Chemistry Class: Periodic Table & Trends

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Questions and Answers

Which of the following is NOT a characteristic of metals?

  • Malleable
  • Brittle (correct)
  • Solid at room temperature
  • Ductile

The electronic configuration of d-block elements is (n-1)d1-10 ns0-2.

True (A)

The tendency of an element to gain electrons is called ______ character.

non-metallic

What is the name for elements that exhibit the properties of both metals and non-metals?

<p>Metalloids or semi-metals</p> Signup and view all the answers

Match the periodic table groups with their corresponding names:

<p>Group 1 = Alkali Metals Group 2 = Alkaline Earth Metals Group 3-12 = Transition Metals Group 18 = Noble Gases Group 17 = Halogens Group 16 = Chalcogens</p> Signup and view all the answers

Which of the following statements is true about atomic radius across a period?

<p>Atomic radius decreases from left to right. (B)</p> Signup and view all the answers

Ionization enthalpy decreases down a group due to the increased distance between the outermost electron and the nucleus.

<p>True (A)</p> Signup and view all the answers

The energy required to remove an electron from an atom in its gaseous state is called ______.

<p>ionization enthalpy</p> Signup and view all the answers

What is the general electronic configuration of f-block elements?

<p>(n-2)f1-14 (n-1)d0-2 ns2</p> Signup and view all the answers

Which of the following is NOT a metalloid?

<p>Oxygen (O) (C)</p> Signup and view all the answers

Atomic radius increases down a group because the number of electron shells decreases.

<p>False (B)</p> Signup and view all the answers

The elements in Group 17 are collectively called ______.

<p>halogens</p> Signup and view all the answers

How does the metallic character of elements change across a period?

<p>Metallic character decreases across a period.</p> Signup and view all the answers

Which of the following has the smallest atomic radius?

<p>Chlorine (Cl) (A)</p> Signup and view all the answers

A positively charged ion (cation) is larger than its corresponding neutral atom.

<p>False (B)</p> Signup and view all the answers

What did Henry Moseley discover about elements?

<p>Atomic number is the fundamental property of elements (A)</p> Signup and view all the answers

Mendeleev's Periodic Table was able to accurately predict all future elements.

<p>False (B)</p> Signup and view all the answers

What are the two main classifications of elements in the periodic table?

<p>Metals and nonmetals</p> Signup and view all the answers

The periodic table consists of ____ periods and ____ groups.

<p>seven, 18</p> Signup and view all the answers

Match the following historical figures with their contributions:

<p>Lavoisier = Classified elements into metals and nonmetals Döbereiner = Proposed triads based on similar properties Newlands = Formulated the Law of Octaves Mendeleev = Developed the first periodic table</p> Signup and view all the answers

What are the 'magic numbers' related to in the periodic table?

<p>The number of elements in each period (C)</p> Signup and view all the answers

Mendeleev's table arranged 63 elements in columns only.

<p>False (B)</p> Signup and view all the answers

What issue did Mendeleev face with isotopes in his periodic table?

<p>He couldn't explain their positions due to differing atomic masses.</p> Signup and view all the answers

Which element has a higher first ionization enthalpy?

<p>Beryllium (D)</p> Signup and view all the answers

Noble gases have negative values of electron gain enthalpy.

<p>False (B)</p> Signup and view all the answers

What happens to electron gain enthalpy as you move across a period from left to right?

<p>It becomes more negative.</p> Signup and view all the answers

Halogens have highly negative electron gain enthalpy because they are only one electron away from having a full outer shell. The energy change is _____ when an electron is added.

<p>released</p> Signup and view all the answers

Match the following elements with their respective oxidation states:

<p>Alkali metals = Positive oxidation state Halogens = Negative oxidation state Oxygen = Usually -2 Transition metals = Variable oxidation states</p> Signup and view all the answers

Which of the following statements about electronegativity is true?

<p>Electronegativity depends on the atom it is bonded to. (A)</p> Signup and view all the answers

Electron gain enthalpy generally becomes less negative down a group.

<p>True (A)</p> Signup and view all the answers

What is the reason for the anomalous behavior of second-period elements?

