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Questions and Answers
What percentage of the total world fisheries and aquaculture production did molluscs comprise in 2019?
What percentage of the total world fisheries and aquaculture production did molluscs comprise in 2019?
How much did the total world fisheries and aquaculture production expand from 2000 to 2019?
How much did the total world fisheries and aquaculture production expand from 2000 to 2019?
What is the approximate percentage of mollusc shells that are represented by oyster, clam, scallop, and mussel shells?
What is the approximate percentage of mollusc shells that are represented by oyster, clam, scallop, and mussel shells?
What is the primary mode of disposal of shells?
What is the primary mode of disposal of shells?
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What is the consequence of uncontrolled disposal of shells?
What is the consequence of uncontrolled disposal of shells?
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Why do shells become waste in low-income countries?
Why do shells become waste in low-income countries?
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At what stage can shells be detached from flesh?
At what stage can shells be detached from flesh?
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How much waste crab, shrimp, and lobster shells are produced globally each year?
How much waste crab, shrimp, and lobster shells are produced globally each year?
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What is the role of crushed oyster shells in biological nitrification and ammonia removal?
What is the role of crushed oyster shells in biological nitrification and ammonia removal?
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What is the application of soft calcite prepared from waste blue mussel shells?
What is the application of soft calcite prepared from waste blue mussel shells?
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What is the result of demineralization and deproteination of crustacean shells?
What is the result of demineralization and deproteination of crustacean shells?
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What is the application of chitin and chitosan in water treatment?
What is the application of chitin and chitosan in water treatment?
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What is the effect of calcination on the heavy metal removal efficiency of shells?
What is the effect of calcination on the heavy metal removal efficiency of shells?
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What is the effect of shell powder on contaminated water?
What is the effect of shell powder on contaminated water?
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What is the effect of calcined shells on soil pH?
What is the effect of calcined shells on soil pH?
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What is the effect of applying calcined oyster shells to agricultural soil?
What is the effect of applying calcined oyster shells to agricultural soil?
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What is the effect of crushed mussel shell on copper-rich vineyard and mine soils?
What is the effect of crushed mussel shell on copper-rich vineyard and mine soils?
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What can crushed mollusc shells be used as a replacement for in soil amendment?
What can crushed mollusc shells be used as a replacement for in soil amendment?
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What is the main cause of acid mine drainage (AMD)?
What is the main cause of acid mine drainage (AMD)?
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What is the effect of acid mine drainage on aquatic environment?
What is the effect of acid mine drainage on aquatic environment?
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What is the role of biomaterials in treating acid mine drainage?
What is the role of biomaterials in treating acid mine drainage?
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What is the potential of constructed wetlands in treating acid mine drainage?
What is the potential of constructed wetlands in treating acid mine drainage?
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What is the main problem associated with ocean acidification?
What is the main problem associated with ocean acidification?
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Which organisms are most sensitive to ocean acidification?
Which organisms are most sensitive to ocean acidification?
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What is the benefit of using waste shells in mitigating ocean acidification?
What is the benefit of using waste shells in mitigating ocean acidification?
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What is the effect of waste shells on mussel banks?
What is the effect of waste shells on mussel banks?
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What is the role of waste shells in defaunated sites?
What is the role of waste shells in defaunated sites?
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What is the benefit of using waste shells as settlement substrates?
What is the benefit of using waste shells as settlement substrates?
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What might occur to metals in the marine water column at high PCO2?
What might occur to metals in the marine water column at high PCO2?
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What is the purpose of water-saturated weight tests for shell types?
What is the purpose of water-saturated weight tests for shell types?
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What is a valuable source of calcium in the food and nutraceutical industry?
What is a valuable source of calcium in the food and nutraceutical industry?
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What is the benefit of calcium supplementation from shell powders in livestock?
What is the benefit of calcium supplementation from shell powders in livestock?
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What is the effect of Ca supplementation in osteoporotic patients in the form of oyster shell electrolysate?
