Chemistry: π Bond Rotation and Cis-Trans Isomers

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Questions and Answers

What is a characteristic of the resulting molecular orbital formed by the side-to-side overlap of atomic orbitals?

  • It has cylindrical symmetry
  • It has a spherical shape
  • It has the highest electron density at the center
  • It has a nodal plane with zero electron density (correct)

Which type of hybridization is adopted by carbon atoms in ethane (C2H6)?

  • No hybridization
  • sp3 hybridization (correct)
  • sp hybridization
  • sp2 hybridization

What is the difference between a σ bond and a π bond?

  • A σ bond is weaker than a π bond
  • A σ bond is stronger than a π bond
  • A σ bond is formed by side-to-side overlap, while a π bond is formed by end-to-end overlap
  • A σ bond is formed by end-to-end overlap, while a π bond is formed by side-to-side overlap (correct)

What is the shape of the molecular orbitals formed by the overlap of atomic orbitals with cylindrical symmetry?

<p>Cylindrical (D)</p> Signup and view all the answers

Why is a double bond less than twice as strong as a single bond?

<p>Because a π bond is weaker than a σ bond (D)</p> Signup and view all the answers

In which type of bond is an s orbital unable to participate?

<p>π bond (B)</p> Signup and view all the answers

What type of bond is formed by end-to-end overlap of orbitals?

<p>Sigma bond (A)</p> Signup and view all the answers

Which statement is true about pi (p) bonds?

<p>They involve sideways overlap of orbitals. (B)</p> Signup and view all the answers

Why is a pi (p) bond weaker than a sigma bond?

<p>It has less effective overlap due to sideways orientation. (D)</p> Signup and view all the answers

In a triple bond, how many sigma bonds are present?

<p>One (A)</p> Signup and view all the answers

What type of bond is formed by the end-to-end overlap of hybridized orbitals?

<p>Sigma bond (C)</p> Signup and view all the answers

Why do larger atoms form longer bonds to hydrogen?

<p>To decrease repulsions due to decreased overlap (D)</p> Signup and view all the answers

Which type of orbital overlap is responsible for the formation of a π bond?

<p>Above and below overlap (D)</p> Signup and view all the answers

In which situation does bond rotation not occur?

<p>Around a π bond (C)</p> Signup and view all the answers

What term is used to describe compounds with the same molecular formula but different structures and properties?

<p>Isomers (A)</p> Signup and view all the answers

Which type of isomerism differentiates between polar and non-polar forms of compounds?

<p>Cis-trans isomerism (C)</p> Signup and view all the answers

In which type of hybridization is a carbon atom involved in only one double bond?

<p>sp2 hybridization (C)</p> Signup and view all the answers

Who was awarded the Nobel Prize in Chemistry in 1966 for his work on the electronic structure of molecules by the molecular orbital method?

<p>Robert S. Mulliken (C)</p> Signup and view all the answers

What is the primary difference between the Molecular Orbital theory and the Valence Bond theory?

<p>The computation of wave functions from all atomic orbitals versus valence orbitals (B)</p> Signup and view all the answers

What is the advantage of the Linear Combination of Atomic Orbitals (LCAO) approach in Molecular Orbital theory?

<p>It gives molecular orbitals that could be delocalized over the entire molecule (A)</p> Signup and view all the answers

What is the primary consequence of Hund's rule of maximum spin multiplicity in populating empty orbitals?

<p>The formation of paramagnetic substances (A)</p> Signup and view all the answers

What is the primary application of the Schrödinger equation in Molecular Orbital theory?

<p>To solve for the wave functions of molecules (A)</p> Signup and view all the answers

What is the primary criterion for determining the bond order of a molecule using MO diagrams?

<p>The difference between the number of bonding and antibonding molecular orbitals (C)</p> Signup and view all the answers

What is the primary characteristic of paramagnetic substances in terms of their molecular orbitals?

<p>They have unpaired electrons in their molecular orbitals (C)</p> Signup and view all the answers

What is the primary reason for the bond strength increasing with greater orbital overlap?

<p>The increased overlap leads to a decreased energy of the molecular orbital (B)</p> Signup and view all the answers

What is the consequence of violating the Pauli principle in molecular orbitals?

<p>The molecular orbital would become unstable (A)</p> Signup and view all the answers

What is the characteristic of the molecular orbital formed by the side-to-side overlap of atomic orbitals?

<p>It is a pi molecular orbital (C)</p> Signup and view all the answers

What determines the bond order of a molecule using MO diagrams?

<p>The number of electrons occupying the molecular orbital (A)</p> Signup and view all the answers

Which of the following is a characteristic of diamagnetic substances?

<p>They are unaffected by magnetic fields (C)</p> Signup and view all the answers

What is the consequence of having unpaired electrons in a molecular orbital?

<p>The molecule becomes paramagnetic (A)</p> Signup and view all the answers

What is the relationship between bond order and bond energy?

<p>Bond order and bond energy are directly proportional. (C)</p> Signup and view all the answers

In Molecular Orbital (MO) Theory, what does a bond order of 2.5 indicate?

<p>The molecule has a stronger bond. (D)</p> Signup and view all the answers

How does the removal of an electron from a molecule typically affect its bond strength and bond length?

<p>Removal of an electron strengthens the bond but increases bond length. (B)</p> Signup and view all the answers

Which of the following compounds is predicted to exhibit paramagnetic properties based on their MO diagrams?

<p>N2+ (A)</p> Signup and view all the answers

What is the relationship between bond order and bond length?

<p>Bond order and bond length are inversely proportional. (D)</p> Signup and view all the answers

Which of the following compounds would likely have a stronger bond compared to O2, based on the bond order calculation?

<p>N2 (A)</p> Signup and view all the answers

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