<p>Smaller size and higher charge-to-radius ratio.</p> Signup and view all the answers

The oxides of alkali metals are typically _____ in nature.

<p>basic</p> Signup and view all the answers

Which of the following groups contains elements that are highly reactive?

<p>Alkali metals and halogens (D)</p> Signup and view all the answers

Which group of elements are known as alkali metals?

<p>Group 1 (C)</p> Signup and view all the answers

The electronic configuration of p-block elements ends with p orbitals.

<p>True (A)</p> Signup and view all the answers

What is the primary characteristic of d-block elements?

<p>They have their last electron enter the d-orbital.</p> Signup and view all the answers

The final electron of alkaline earth metals enters the ______.

<p>s-orbital</p> Signup and view all the answers

Match the following groups with their properties:

<p>Alkali Metals = Soft and highly reactive Alkaline Earth Metals = Hard and less reactive Halogens = Most reactive nonmetals Noble Gases = Colorless and unreactive</p> Signup and view all the answers

Which of the following statements about noble gases is true?

<p>They have a filled outermost electron shell. (A)</p> Signup and view all the answers

Hydrogen is classified as an alkaline earth metal.

<p>False (B)</p> Signup and view all the answers

Name an element from the f-block category.

<p>Lanthanum or Actinium.</p> Signup and view all the answers

Elements in Group 15 are known as the ______ Group.

<p>Nitrogen</p> Signup and view all the answers

What determines the period of an element in the periodic table?

<p>The highest value of its principal quantum number (n) (A)</p> Signup and view all the answers

Silicon is crucial for electronics and semiconductors.

<p>True (A)</p> Signup and view all the answers

The oxidation state exhibited by most f-block elements is ______.

<p>+3</p> Signup and view all the answers

Match the following groups with their characteristics:

<p>Oxygen Group = Vital for respiration Carbon Group = Backbone of organic chemistry Halogens = Reactive nonmetals Transition Metals = Variable oxidation states</p> Signup and view all the answers

Flashcards

Periodic Table

The organization of elements based on their properties and atomic numbers, arranged in rows (periods) and columns (groups).

Modern Periodic Law

The principle that states the chemical and physical properties of elements repeat periodically when arranged by increasing atomic number.

Magic Numbers

The number of elements in each period of the periodic table (e.g., 2, 8, 8, 18, 18, 32).

Classification of Elements

The process of classifying elements based on their similarities in chemical and physical properties.

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Periodic Trends

The change in a property of elements as you move across a period or down a group on the Periodic Table.

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Döbereiner's Triads

Döbereiner's observation that groups of three elements (triads) share similar chemical properties.

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Newland's Law of Octaves

Newland's observation that every eighth element in a period displays similar properties.

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Mendeleev's Periodic Table

Mendeleev's initial attempt to organize the periodic table based on atomic mass, leading to a few limitations.

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First ionization enthalpy

The energy required to remove one electron from a neutral gaseous atom in its ground state.

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Why is beryllium's first ionization enthalpy higher than boron's?

Beryllium's outermost electron is in the s orbital, which is more strongly attracted to the nucleus than boron's outermost electron in the p orbital.

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Why is nitrogen's first ionization enthalpy higher than oxygen's?

Nitrogen has a half-filled p orbital, which is more stable than oxygen's partially filled p orbital.

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Electron Gain Enthalpy

The change in energy when an electron is added to a neutral gaseous atom.

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Why do halogens have high negative electron gain enthalpy?

Halogens have very high negative electron gain enthalpy because they only need one more electron to achieve a full outer shell, making them very stable.

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How does electron gain enthalpy change down a group?

Electron gain enthalpy generally becomes less negative down a group because the outermost electron is further from the nucleus, decreasing the attraction.

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Electronegativity

The ability of an atom to attract shared electrons in a compound.

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How does electronegativity vary across a period?

Electronegativity increases across a period from left to right due to increasing nuclear charge, resulting in a stronger attraction for electrons.

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Oxidation state

The charge acquired by an atom when it forms a compound. It reflects the number of electrons gained or lost.

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Why are alkali metals highly reactive?

Alkali metals have high reactivity because they readily lose one electron to achieve a stable octet configuration.

