Glycol and Glycerol Reactions PDF
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This document provides a detailed description of the reactions of glycol and glycerol, presenting the chemical formulas and processes with step-by-step instructions. Includes specific reaction conditions. It's suitable for chemistry study at the undergraduate level.
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## Reactions of glycerol **(glycerol)** ### Dilute HNO3 - COOH - CHOH - CH2OH **Glyceric acid** ### Fe/H2O2 - CHO - CHOH - CH2OH **Glyceraldehyde** ### Bismuth Nitrate/A - COOH - C=O - COOH - (mesoxalic acid) ### Hot & acidified KMnO4 solution - COOH - COOH - (oxalic acid) ### 110°C - COO...
## Reactions of glycerol **(glycerol)** ### Dilute HNO3 - COOH - CHOH - CH2OH **Glyceric acid** ### Fe/H2O2 - CHO - CHOH - CH2OH **Glyceraldehyde** ### Bismuth Nitrate/A - COOH - C=O - COOH - (mesoxalic acid) ### Hot & acidified KMnO4 solution - COOH - COOH - (oxalic acid) ### 110°C - COOH - CH2 - O -C-C-OH - CHOH - CH2OH **Glycerolmonooxalate** ### 220°C/Δ - COOH - CH2OH - CHOH - CH2OH **Glycerol dioxalate** ### H2O/H+ - CH2-O-C-H - CH-O-C-H - CH2OH - CO2 - CHO-C=O - CHOH - CH2OH - 2CO2 - CH2=CH-CH2OH **Allyl alcohol** ### CH2=CH-CH2-I **Allyl iodide** ### excess of H+ - CH-CH-CH3 **(Via Allyl iodide and Propene)** ### Conc. HNO3 - CH2-ONO2 - CH-ONO2 - CH2-ONO2 **trinitroglycerol (TNG)** ### conc. H2SO4/Δ - CH2=CH-CH=O **Acrolein** ### PCl5 - CH-CH-CH - ClClCl #### Preparation and reactions of Glycerol - CH2-OH - CH-OH - CH2-OH - CH2-Cl - CH-Cl - CH2-Cl - CH2-CH2 - CH-CH2 - CH2-CH2 - CH2-OCOCH3 - CH-OCOCH3 - CH2-OCOCH3 - CH2-OH - CH=O - COOH - CH2OH - CH-OH - CH2OH - CHO - COOH - CH2OH - CHOH - CH2OH - CH2 - CH2 - HO-CH2-CH2-O-CH2-CH2-OH #### Glycerol - It is trihydroxy alcohols having one 2º alcohol and two 1º alcohol groups. It is colourless viscous hygroscopic, non-toxic liquid with boiling point 290° #### Preparation
