Chemistry Chapter: Atomic Structure and Elements

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Questions and Answers

What particles are found in the nucleus of an atom?

  • Electrons
  • Protons and neutrons (correct)
  • Protons
  • Protons and electrons

Identify the correct classification of potassium and chlorine.

  • Metalloid, nonmetal
  • Metal, metalloid
  • Metal, nonmetal (correct)
  • Nonmetal, metal

What is the empirical formula of the ionic compound formed from aluminum and sulfur?

  • AlS
  • Al3S2
  • AlS2
  • Al2S3 (correct)

What is the correct name for the compound SrO?

<p>Strontium oxide (C)</p> Signup and view all the answers

What is the name of the compound PCl3?

<p>Phosphorous trichloride (C)</p> Signup and view all the answers

Which formula represents ammonium carbonate?

<p>(NH4)2CO3 (C)</p> Signup and view all the answers

Which subatomic particle is the smallest and lightest?

<p>Proton (A)</p> Signup and view all the answers

In an atom of 18Ar, how many electrons, protons, and neutrons are present?

<p>18, 18, 22 (D)</p> Signup and view all the answers

Isotopes are defined as atoms that have the same number of _______ but differing number of _______.

<p>Protons, neutrons (D)</p> Signup and view all the answers

Which element has the largest first ionization energy?

<p>F (B)</p> Signup and view all the answers

Which of the following has the largest second ionization energy?

<p>Li (A)</p> Signup and view all the answers

Which equation correctly represents the first ionization of aluminum?

<p>Al(g) → Al+(g) + e- (C)</p> Signup and view all the answers

Which ion has the largest radius?

<p>Cl- (B)</p> Signup and view all the answers

Of the following elements, which has the greatest electronegativity?

<p>O (B)</p> Signup and view all the answers

Which list indicates the correct order of metallic character?

<p>Na &gt; K &gt; Rb (D)</p> Signup and view all the answers

Based on the octet rule, strontium most likely forms which type of ion?

<p>Sr2+ (C)</p> Signup and view all the answers

How many unpaired electrons are there in the Lewis structure of a nitrogen atom?

<p>3 (D)</p> Signup and view all the answers

Which of the following would need to lose one electron to achieve a noble gas electron configuration?

<p>Na (A)</p> Signup and view all the answers

The Lewis structure of H2O shows how many nonbonding electron pair(s) on oxygen?

<p>2 (D)</p> Signup and view all the answers

Which compound is chromium(III) oxide?

<p>Cr2O3 (A)</p> Signup and view all the answers

What is the frequency of electromagnetic radiation with a wavelength of 0.53 m?

<p>5.7 × 10^8 (D)</p> Signup and view all the answers

Which pair of elements is most apt to form a molecular compound?

<p>Sulfur, Fluorine (A)</p> Signup and view all the answers

Which type of radiation has the shortest wavelength?

<p>X-ray (B)</p> Signup and view all the answers

What is the energy of a photon with a wavelength of 12.3 nm?

<p>1.62 × 10^-17 J (A)</p> Signup and view all the answers

How many quantum numbers are necessary to designate a particular electron in an atom?

<p>4 (B)</p> Signup and view all the answers

There are how many unpaired electrons in a ground state phosphorus atom?

<p>3 (C)</p> Signup and view all the answers

The lowest energy shell that contains f orbitals has what principal quantum number?

<p>4 (C)</p> Signup and view all the answers

Which of the following quantum numbers set is not acceptable for an electron?

<p>1, 1, 1 (D)</p> Signup and view all the answers

What is the ground state electron configuration for zinc (Zn)?

<p>[Kr]4s2 3d10 (A)</p> Signup and view all the answers

Which set of three quantum numbers (n, l, ml) corresponds to a 3d orbital?

<p>3, 2, 2 (C)</p> Signup and view all the answers

At maximum, an s-subshell can hold __________ electrons, a p-subshell can hold __________ electrons, and a d-subshell can hold __________ electrons.

<p>2, 6, 10 (C)</p> Signup and view all the answers

Elements in the modern version of the periodic table are arranged in order of increasing _______.

<p>atomic number (B)</p> Signup and view all the answers

Which of the following gives the correct order for atomic radius for Mg, Na, P, Si, and Ar?