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Why do d-block elements fill the d-orbital last?

d-block elements are a group of elements in the periodic table whose last electron enters the d-orbital, even though the 4s orbital fills first due to the order of increasing energy levels.

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What role do transition metals play in the periodic table?

Transition metals form a bridge between s-block and p-block elements.

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What's the general electronic configuration of d-block elements?

The general electronic configuration for d-block elements is (n-1)d1-10 ns0-2, where n represents the principal quantum number.

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What are f-block elements?

f-block elements are those in which the last electron enters an f-orbital and are also known as inner transition elements.

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What's the general electronic configuration of f-block elements?

The general electronic configuration for f-block elements is (n-2)f1-14 (n-1)d0-2 ns2, where n represents the principal quantum number.

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How do you determine the group number based on the electronic configuration?

For s-block elements, the group number equals the number of valence electrons. For p-block elements, the group number is 10 plus the number of valence electrons. For d-block elements, the group number is the total number of electrons in the (n-1) d sub-shell plus the number of valence electrons.

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What types of elements are found in the periodic table?

Most elements in the periodic table are metals, including s-block, d-block, and f-block elements. p-block contains metals, non-metals, and metalloids.

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What are metalloids?

Metalloids are elements that exhibit both metallic and non-metallic properties.

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What is metallic character?

Metallic character refers to an element's tendency to lose electrons.

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What is non-metallic character?

Non-metallic character refers to an element's tendency to gain electrons.

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How does metallic character change down a group?

Metallic character increases down a group because the valence electrons are further from the nucleus and easier to lose.

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How does metallic character change across a period?

Metallic character decreases across a period because the nuclear charge increases, pulling the valence electrons closer to the nucleus, making them harder to lose.

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What is atomic radius?

Atomic radius is a measure of the size of an atom, defined as half the distance between the centers of two adjacent atoms of the same element.

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How does atomic radius change across a period?

Atomic radius decreases across a period because the nuclear charge increases, pulling the electrons closer to the nucleus.

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How does atomic radius change down a group?

Atomic radius increases down a group because the number of electron shells increases, making the atoms larger.

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Temporary Name for Elements

A temporary name given to a newly discovered element based on its atomic number.

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What determines an element's Period?

The number of shells in an atom is determined by the highest value of the principal quantum number. Elements in the same period have the same number of atomic orbitals and electron shells.

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Elements in the same Group

Elements in the same group share the same number of valence electrons and similar chemical properties, but have different principal quantum numbers.

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Valence Electrons and Groups

The outermost shell electrons determine an element's chemical behavior and are crucial for bonding. Different elements in the same group have different energy levels for their valence electrons.

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s-Block Elements

The s-block of the periodic table includes Groups 1 and 2, which are the alkali metals and alkaline earth metals, respectively.

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Alkali Metals (Group 1)

Alkali metals are soft, highly reactive metals with low melting points. They form strongly basic oxides and exist as monovalent cations (positive charge).

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Alkaline Earth Metals (Group 2)

Alkaline earth metals are harder, less reactive, and have higher melting points than alkali metals. They form less basic oxides and exist as divalent cations (positive charge).

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p-Block Elements

Elements in which the last electron enters the p-orbital. They encompass groups 13 to 18, and include various types of elements.

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d-Block Elements

The final electron goes into the d-orbital, which is an inner shell. They are located in Groups 3 to 12, and include transition metals.

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f-Block Elements

The last electron enters the f-orbital. They are called inner transition elements and include lanthanides and actinides.

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Main Group Elements

s-block and p-block elements are collectively called the 'main group' elements or 'representative elements'.

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Electronic Configuration of s-block Elements

The general electronic configuration of s-block elements is ns1 or ns2, meaning the last electron enters the s orbital.

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Electronic Configuration of p-block Elements

The general electronic configuration of p-block elements varies from ns2 np1 to ns2 np6, with the last electron entering the p orbital.

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Electronic Configuration of d-block Elements

The electronic configuration of d-block elements involves the last electron entering the d-orbital, which is an inner (not the outermost) orbital.

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Study Notes

  • Understanding the elements is crucial for learning chemistry.
  • Elements are classified based on their properties.
  • The periodic table is the categorization of elements.
  • Trends in properties are essential to understand, rather than each element's individual characteristics.

