Glycerol Reactions Chemistry Quiz
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Questions and Answers

What product is formed when glycerol reacts with dilute HNO3?

  • Trinitroglycerol
  • Glycerolmonooxalate
  • Glyceraldehyde
  • Glyceric acid (correct)
  • Which of the following reactions produces glycerol dioxalate?

  • Reaction of glycerol with Bismuth Nitrate
  • Allyl iodide plus excess H+
  • Heating glycerol with hot and acidified KMnO4 solution
  • Heating glycerol at 220°C under elevated pressure (correct)
  • What is the product of the reaction between glycerol and concentrated HNO3?

  • Trinitroglycerol (TNG) (correct)
  • Glyceraldehyde
  • Acrolein
  • Allyl alcohol
  • What type of compound is produced when glycerol undergoes oxidation with hot, acidified KMnO4 solution?

    <p>Oxalic acid</p> Signup and view all the answers

    Which chemical structure corresponds to the product formed from the reaction of glycerol and PCl5?

    <p>CH-CH-CH3</p> Signup and view all the answers

    Study Notes

    Reactions of Glycerol

    • Oxidation with Dilute HNO3: Glycerol reacts with dilute nitric acid to form glyceric acid and tartaric acid.
    • Oxidation with Fe/H2O2: This reaction yields glyceraldehyde and dihydroxyacetone.
    • Oxidation with Bismuth nitrate/Acid: Results in mesoxalic acid formation.
    • Oxidation with Hot Acidified KMnO4: Forms oxalic acid.
    • Glycerol Dioxalate Formation: Via reaction with excess oxalic acid.
    • Dehydration Reactions (220°C): This process results in the formation of allyl alcohol and carbon dioxide as byproducts.
    • Reaction with H2/I2: Lead to allyl iodide.
    • Reaction with Excess H2I2: Yields isopropyl iodide.
    • Reaction with Concentrated HNO3: Produces trinitroglycerine (TNG) or nitroglycerin.
    • Reaction with Concentrated H2SO4: Results in acrolein production if acidified.
    • Reaction with Phosphorus trichloride (PCl3): Forms 1,2,3-trichloropropane

    Preparation and Reactions of Glycerol (Continued)

    • Preparation method using ethylene bromide: Results in ethyleneacetate, through a series of reactions, including reagents like Ag/catalyst, conc. H2SO4/Heat, and NaHSO4.
    • Preparation Method using ethylene bromide: Results in ethyleneacetate, through a series of reactions, including reagents like Ag/catalyst, conc. H2SO4/Heat, and NaHSO4.
    • Formation of Glycollic acid: From reaction with [O], which denotes an oxidizing agent.
    • Preparation of Glyoxalic Acid: Reaction with [O] to form glyoxal, then further reaction with [O] producing glyoxalic acid.
    • Reaction with formaldehyde, Hio4, and other reagents: Leads to cyclic acetal formations as intermediates during respective reaction conditions.
    • Reaction with acidified KMnO4: Leads to the formation of oxalic acid.

    Additional Information on Glycerol

    • Glycerol is a trihydroxy alcohol.
    • It is a colorless, viscous liquid.
    • It has a boiling point of 290°C.
    • It's used as an antifreeze and de-icing fluid.
    • It's a monomer in certain polymers.

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    Description

    Test your knowledge on the various reactions of glycerol, including oxidation processes with different reagents and conditions. This quiz covers fundamental concepts in organic chemistry, focusing on the transformation of glycerol into various products. Enhance your understanding of glycerol chemistry through interactive learning.

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