Lead Acid Battery: Advantages and Disadvantages
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Questions and Answers

What is the composition of the anode and cathode in a Nickel-Cadmium (NICAD) battery?

The anode is cadmium and the cathode is nickel oxide (NiO2).

What is the electrolyte in a Nickel-Cadmium (NICAD) battery?

The electrolyte is a solution of KOH.

What is the cell voltage of a Nickel-Cadmium (NICAD) battery?

The cell voltage is fairly constant at about 1.4 volts.

What is the working principle of a Nickel-Cadmium (NICAD) battery during discharging?

<p>The NICAD battery operates when cadmium is oxidized to Cd2+ ions and insoluble Cd (OH)2 is formed. Ni2+ ions then combine with OH- ions to form Ni (OH)2.</p> Signup and view all the answers

What is the overall reaction during charging of a Nickel-cadmium battery?

<p>Cd(s) + 2NiO2(s) + 2H2O(l) ightarrow Cd(OH)2(s) + 2Ni(OH)2(s)</p> Signup and view all the answers

What are the advantages of a Nickel-cadmium battery?

<p>Longer life than lead storage cell, available in a wide range of sizes, good load performance, compact and lighter, can be packed and sealed, lowest cost in terms of cost per cycle</p> Signup and view all the answers

What are the disadvantages of a Nickel-cadmium battery?

<p>Very expensive, cadmium is highly toxic, relatively low energy density, relatively high self-discharge</p> Signup and view all the answers

How can the Nickel-cadmium battery be recharged?

<p>By passing an excess current in the opposite direction to that of the cell current</p> Signup and view all the answers

How does the energy density of a metal hydride electrode compare to a cadmium electrode in nickel-metal hydride batteries?

<p>A higher energy density can be achieved with a metal hydride electrode compared to a cadmium electrode.</p> Signup and view all the answers

What is the environmental advantage of nickel-metal hydride batteries over nickel-cadmium batteries?

<p>Nickel-metal hydride batteries are considered more environmentally friendly as they are free of Cd, reducing disposal problems associated with rechargeable nickel batteries.</p> Signup and view all the answers

What are the uses of nickel-cadmium batteries?

<p>Emergency power applications, communication equipment, electronic calculators, electronic flash units, transistors, battery powered small tools, aircraft, and space satellites.</p> Signup and view all the answers

What are the main components of a nickel-metal hydride battery?

<p>Positive plate of highly porous sintered or felt nickel substrate impregnated with nickel hydroxide, negative plate using a perforated LaNi 5 alloy grid.</p> Signup and view all the answers

Study Notes

Nickel-Cadmium (NICAD) Battery

Composition

  • Anode: Cadmium oxide (CdO)
  • Cathode: Nickel oxide hydroxide (NiOx)

Electrolyte

  • Potassium hydroxide (KOH) solution

Cell Voltage

  • 1.2V per cell

Working Principle

  • During discharging, the nickel oxide hydroxide (cathode) releases electrons, while the cadmium oxide (anode) absorbs electrons

Overall Reaction

  • During charging, the reaction is reversed: nickel oxide hydroxide (cathode) absorbs electrons, and cadmium oxide (anode) releases electrons

Advantages

  • High discharge rate capability
  • Long cycle life
  • Low self-discharge rate
  • Relatively low cost

Disadvantages

  • Toxic chemistry (cadmium)
  • Memory effect (reduced capacity if not fully discharged before recharging)
  • Low energy density

Recharging

  • Can be recharged hundreds of times
  • Rechargeable by applying an external electrical potential to reverse the chemical reaction

Nickel-Metal Hydride (NiMH) Battery

Energy Density

  • Metal hydride electrode has a higher energy density compared to a cadmium electrode

Environmental Advantage

  • Less toxic than nickel-cadmium batteries
  • More environmentally friendly

Uses

  • Portable devices (e.g., cordless phones, cameras)
  • Electric vehicles
  • Renewable energy systems

Main Components

  • Positive electrode: Nickel oxide hydroxide (NiOx)
  • Negative electrode: Hydrogen-absorbing alloy (e.g., LaNi5)
  • Electrolyte: Potassium hydroxide (KOH) solution

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Description

Explore the advantages and disadvantages of lead acid batteries, including their usage in automobiles and the environmental impact of recycling. Learn about the challenges associated with low temperatures and mechanical strain, as well as the limitations in energy density for handheld devices.

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