History of the Periodic Table

  • 1789: Lavoisier classified 33 elements into metals, nonmetals, gases, and earths.
  • 1829: Döbereiner proposed triads based on similar properties.
  • 1865: Newlands formulated the Law of Octaves, where every 8th element shares similar characteristics.
  • Around 1860: Mendeleev developed the Periodic Table based on atomic mass and chemical characteristics, including compound oxides and hydrides.
  • 1913: Henry Moseley discovered atomic number, not atomic mass, is the fundamental property, revising the Periodic Table into the modern structure.

Advantages of Mendeleev's Periodic Table

  • Organized 63 elements into rows (periods) and columns (groups).
  • Used chemical properties of compounds like oxides and hydrides to classify elements.
  • Predicted the existence of undiscovered elements like gallium and germanium.

Limitations of Mendeleev's Periodic Table

  • Couldn't explain the position of isotopes.
  • Some elements with higher atomic masses preceded those with lower atomic masses (e.g., cobalt and nickel).
  • The position of hydrogen, with its unusual properties, resembling sometimes alkali metals and sometimes halogens, was problematic.

The Modern Periodic Law

  • States that the physical and chemical properties of elements are periodic functions of their atomic numbers.
  • The long form of the Periodic Table is widely used.
  • The Periodic Table consists of seven periods (horizontal rows) and 18 groups (vertical columns).

Magic Numbers

  • The number of elements in each period (2, 8, 8, 18, 18, 32) are "magic numbers".
  • Elements with similar properties reappear with intervals of these magic numbers.
  • Adding the magic number to an element's atomic number gives the atomic number of the element directly below it.
  • The same magic number applies for all elements in a group due to their shared chemical properties.

IUPAC Nomenclature for Newly Discovered Elements

  • As new elements are discovered, names and symbols are needed.
  • Initially, discoverers could choose names, leading to conflicts.
  • The IUPAC (International Union of Pure and Applied Chemistry) established a standardized system for temporary names.
  • Temporary names are assigned based on the element's atomic number.
  • Confirmed elements receive permanent names and symbols, decided by IUPAC representatives.

Electronic Configuration and Group Number

  • An element's period is determined by the highest value of its principal quantum number (n).
  • The number of atomic orbitals in a period is given by n².
  • Elements in the same group have the same number of valence electrons but different principal quantum numbers.
  • Electronic configurations help determine group membership.

Block Classification

  • Elements are categorized into four blocks (s, p, d, f) based on the orbital where the last electron enters.
  • Elements within each block share similar chemical properties.

s-Block Elements

  • Final electron enters the s-orbital.

  • Groups 1 and 2 belong to the s-block.

  • Alkali metals (Group 1) and alkaline earth metals (Group 2) are s-block elements.

  • Alkali Metals (Group 1):

    • Soft metals
    • Highly reactive
    • Low melting points
    • Form strongly basic oxides.
    • Exist as monovalent cations.
  • Alkaline Earth Metals (Group 2):

    • Hard, silvery-white to yellow metals
    • Less reactive than alkali metals
    • Higher melting points
    • Form oxides less basic than alkali metal oxides
    • Exist as divalent cations.

p-Block Elements

  • Final electron enters the p-orbital.

  • Groups 13 to 18 belong to the p-block.

  • Diverse properties: nonmetals, metalloids, and metals.

  • General p-block properties:

    • Show a wide range of oxidation states.
    • Variable reactivity.
    • Form basic, acidic, or amphoteric oxides (depending on the element).
  • Specific Group Properties: Detailed below.

d-Block Elements

  • Final electron enters the d-orbital.
  • Groups 3 to 12

f-Block Elements

  • Final electron enters the f-orbital.
  • Includes lanthanides and actinides.
  • Inner transition elements placed below the main table.

Other Sections (Remaining sections are updated with details, keeping the existing structure and adding details where applicable - too lengthy to copy and paste)

...(Detailed update of remaining sections, including specific p-block element properties, trends in atomic radius, ionization enthalpy, electron gain enthalpy, electronegativity, oxidation states, chemical reactivity, and anomalous behavior of second-period elements)

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