Gases and Gas Laws Quiz
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Questions and Answers

How many moles of gas are present in a sample containing $1.8 \times 10^{24}$ atoms of chlorine at standard temperature and pressure?

  • 0.75 moles
  • 2.0 moles
  • 1.8 moles
  • 1.5 moles (correct)
  • Which of the following assumptions is NOT part of the kinetic theory of gases?

  • Gas particles have negligible volume compared to the volume of the container
  • Gases are made up of particles in rapid, random motion
  • The average kinetic energy of molecules is proportional to their mass (correct)
  • Molecules collide elastically
  • Why are non-volatile liquids unsuitable for the method described for relative molecular mass calculation?

  • They do not vaporise easily (correct)
  • They are less dense than water
  • They have high boiling points
  • They react with atmospheric oxygen
  • What modern technique can improve the accuracy of measuring the relative molecular mass of volatile and non-volatile substances?

    <p>Mass spectrometer (D)</p> Signup and view all the answers

    According to Avogadro's law, what do equal volumes of gases contain?

    <p>Equal numbers of molecules (B)</p> Signup and view all the answers

    What does Charles' Law state about the volume of a gas at constant pressure?

    <p>Volume is directly proportional to temperature. (B)</p> Signup and view all the answers

    What is the significance of the temperature -273°C in the context of Charles' Law?

    <p>It represents absolute zero where volume theoretically becomes zero. (A)</p> Signup and view all the answers

    In the equation V/T = k, what does 'k' represent?

    <p>The constant that relates volume and temperature. (C)</p> Signup and view all the answers

    How does pressure relate to the volume of gas according to Boyle's Law?

    <p>Pressure is inversely proportional to volume. (B)</p> Signup and view all the answers

    What does the straight line in the volume versus temperature graph signify?

    <p>The relationship is not linear across all temperatures. (B)</p> Signup and view all the answers

    What happens to the volume of a gas when it is cooled at constant pressure?

    <p>The volume decreases. (C)</p> Signup and view all the answers

    If the temperature of a gas is increased while keeping pressure constant, what is the expected change in volume?

    <p>The volume will increase. (C)</p> Signup and view all the answers

    In the equation pV = k, what does the term 'p' represent?

    <p>Pressure in Pascals. (A)</p> Signup and view all the answers

    Which of the following best describes an ideal gas?

    <p>A gas that perfectly obeys the assumptions of the kinetic theory under all conditions. (A)</p> Signup and view all the answers

    What assumption of the kinetic theory states that gas molecules collide without losing energy?

    <p>The elastic collision assumption. (C)</p> Signup and view all the answers

    Which factor is NOT a limitation of the kinetic theory of gases?

    <p>Collisions between gas particles are elastic. (A)</p> Signup and view all the answers

    In the equation of state for an ideal gas, pV = NRT, what does the variable R represent?

    <p>Universal gas constant. (D)</p> Signup and view all the answers

    During the mandatory experiment to measure the relative molecular mass of a volatile liquid, what is the purpose of covering the flask with aluminium foil?

    <p>To prevent vapor from escaping. (C)</p> Signup and view all the answers

    What measurement should be controlled to ensure accurate results during the experiment?

    <p>Temperature of the water. (D)</p> Signup and view all the answers

    At what temperature are the gas molecules' average kinetic energy proportional according to the kinetic theory?

    <p>Kelvin scale. (A)</p> Signup and view all the answers

    Which step is NOT part of the experiment to measure the relative molecular mass of a volatile liquid?

    <p>Pricking multiple holes in the aluminium foil. (D)</p> Signup and view all the answers

    What is the relationship between the volume and pressure of a gas at constant temperature according to Boyle's Law?

    <p>They are inversely proportional. (A)</p> Signup and view all the answers

    What is the SI unit for measuring pressure?

    <p>Pascal (Pa) (A)</p> Signup and view all the answers

    Which of the following temperature scales indicates absolute zero at 0K?

    <p>Kelvin (A)</p> Signup and view all the answers

    What is standard atmospheric pressure in pascals?

    <p>100,000 Pa (A)</p> Signup and view all the answers

    Which of the following statements about gas volume is correct?

    <p>The volume of a gas equals the volume of its container. (C)</p> Signup and view all the answers

    At what temperature is standard temperature set, according to standard temperature and pressure (s.t.p)?

    <p>273 K (B)</p> Signup and view all the answers

    How is temperature converted from Celsius to Kelvin?

    <p>Add 273 (C)</p> Signup and view all the answers

    What is the value of 1 litre in terms of cubic centimetres?

    <p>1000 cm3 (A)</p> Signup and view all the answers

    What must be done immediately after removing the flask from the beaker?

    <p>Record the atmospheric pressure using a barometer. (B)</p> Signup and view all the answers

    How is the mass of the vapor determined in the experiment?

