Chemistry Titration Principles and Techniques
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Questions and Answers

Why is it necessary to add excess potassium iodide (KI) in the titration process?

  • To neutralize the sulfuric acid
  • To increase the temperature of the solution
  • To act as a catalyst for the reaction.
  • To ensure all the potassium permanganate or bleach has reacted and to keep the iodine in solution. (correct)
  • The first titration is a rough titration and two further titrations should be within 0.5mL of each other for accurate results.

    False

    What is the purpose of placing a white tile underneath the conical flask during a titration?

    To see the colour change better.

    What is the purpose of putting a pinhole in the tin foil covering the conical flask?

    <p>To ensure the pressure inside the flask is the same as outside</p> Signup and view all the answers

    When preparing a standard solution of sodium carbonate, it is not necessary to wash all traces of the sodium carbonate into the beaker or volumetric flask.

    <p>False</p> Signup and view all the answers

    When reading the meniscus in a burette or volumetric flask, the reading should be taken at ______ level.

    <p>eye</p> Signup and view all the answers

    Match the observed colour changes in the conical flask during the titration with the correct stage:

    <p>Purple to reddish-brown = Addition of potassium iodide Reddish brown to straw yellow = Addition of sodium thiosulfate Straw yellow to blue black = Addition of starch indicator Blue black to colourless = Further addition of sodium thiosulfate</p> Signup and view all the answers

    What is the standard value for the universal gas constant (R) used in the ideal gas law calculation?

    <p>8.3</p> Signup and view all the answers

    Why is it important to dilute the bleach solution before titrating?

    <p>To prevent excess amounts of sodium thiosulfate being used.</p> Signup and view all the answers

    The formula to calculate the number of moles using the ideal gas law is derived from PV = nRT by dividing by ______

    <p>RT</p> Signup and view all the answers

    Match the step in the procedure for standardizing HCl with the required action:

    <p>Rinsing the pipette = Rinse with deionised water followed by sodium carbonate Rinsing the burette = Rinse with deionised water followed by HCl Filling the burette = Fill to the calibration mark read at eye level Titration = Swirl the conical flask, wash sides, note colour change</p> Signup and view all the answers

    The burette should be rinsed with deionised water only before use.

    <p>False</p> Signup and view all the answers

    What unit is used for volume (V) when using the ideal gas law in these calculations?

    <p>m³</p> Signup and view all the answers

    How many times should the volumetric flask be inverted to ensure the solution is thoroughly mixed during the dilution of bleach?

    <p>20</p> Signup and view all the answers

    In the procedure for preparing a standard solution the volumetric flask should be filled to slightly above the calibration mark for better accuracy.

    <p>False</p> Signup and view all the answers

    What is used to indicate when the titration is complete when standardising the hydrochloric acid solution with sodium carbonate?

    <p>methyl orange</p> Signup and view all the answers

    What is the purpose of diluting the vinegar solution in the experiment to determine the concentration of ethanoic acid?

    <p>To prevent excess amounts of sodium hydroxide from being used.</p> Signup and view all the answers

    In a titration, it is necessary to read the meniscus from above eye level for accuracy.

    <p>False</p> Signup and view all the answers

    What indicator is recommended when titrating a strong base with a weak acid?

    <p>phenolphthalein</p> Signup and view all the answers

    A ________ is used to accurately measure and transfer a specific volume of liquid, such as sodium hydroxide for titration

    <p>pipette</p> Signup and view all the answers

    What is placed underneath the conical flask to help see the colour change in a titration?

    <p>a white tile</p> Signup and view all the answers

    The first titration is a precise titration and should be used in calculations.

    <p>False</p> Signup and view all the answers

    Match the chemical formula with its name:

    <p>NaOH = Sodium hydroxide HCl = Hydrochloric acid NaCl = Sodium chloride CH3COOH = Ethanoic acid</p> Signup and view all the answers

    Which of these options are correct for experiment to determine the amount of water of crystallisation in hydrated sodium carbonate? (Select all that apply)

    <p>A known mass of hydrated sodium carbonate crystals are measured</p> Signup and view all the answers

    What is the purpose of the starch indicator in the titration experiment?

