Ions, Valence Electrons, and Ionic Compounds
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Questions and Answers

Explain the relationship between valence electrons and the octet rule in the formation of ions.

Atoms gain or lose valence electrons to achieve a full outer shell (octet), resulting in a stable ion with a noble gas electron configuration.

Considering the properties of ionic compounds, why are they typically solids at room temperature, while molecular compounds can be gases, liquids, or solids?

Ionic compounds have strong electrostatic attractions between ions, requiring more energy to break, hence higher melting points and solid-state at room temperature.

How does the chemical formula of an ionic compound, such as $MgCl_2$, reflect the electrical neutrality of the compound?

The ratio of Mg to Cl ensures that the total positive charge from the magnesium ions ($Mg^{2+}$) equals the total negative charge from the chloride ions ($Cl^−$), resulting in a neutral compound.

Explain why a polyatomic ion acts as a single unit in forming ionic compounds.

<p>The atoms within a polyatomic ion are covalently bonded and share charge density, resulting in it carrying an overall charge and behaving as a single charged entity.</p> Signup and view all the answers

If element X readily forms a 2+ cation and element Y readily forms a 1- anion, what is the most likely chemical formula of the ionic compound formed between X and Y?

<p>The most likely chemical formula is $XY_2$, ensuring charge neutrality where two Y anions balance the 2+ charge of the X cation.</p> Signup and view all the answers

Describe how the formation of a cation and an anion leads to the formation of an ionic bond.

<p>A cation donates electrons to form an anion to get to a full valence shell which creates opposite charges. Because opposite charges attract each other in this way, it creates an ionic bond.</p> Signup and view all the answers

How does the number of valence electrons in an atom relate to its tendency to form an ionic bond?

<p>Atoms with few valence electrons tend to lose them to form cations, while atoms with nearly full valence shells tend to gain electrons to form anions, both resulting in stable ionic bonds.</p> Signup and view all the answers

Explain why ionic compounds conduct electricity when dissolved in water but not in their solid-state.

<p>In the solid-state, ions are fixed in a lattice; when dissolved, ions are mobile and can carry charge, thus conducting electricity.</p> Signup and view all the answers

Flashcards

What is a cation?

A positively charged ion formed by losing electrons.

What is an anion?

A negatively charged ion formed by gaining electrons.

Valence Electrons

Electrons in the outermost energy level of an atom.

Octet Rule Definition

Atoms gain, lose, or share electrons to achieve a full outer shell (8 electrons).

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Ionic Bond

Electrostatic attraction between oppositely charged ions.

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Ionic vs. Molecular Formula

Ionic compounds typically start with a metal or ammonium ($NH_4^+$).

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Polyatomic Ion

A group of atoms covalently bonded together that have an overall charge.

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Ionic Formula Meaning

The ratio of cations to anions in the crystal lattice.

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Study Notes

  • A neutral atom loses one or more electrons, forming a cation
  • A calcium atom becomes a calcium cation by losing two electrons: Ca -> Ca2+ + e- + e-
  • A neutral atom gains one or more electrons, forming an anion
  • An oxygen atom becomes an oxide anion by gaining two electrons: O + e- + e- -> O2-
  • Valence electrons are higher in energy and in the outermost occupied energy level, but otherwise, the same charge and mass as any other electron
  • Number of valence electrons in a neutral atom
  • Na: 1
  • N: 5
  • Ar: 8
  • Mg: 2
  • S: 6
  • Cl: 7
  • Predicted charge of an atom based on the octet rule
  • Na: 1+
  • N: 3-
  • Ar: 0
  • Mg: 2+
  • S: 2-
  • Cl: 1-
  • Ionic bonds hold atoms together because oppositely charged cations and anions attract one another
  • Ionic compounds show a metal (or NH4+) ion at the beginning, while molecular compounds show only 2 nonmetals
  • A polyatomic ion is multiple atoms, bonded together, that function as an individual ion
  • The chemical formula for an ionic compound tells the ratio of cations to anions in the larger crystal lattice structure
  • Ionic compounds are electrically neutral because the ratio of cations to anions will always be such that the positive charges exactly cancel the negatives
  • A compound that is a liquid at room temperature, has a melting point of -25°C, and does not conduct electricity is most likely made of molecules because its low melting point suggests that it is not a solid at room temperature

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Explore ion formation through electron gain or loss, creating cations and anions. Understand valence electrons, their role in bonding, and predicting ionic charges using the octet rule. Learn about ionic bonds and how to identify ionic compounds.

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