    <p>By weighing the flask before and after heating. (C)</p> Signup and view all the answers

    Which of the following describes the condition under which the pressure of the vapor equals atmospheric pressure?

    <p>The vapor is allowed to escape through a hole. (C)</p> Signup and view all the answers

    What is a suitable example of a liquid to use in this experiment?

    <p>Cyclohexane (B)</p> Signup and view all the answers

    What is the first step to find the volume of the flask?

    <p>Fill the flask with water and measure the amount. (D)</p> Signup and view all the answers

    Why is it necessary to allow the flask to cool after removing it from the beaker?

    <p>To allow vapor to condense for measurement. (C)</p> Signup and view all the answers

    What happens to the volatile liquid when the flask is heated?

    <p>It vaporizes completely and escapes. (B)</p> Signup and view all the answers

    What is the atmospheric pressure recorded for the vapor in this experiment?

    <p>101 kPa (D)</p> Signup and view all the answers

    What does the Combined Gas Law relate?

    <p>Pressure, volume, and temperature of a gas (A)</p> Signup and view all the answers

    In the Combined Gas Law, if the pressure of a gas decreases, what happens to its volume at constant temperature?

    <p>The volume increases (B)</p> Signup and view all the answers

    What is the molar volume of a gas at standard temperature and pressure (s.t.p)?

    <p>22.4 liters (C)</p> Signup and view all the answers

    According to Gay-Lussac’s Law of Combining Volumes, what is true about the volumes of reacting gases?

    <p>They are in ratios of small whole numbers (B)</p> Signup and view all the answers

    When using the Combined Gas Law, which of the following variables is NOT required?

    <p>Final temperature (A)</p> Signup and view all the answers

    What would happen to the volume of nitrogen gas if the temperature decreases while pressure is maintained?

    <p>It will decrease (D)</p> Signup and view all the answers

    How is the volume of gas at standard and room temperature defined?

    <p>One mole occupies 22.4 liters at s.t.p. and 24.0 liters at room temperature (B)</p> Signup and view all the answers

    What is the relationship between the temperature and volume of a gas according to Charles’ Law?

    <p>Volume is directly proportional to temperature (C)</p> Signup and view all the answers

    Study Notes

    Gases

    • A gas is a substance with no defined boundaries. It rapidly fills any container it's placed in.
    • Gases are one of the three states of matter (solid, liquid, gas).

    Gas Laws

    Temperature

    • Temperature measures hotness.
    • Two common scales:
      • Kelvin: 0 K is absolute zero (-273°C)
      • Celsius: Water freezes at 0°C and boils at 100°C.
    • Converting between scales: Add 273 to Celsius to get Kelvin.

    Pressure

    • Pressure is the force exerted by a gas per unit area.
    • Units:
      • Newton per square meter (N/m²) or Pascal (Pa)
      • Kilopascal (kPa) = 1000 Pa
      • Hectopascal (hPa) = 100 Pa
    • Normal atmospheric pressure: 100,000 Pa.

    Volume

    • Volume is the space occupied by a gas. It's the same as the container's volume.
    • Units:
      • Cubic metre (m³)
      • Cubic centimetre (cm³)
      • Litre (L) = 1 dm³ = 1000 cm³

    Standard Temperature and Pressure (STP)

    • Standard temperature: 273 K
    • Standard pressure: 100,000 Pa

    Boyle's Law

    • At constant temperature, the volume of a gas is inversely proportional to its pressure.
    • pV = k (where p is pressure, V is volume, and k is a constant)

    Charles' Law

    • At constant pressure, the volume of a gas is directly proportional to its Kelvin temperature.
    • V/T = k (where V is volume, T is temperature, and k is a constant)

    Combined Gas Law

    • Combines Boyle's and Charles' Laws.
    • (P₁V₁)/T₁ = (P₂V₂)/T₂

    Gay-Lussac's Law of Combining Volumes

    • In reactions involving gases, the volumes of reacting gases and the products are in ratios of small whole numbers at the same temperature and pressure.

    Avogadro's Law

    • Equal volumes of gases at the same temperature and pressure contain equal numbers of molecules.
    • Molar volume: at STP, 1 mole of any gas occupies 22.4 litres

    Kinetic Theory of Gases

    • Gases are made of constantly moving particles.
    • There are no forces between particles (ideally).
    • Particle volume is negligible compared to the space between them.
    • Collisions are perfectly elastic.
    • Average kinetic energy is proportional to temperature.
    • Equation PV=nRT, using units of Pascal for pressure, cubic meters for volume, moles as quantity of gas, the universal gas constant R and Kelvin for temperature.

    Measurements of Relative Molecular Mass

    • Experimental method for determining the relative molecular mass of volatile liquids.
      • Carefully measure a known amount of liquid in a conical flask.
      • Heat the flask until all the liquid vaporizes while maintaining a constant temperature and pressure.
      • Cool the flask and record the new mass of the contents.
      • (Mathematical calculations follow to find the relative molecular mass)

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