    <p>To help the solution change from straw yellow to blue-black.</p> Signup and view all the answers

    In the experiment monitoring oxygen production, the rate of production of oxygen remains constant until the hydrogen peroxide is fully decomposed.

    <p>False</p> Signup and view all the answers

    What is the catalyst used in the experiment to monitor the rate of oxygen production from hydrogen peroxide?

    <p>manganese dioxide</p> Signup and view all the answers

    In the temperature effect experiment, the timer is stopped once the ________ is no longer visible.

    <p>X</p> Signup and view all the answers

    What is the color of the solution after the addition of potassium iodide in the titration experiment?

    <p>Reddish-brown</p> Signup and view all the answers

    In the rate of reaction experiment. the conical flask is placed over a black paper with an X marked on it

    <p>False</p> Signup and view all the answers

    In the sodium thiosulfate reaction with hydrochloric acid, what is specifically being measured to determine the rate of reaction?

    <p>time</p> Signup and view all the answers

    Match the color changes with their corresponding steps in the titration experiment:

    <p>Colourless to reddish-brown = Addition of potassium iodide Reddish brown to straw yellow = Addition of sodium thiosulfate Straw yellow to blue black = Addition of starch indicator Blue black to colourless = Addition of sodium thiosulfate</p> Signup and view all the answers

    What is the purpose of adding anhydrous magnesium sulfate to the organic solution in the clove oil extraction process?

    <p>To remove any water present</p> Signup and view all the answers

    In the soap making process, brine is used to dissolve the soap.

    <p>False</p> Signup and view all the answers

    What color change is observed when ethanal reacts with acidified potassium permanganate?

    <p>Purple to colorless</p> Signup and view all the answers

    In the soap making process, the _ _ is used as a solvent for the oil.

    <p>ethanol</p> Signup and view all the answers

    What is the key comment for making soap?

    <p>Glycerol tristerate</p> Signup and view all the answers

    Match the following apparatus/substances with their function in the soap making process:

    <p>Reflux apparatus = Ensures completion of the reaction and prevents loss of solvent Distillation apparatus = Collects the ethanol solvent Brine = Precipitates the soap Ice cold water = Washes the soap and prevents it dissolving too quickly</p> Signup and view all the answers

    Why is the soap washed with ice cold water?

    <p>To prevent the soap from dissolving too quickly</p> Signup and view all the answers

    An acidifed potassium permanganate solution acts as an _ agent.

    <p>oxidising</p> Signup and view all the answers

    What is the primary purpose of adding sodium carbonate in the oxidation of phenylmethanol to benzoic acid?

    <p>To ensure alkaline conditions for the reaction</p> Signup and view all the answers

    During recrystallization, using more solvent will result in more crystal formation.

    <p>False</p> Signup and view all the answers

    What is the chemical name of the compound that produces a fruity smell?

    <p>ethyl ethanoate</p> Signup and view all the answers

    The brown precipitate formed during the oxidation of phenylmethanol is due to the formation of ______.

    <p>MnO2</p> Signup and view all the answers

    Match the oxidation state of manganese with the corresponding chemical form during the oxidation of phenylmethanol process:

    <p>+7 = KMnO4 +4 = MnO2 +2 = Mn2+</p> Signup and view all the answers

    What is the function of hydrochloric acid(HCl) in the oxidation of phenylmethanol?

    <p>To convert sodium benzoate to benzoic acid, neutralise excess sodium carbonate and provide an acidic medium</p> Signup and view all the answers

    The purpose of using a heated funnel during recrystallization is to prevent the benzoic acid from solidifying during filtration.

    <p>True</p> Signup and view all the answers

    Why is a seed crystal added when recrystallizing benzoic acid?

