cadmium battery be recharged?
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How does the energy density of a metal hydride electrode compare to a cadmium electrode in nickel-metal hydride batteries?
How does the energy density of a metal hydride electrode compare to a cadmium electrode in nickel-metal hydride batteries?
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What is the environmental advantage of nickel-metal hydride batteries over nickel-cadmium batteries?
What is the environmental advantage of nickel-metal hydride batteries over nickel-cadmium batteries?
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What are the uses of nickel-cadmium batteries?
What are the uses of nickel-cadmium batteries?
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What are the main components of a nickel-metal hydride battery?
What are the main components of a nickel-metal hydride battery?
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Study Notes
Nickel-Cadmium (NICAD) Battery
Composition
- Anode: Cadmium oxide (CdO)
- Cathode: Nickel oxide hydroxide (NiOx)
Electrolyte
- Potassium hydroxide (KOH) solution
Cell Voltage
- 1.2V per cell
Working Principle
- During discharging, the nickel oxide hydroxide (cathode) releases electrons, while the cadmium oxide (anode) absorbs electrons
Overall Reaction
- During charging, the reaction is reversed: nickel oxide hydroxide (cathode) absorbs electrons, and cadmium oxide (anode) releases electrons
Advantages
- High discharge rate capability
- Long cycle life
- Low self-discharge rate
- Relatively low cost
Disadvantages
- Toxic chemistry (cadmium)
- Memory effect (reduced capacity if not fully discharged before recharging)
- Low energy density
Recharging
- Can be recharged hundreds of times
- Rechargeable by applying an external electrical potential to reverse the chemical reaction
Nickel-Metal Hydride (NiMH) Battery
Energy Density
- Metal hydride electrode has a higher energy density compared to a cadmium electrode
Environmental Advantage
- Less toxic than nickel-cadmium batteries
- More environmentally friendly
Uses
- Portable devices (e.g., cordless phones, cameras)
- Electric vehicles
- Renewable energy systems
Main Components
- Positive electrode: Nickel oxide hydroxide (NiOx)
- Negative electrode: Hydrogen-absorbing alloy (e.g., LaNi5)
- Electrolyte: Potassium hydroxide (KOH) solution
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Description
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