What is the effect of Ca supplementation in osteoporotic patients in the form of oyster shell electrolysate?
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What is a byproduct of the deproteinization process of crustacean shell waste?
What is a byproduct of the deproteinization process of crustacean shell waste?
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What is the antibacterial effect of macromolecular chitosan on aquatic and meat products?
What is the antibacterial effect of macromolecular chitosan on aquatic and meat products?
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What is the effect of chitosan on Bacillus cereus spore germination and (out)growth?
What is the effect of chitosan on Bacillus cereus spore germination and (out)growth?
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What is the purpose of covalent immobilization of chitinase on glutaraldehyde-activated chitosan?
What is the purpose of covalent immobilization of chitinase on glutaraldehyde-activated chitosan?
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What is the benefit of using chitosan as a food additive?
What is the benefit of using chitosan as a food additive?
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What is the main component of shells?
What is the main component of shells?
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What is the temperature required for the thermal decomposition of shells?
What is the temperature required for the thermal decomposition of shells?
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Why are shells difficult to dispose of?
Why are shells difficult to dispose of?
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What is the purpose of calcining shells?
What is the purpose of calcining shells?
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How many mollusc species are marketed for ornamental purposes?
How many mollusc species are marketed for ornamental purposes?
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What is the main goal of the European Commission's Green Growth and Circular Economy package?
What is the main goal of the European Commission's Green Growth and Circular Economy package?
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What is the current status of shell waste reutilization?
What is the current status of shell waste reutilization?
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What is the purpose of reviewing previous studies on shell waste reutilization?
What is the purpose of reviewing previous studies on shell waste reutilization?
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What is the main benefit of valorizing shells?
What is the main benefit of valorizing shells?
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Why are shells considered a valuable resource?
Why are shells considered a valuable resource?
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What is a limitation of this review?
What is a limitation of this review?
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What is the primary sector represented in search hits?
What is the primary sector represented in search hits?
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Why do shells with organic residue attached need to be cleaned?
Why do shells with organic residue attached need to be cleaned?
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What is the percentage of publications from 2010 till 2019?
What is the percentage of publications from 2010 till 2019?
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What is the purpose of enzymatic cleaning of shells?
What is the purpose of enzymatic cleaning of shells?
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What is the result of heating shells at 500 °C?
What is the result of heating shells at 500 °C?
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What is the purpose of ball milling and ultrasound-assisted hydrogen peroxide decolorization in the processing of crayfish shells?
What is the purpose of ball milling and ultrasound-assisted hydrogen peroxide decolorization in the processing of crayfish shells?
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What is the primary reason for using enzymatic cleaning over other methods?
What is the primary reason for using enzymatic cleaning over other methods?
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How can mollusc shells be cleaned for synthesizing aragonite needles by carbonation?
How can mollusc shells be cleaned for synthesizing aragonite needles by carbonation?
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What is the result of enzymatic hydrolysis on shrimp shells?
What is the result of enzymatic hydrolysis on shrimp shells?
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What is the challenge in cleaning shells with fresh water?
What is the challenge in cleaning shells with fresh water?
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What is the main benefit of using waste shells in wastewater treatment?
What is the main benefit of using waste shells in wastewater treatment?
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Why are intact shells poorly hydrolyzed by chitinases?
Why are intact shells poorly hydrolyzed by chitinases?
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What percentage of publications were from the year 2020 till November 2022?
What percentage of publications were from the year 2020 till November 2022?
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What is the difference between raw shells and calcined shells in phosphate removal?
What is the difference between raw shells and calcined shells in phosphate removal?
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What is the role of shells in nitrate removal from wastewater of fish farms?
What is the role of shells in nitrate removal from wastewater of fish farms?
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Why are enzymes often not used in certain applications?
Why are enzymes often not used in certain applications?
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What is the main application of chitin film and fiber in medicine?
What is the main application of chitin film and fiber in medicine?
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What is the main mechanism of phosphate removal from wastewater using raw shells?