    <p>To speed up the crystallization process</p> Signup and view all the answers

    Study Notes

    Chemistry Experiment Booklet

    • Flame Tests: Used to identify metal ions. Each metal produces a unique colour.
    • Anions Tests: Used to test for the presence of specific anions (negatively charged ions) in a solution. A common chloride ion test forms a white precipitate with silver nitrate, the precipitate disappears when ammonia is added. A sulphate ion solution forms a white precipitate with barium chloride.
    • Molecular Mass of Volatile Liquids: Explores measuring the vapour density to determine the molecular mass of liquid substances.
    • Standard Solution of Sodium Carbonate: A known mass of sodium carbonate is dissolved in a precise volume of water, to create a standard solution.
    • Standardizing Hydrochloric Acid: Standard sodium carbonate solution is used to determine the concentration of a hydrochloric acid solution.
    • Sodium Hydroxide Solution: A known mass of sodium hydroxide is measured and dissolved in a volumetric flask, and then standardized with hydrochloric acid.
    • Concentration of Ethanoic Acid in Vinegar: A precise volume of vinegar is diluted and titrated with a standard base solution (e.g., sodium hydroxide) using an indicator.
    • Water of Crystallisation in Hydrated Sodium Carbonate: Analysed to determine the amount of water in hydrated salt crystals.
    • Iron in Iron Tablets: A known mass of iron tablets is dissolved and titrated with potassium permanganate to determine the iron content.
    • Percentage of Sodium Hypochlorite: A measurement of sodium hypochlorite in household bleach using sodium thiosulfate in a titration.
    • Reaction Rate (Temperature): Sodium thiosulfate's reaction rate with hydrochloric acid is monitored at different temperatures to determine how the change in temperature affects the reaction rate.
    • Reaction Rate (Concentration): Sodium thiosulfate's reaction rate with hydrochloric acid is monitored at different concentrations to determine how changing concentration affects the reaction rate.
    • Le Chatelier's Principle: Iron III chloride and potassium thiocyanate are used to demonstrate the principle, by showing how changes in temperature or concentration affect a system at chemical equilibrium.
    • Total Water Hardness: Water samples are measured using EDTA to determine the total hardness of water.
    • Total Suspended and Dissolved Solids: The presence of suspended and dissolved solids is measured using filter paper weight and evaporation techniques.
    • Dissolved Oxygen: A redox titration method is used to analyze the dissolved oxygen content of water by determining the amount of iodine released from a specific reaction.
    • Free Chlorine in Swimming Pools: Various chlorine standards are made and measured using a colorimeter to estimate the free chlorine concentration in a swimming pool.
    • Preparation of Ethylene and Examined Properties: Ethylene is prepared and tested for its physical (colorless sweet smelling gas) and chemical properties (reaction with bromine, combustion).
    • Preparation of Ethyne and Examined Properties: Ethyne is generated and tested for its characteristics, including its physical attributes (colourless, sweet smelling gas) and chemical qualities (combustion and reactions with other substances).
    • Heat of Reaction with Hydrochloric Acid and Sodium Hydroxide: Reaction heat is measured in a polystyrene cup to calculate heat of neutralization.
    • Clove Oil Extraction: Steam distillation extracts clove oil from cloves, separating it from water.
    • Preparation of Soap: The reaction between oils and sodium hydroxide is used to synthesize soap, which is then filtered and dried.
    • Reactions of Ethanal: The oxidation reactions of Ethanal with potassium permanganate (acidified), Fehling's reagent, and ammoniacal silver nitrate (silver mirror test) are explored, confirming if the reactants are aldehydes or ketones, and the conditions impacting the results.
    • Ethanioc Acid with Sodium Carbonate: Ethanoic acid reacts with sodium carbonate, producing carbon dioxide gas which is detected using limewater.
    • Ethanoic Acid with Magnesium Metal:, A reaction between ethanoic acid and magnesium metal is explored, producing hydrogen gas, observable through a "pop" test.
    • Ethanoic Acid with Ethanol: Ethanol and ethanoic acid react in the presence of a catalyst (sulfuric acid) to form an ester (ethyl ethanoate) evidenced by the fruity smell of the product.
    • Oxidation of Phenylmethanol: The reaction of phenylmethanol with potassium permanganate under alkaline conditions and subsequent crystallization are examined.
    • Recrystallization of Benzoic Acid: To purify benzoic acid, through recrystallization using a vacuum filtering setup.
    • Boiling Point of Benzoic Acid: The melting point of benzoic acid is tested and reported.
    • Separation of Ink Components: Paper chromatography method is used to separate the ink's components into its different dyes.

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    Description

    This quiz covers essential concepts and techniques in titration, including the role of potassium iodide, the significance of the white tile, and the proper method for reading measurements. Additionally, it explores the ideal gas law and the importance of accurately preparing standard solutions. Test your understanding of these fundamental chemistry principles.

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