What is the main mechanism of phosphate removal from wastewater using raw shells?
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What is the purpose of using crushed seashells in woodchip bioreactors?
What is the purpose of using crushed seashells in woodchip bioreactors?
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What properties of chitosan make it an excellent ingredient in topical skin ointments?
What properties of chitosan make it an excellent ingredient in topical skin ointments?
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Why are waste shells considered a potential solution for environmental applications?
Why are waste shells considered a potential solution for environmental applications?
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What is the benefit of using calcined oyster shell powder as a biofiller in plastics?
What is the benefit of using calcined oyster shell powder as a biofiller in plastics?
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What is the purpose of biopackaging made from chitin biopolymers?
What is the purpose of biopackaging made from chitin biopolymers?
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What is a challenge in developing biomaterials from shell waste?
What is a challenge in developing biomaterials from shell waste?
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What is the advantage of using mollusc shells in the production of hydroxyapatite?
What is the advantage of using mollusc shells in the production of hydroxyapatite?
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What is the role of chitin and chitosan in wound healing?
What is the role of chitin and chitosan in wound healing?
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What is a potential application of mollusc shells in medical radiation shielding?
What is a potential application of mollusc shells in medical radiation shielding?
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What is the benefit of using biodegradable chitin biopolymers in packaging?
What is the benefit of using biodegradable chitin biopolymers in packaging?
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What is the challenge in commercializing biomaterials from shell waste?
What is the challenge in commercializing biomaterials from shell waste?
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What is the potential application of chitin and its derivatives?
What is the potential application of chitin and its derivatives?
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What is the process of synthesizing chitosan?
What is the process of synthesizing chitosan?
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What is the biomedical application of chitosan?
What is the biomedical application of chitosan?
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What is the potential application of oyster shell powder in cosmetics?
What is the potential application of oyster shell powder in cosmetics?
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What is the potential application of hydroxyapatite in tissue engineering?
What is the potential application of hydroxyapatite in tissue engineering?
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What is the benefit of using hydroxyapatite in bone tissue engineering?
What is the benefit of using hydroxyapatite in bone tissue engineering?
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What is the potential application of chitin nanofibers?
What is the potential application of chitin nanofibers?
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What is the process of synthesizing chitin nanoparticles?
What is the process of synthesizing chitin nanoparticles?
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What is the benefit of using chitin and its derivatives in biomedical applications?
What is the benefit of using chitin and its derivatives in biomedical applications?
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What is the potential application of chitin hydrogels?
What is the potential application of chitin hydrogels?
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What is the primary benefit of using mollusc shells for reef restoration?
What is the primary benefit of using mollusc shells for reef restoration?
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What is the major air pollutant causing acid rain?
What is the major air pollutant causing acid rain?
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What is the advantage of using calcined oyster shells over limestone for acid gas cleaning?
What is the advantage of using calcined oyster shells over limestone for acid gas cleaning?
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What is the alternative to sodium chloride (NaCl) for road de-icing?
What is the alternative to sodium chloride (NaCl) for road de-icing?
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What is the benefit of using waste CaCO3 derived from waste shells for road de-icing?
What is the benefit of using waste CaCO3 derived from waste shells for road de-icing?
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What is the purpose of mollusc shells in green roofing structures?
What is the purpose of mollusc shells in green roofing structures?
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What is the challenge of using calcined shells for large-scale applications?
What is the challenge of using calcined shells for large-scale applications?
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What is the issue with using raw shells as bio-filters?
What is the issue with using raw shells as bio-filters?
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What is the concern with using shells from certain sources for environmental applications?
What is the concern with using shells from certain sources for environmental applications?
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What is the benefit of using mollusc shells for environmental applications?
What is the benefit of using mollusc shells for environmental applications?
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What is the most widely used building material discussed in the content?
What is the most widely used building material discussed in the content?
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What is the binder component of concrete?
What is the binder component of concrete?
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What is the effect of incorporating mollusc shell ash/powder for cement partial replacement?
What is the effect of incorporating mollusc shell ash/powder for cement partial replacement?
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What is the purpose of using mollusc shells as cement additives?
What is the purpose of using mollusc shells as cement additives?
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What is the advantage of using waste shell powder in cement-based materials?
What is the advantage of using waste shell powder in cement-based materials?
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What is the effect of using mollusc shells as aggregates in concrete?
What is the effect of using mollusc shells as aggregates in concrete?
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What is the benefit of using mollusc shells in construction?
What is the benefit of using mollusc shells in construction?
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What is the challenge associated with the pretreatment of waste shells?
What is the challenge associated with the pretreatment of waste shells?
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What is the problem associated with the use of high chloride content in aggregates?
What is the problem associated with the use of high chloride content in aggregates?
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What is the potential application of waste shells in construction?
What is the potential application of waste shells in construction?
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What type of radicals do chitosan and chitosan oligosaccharides scavenge?
What type of radicals do chitosan and chitosan oligosaccharides scavenge?
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What is the role of astaxanthin in crustaceans and wild salmonids?
What is the role of astaxanthin in crustaceans and wild salmonids?
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What is the effect of chitosan on LDL-cholesterol levels?
What is the effect of chitosan on LDL-cholesterol levels?
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What is the mechanism by which chitosan and chitosan oligosaccharides remove cholesterol from the digestive tract?
What is the mechanism by which chitosan and chitosan oligosaccharides remove cholesterol from the digestive tract?
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What is the effect of chitosan oligosaccharides on peripheral blood pressure?
What is the effect of chitosan oligosaccharides on peripheral blood pressure?
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What is the limitation of using chitosan for weight loss?
What is the limitation of using chitosan for weight loss?
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What is the potential application of chitosan in the treatment of hypertension?
What is the potential application of chitosan in the treatment of hypertension?
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What is the challenge in extracting chemicals from waste crustacean shells?
What is the challenge in extracting chemicals from waste crustacean shells?
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What is the limitation of using shells in industrial processes?
What is the limitation of using shells in industrial processes?
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What is the potential application of chitin and chitosan in the production of glucosamine products?
What is the potential application of chitin and chitosan in the production of glucosamine products?
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What is the primary concern with using waste shells as an aggregate replacement material in concrete?
What is the primary concern with using waste shells as an aggregate replacement material in concrete?
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Why is the aquaculture industry not currently utilizing waste shells as a valuable resource?
Why is the aquaculture industry not currently utilizing waste shells as a valuable resource?
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What is the benefit of using cleaner energy sources in the repurposing of waste shells?
What is the benefit of using cleaner energy sources in the repurposing of waste shells?
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What is the potential environmental benefit of repurposing waste shells?
What is the potential environmental benefit of repurposing waste shells?
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Why is it necessary to evaluate the environmental impact of waste shell repurposing?
Why is it necessary to evaluate the environmental impact of waste shell repurposing?
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What is the main challenge in utilizing waste shells as a sustainable resource?
What is the main challenge in utilizing waste shells as a sustainable resource?
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What is the benefit of using waste shells in industrial applications?
What is the benefit of using waste shells in industrial applications?
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What is necessary to support the development of a sustainable waste shell bioeconomy?
What is necessary to support the development of a sustainable waste shell bioeconomy?
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Study Notes
Fisheries and Aquaculture Production
- The total world fisheries and aquaculture production showed a 41% growth from 2000 to 2019, reaching 178 million tons in 2019.
- Molluscs comprised 13% of the total production, while crustaceans comprised 9%.
Shell Waste Generation and Composition
- Close to 8 million tons of waste crab, shrimp, and lobster shells are produced globally each year, comprising up to 60% of overall crab mass.
- Over 10 million tons of mollusc shells are produced annually, with over 70% represented by oyster, clam, scallop, and mussel shells.
- Shell waste accounts for 65-90% of live weight, depending on the species.
- Mussels have the greatest increase in production and shell contribution compared to other shellfish species.
Shell Waste Disposal and Environmental Impacts
- Disposed shells are primarily dumped at sea or sent to landfills, causing environmental damage.
- Shell waste can lead to decomposition of residual tissues, foul odors, and visual pollution.
- Shell waste is generated at various locations, including fisheries, aquaculture, processing companies, restaurants, and individual consumers.
Chemical Composition of Shells
- Shells are composed mainly of calcium carbonate (CaCO3).
- The decomposition of shells requires high temperatures of over 1000°C, resulting in high energy consumption and greenhouse gas emissions.
Valorization of Shell Waste
- Shell waste can be valorized through various applications, including agriculture, medicine, chemical production, construction, environmental protection, and cosmetics.
- The valorization of shells and the unlocking of markets for new products is essential for sustainable waste management.
Cleaning and Preparation of Shells
- Shells need to be cleaned prior to industrial use.
- Cleaning methods include washing with freshwater, heating at 500°C to burn off residual organic material, and enzymatic cleaning.
Environmental Applications of Shell Waste
- Shell waste can be used for water purification and bio-filters, particularly in wastewater treatment and phosphate removal.
- Calcined shells can be used for heavy metal removal from water and wastewater.
- Shell waste can be used for soil remediation, acid mine drainage treatment, and ocean deacidification.
Sustainability Challenges
- Cleaning shells with freshwater is water-intensive, and the use of enzymes is costly.
- The calcination of shells requires high temperatures, resulting in energy consumption and greenhouse gas emissions.### Sensitivity to Ocean Acidification
- Shellfish are more sensitive to ocean acidification at the larval stage than at the adult stage
- Ocean acidification can negatively impact shellfish production
- Increasing seawater alkalinity can help mitigate the effects of ocean acidification
- Restoration of macroalgae and seagrass beds can remove CO2 from seawater during photosynthesis
Use of Waste Shells
- Waste shells can be used to buffer decreases in seawater carbonate due to ocean acidification
- Placing shell reefs adjacent to shellfish farms can improve pH and carbonate geochemical conditions
- Waste shells can control benthic acidity, prevent heavy metal speciation, and reduce eutrophication
- Waste shells can serve as settlement substrates for free-living shellfish larvae and as shelter for other aquatic organisms
Flue Gas Treatment
- Calcined shell waste can be used as an excellent biosorbent material to remove pollutants like SO2, SO3, H2S, and NOx
- Calcined oyster shells can be used to prepare CaO adsorbent for CO2 sequestration
Road De-icing
- Crushed freshwater bivalve shells can be used as an alternative to sodium chloride (NaCl) for road de-icing
- Calcium-magnesium acetate or calcium acetate derivatives can be used as environmentally friendly road de-icers
Green Roofing
- Mollusc shells can be used as a material for green roofing structures, such as drainage layers, or to help neutralize acid rain
- Shells have bioremediation potential and can be used to reduce runoff water
Sustainability Challenges
- Calcination of waste shells requires high temperatures and special machinery, making it a non-sustainable solution
- Using raw shells as bio-filters can be a more sustainable solution, but requires careful consideration of instability in acidic waters and sludge formation
Food and Feed Additives; Nutraceuticals
- Waste shells can be used to produce natural shell powder, a relevant source of calcium for the food and nutraceutical industry
- Chitin is widely used to immobilize enzymes and whole cells in the food industry
- Chitosan is used as a preservative, thickener, and stabilizer in food products
Calcium Supplement
- Calcium supplementation from shell powders can improve bone health, blood circulation, and eggshell quality in livestock
Protein Supplement
- Meals derived from crustacean shell waste are usable feed ingredients, rich in essential amino acids
- Shell fermentation products can be used as a feed ingredient in the aquaculture industry
Antibacterials for Food
- Macromolecular chitosan has powerful antibacterial properties, inhibiting bacterial growth on surfaces of aquatic and meat products
Bioactive Molecules/Antioxidants
- Chitosan and chitosan oligosaccharides act as potent antioxidants, scavenging free radicals and preventing oxidative sequences
Bioactive Molecules/Cholesterol Reduction
- Chitosan acts as a hypocholesterolemic agent, reducing LDL-cholesterol levels and increasing HDL-cholesterol levels
Bioactive Molecules/Blood Pressure Reduction
- Chitosan oligosaccharides have angiotensin-converting-enzyme (ACE) inhibitory activity, reducing peripheral blood pressure and having an anti-hypertensive effect
Sustainability Challenges
- Extracting chemicals from waste crustacean shells is destructive and expensive, requiring fractionation and the use of hazardous chemicals
- A sustainable fractionation method to separate proteins, CaCO3, and chitin without hazardous chemicals is needed
Biomaterials
- Shells of both crustaceans and molluscs have potential applications in biofuels, flavors, fragrances, pharmaceuticals, industrial chemicals, and biomaterials
- Chitin and chitosan can be used as chemical building blocks for various biomedical applications
Bone Tissue Regeneration/Bioceramic
- Powdered oyster nacre can stimulate bone cell differentiation and bone formation in vitro and in vivo
- Oyster shell powder can be used as an injectable osteogenic biomaterial for treating vertebral bone loss
Cosmetics
- Clam shell powder has potential as a new biomaterial with high calcium, phosphate, chitin, and protein content
- Hydroxyapatite from shells can be used as an additive in sunscreen lotions, substituting oxybenzone, zinc oxide, and titanium dioxide
Wound Healing
- Chitin film and fiber can be used as a wound-dressing material, exhibiting bacteriostatic and fungistatic properties
Biocomposites/Biofillers
- Calcined, powdered mollusc shells can be used as additives for polyesters, endowing antibacterial properties to biocomposites
Biopackaging
- Biopolymers deriving from waste shells can be used to manufacture eco-friendly bioplastics for biomedical, industrial, and household applications### Antimicrobial Biopackaging
- Chitosan, derived from shell waste, is a promising active packaging material developed in the last decade.
- However, its stability is lower due to its hydrophilic character and pH sensitivity, making it imperative to investigate its bioactivities and develop new separation and enrichment technologies.
Sustainability Challenges
- Shell waste biomaterials are only developed as niche applications or tested in laboratory scales, not yet realized in production.
- To commercialize these biomaterials, it is necessary to consider their overall performance, chemical stability, reusability, economic, and environmental values for maintaining sustainability.
Construction
- Shells have been used in houses and walls as path aggregates and mortar mixes.
- Mollusc shells can be used as cement additives or aggregates to replace conventional aggregates in concrete, reducing production costs.
- Incorporating mollusc shell ash/powder for cement partial replacement results in reduced early compressive strength, but increases with age due to hydration of calcium oxide.
- The use of waste shell powder can possibly supplement non-renewable limestone powder in cement-based materials.
Shell Waste Repurposing
- Shell waste repurposing and valorization are important for determining strategies to make them a standard valuable resource for various applications.
- Bivalve aquaculture has the potential to act as a carbon sink, sequestering several million metric tons of CO2 per year globally.
- However, most aqua-cultured bivalves and crustaceans are traded fresh, and their shells are disposed of as domestic waste, releasing trapped CO2 back to the atmosphere during incineration.
- To upgrade waste shells, they should be collected in an organized manner, and their quantities estimated, ensuring a stable supply for large-scale applications.
Environmental Impact
- The repurposing of waste shells should reduce environmental impact, particularly in terms of energy and water demand.
- The use of cleaner energy sources could ameliorate the environmental impact of repurposing operations.
- The reuse and valorization of waste shells must consider collection, cleaning, storage, transport, and utilization costs, as well as economic value and impact.
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Quiz about the growth of global fisheries and aquaculture production, including the types of seafood produced and waste generated. Learn about the industry's expansion and the impact of shell waste.