<p>Ar &gt; P &gt; Si &gt; Mg &gt; Na (A)</p> Signup and view all the answers

The atomic radius of main-group elements generally increases down a group because __________.

<p>the principal quantum number of the valence orbitals increases (A)</p> Signup and view all the answers

Which one of the following atoms has the largest radius?

<p>Cl (B)</p> Signup and view all the answers

Which one of the following has the smallest radius?

<p>Na (C)</p> Signup and view all the answers

Which of the following is an isoelectronic series?

<p>O2-, F-, Ne, Na+ (B)</p> Signup and view all the answers

Which of the following correctly lists the atoms in order of increasing size (smallest to largest)?

<p>F &lt; Ge &lt; Br &lt; K &lt; Rb (B)</p> Signup and view all the answers

Flashcards

Molecular Compound

A chemical compound formed from nonmetallic elements. Their bonds are typically covalent, meaning they share electrons.

Ionic Compound

A chemical compound formed when a metal reacts with a nonmetal. The metal typically loses electrons, forming a positive ion, and the nonmetal gains electrons, forming a negative ion.

Molecular Formula

A formula that indicates the kinds and relative numbers of atoms present in a molecule of a substance.

Empirical Formula

The simplest whole-number ratio of atoms of each element present in a compound.

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Organic Compound

A compound that contains carbon and hydrogen, often combined with other elements such as oxygen, nitrogen, sulfur, phosphorus, and halogens.

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Inorganic Compound

A compound that does not contain carbon.

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Salt

A compound that contains a metal and a nonmetal. The metal typically forms a positive ion, and the nonmetal forms a negative ion.

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Oxide

A compound of oxygen with another element where oxygen is in -2 oxidation state.

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Hydroxide

A compound that contains hydrogen and oxygen.

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Acid

A compound that dissolves in water to produce hydrogen ions (H+)

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Quantum Numbers

A set of three quantum numbers (n, l, ml) that uniquely describes the state of an electron in an atom.

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Principle Quantum Number (n)

The value 'n' of a quantum number set (n, l, ml) represents the principle quantum number.

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Angular Momentum Quantum Number (l)

The value 'l' of a quantum number set (n, l, ml) represents the angular momentum quantum number.

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Magnetic Quantum Number (ml)

The value 'ml' of a quantum number set (n, l, ml) represents the magnetic quantum number.

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Subshell Electron Capacity

The maximum number of electrons that can occupy a subshell is determined by the specific subshell.

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Periodic Table Organization

The modern periodic table organizes elements by increasing atomic number.

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Group Trends (Periodic Table)

Elements within the same group (vertical column) of the periodic table share similar chemical properties.

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Atomic Radius

Atomic radius is the distance from the nucleus of an atom to its outermost electron.

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Atomic Radius Trend: Downward

Atomic radius generally increases moving down a group in the periodic table.

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Atomic Radius Trend: Across

Atomic radius generally decreases across a period in the periodic table.

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First ionization energy (IE1)

The ability of an atom in a gaseous state to lose an electron and become a positively charged ion. It is always endothermic - energy must be absorbed from the surroundings to remove the electron.

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Second ionization energy (IE2)

The energy required to remove one electron from a singly charged positive ion in its gaseous state.

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Electronegativity

A measure of the tendency of an atom to attract electrons to itself in a chemical bond.

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Metallic character

The tendency of an element to lose electrons and form positive ions.

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Octet rule

The principle stating that atoms tend to gain or lose electrons to achieve a stable electron configuration, usually with eight valence electrons like noble gases.

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Lewis symbol

A representation of an atom's valence electrons using dots around its symbol.

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Lewis structure

A representation of a molecule showing the bonding and nonbonding electrons as dots or lines.

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Valence electrons

The electrons that occupy the outermost energy level of an atom and participate in chemical bonding.

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Covalent bond

A chemical bond formed by the sharing of electron pairs between atoms.

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Ionic bond

A chemical bond formed by the electrostatic attraction between oppositely charged ions.

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What is the nucleus of an atom?

The center of an atom, containing protons and neutrons.

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What are the categories of Potassium and Chlorine?

Potassium is a metal due to its tendency to lose electrons, while chlorine is a nonmetal due to its tendency to gain electrons.

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What is the empirical formula of the compound formed by Aluminum and Sulfur?

Aluminum forms a +3 cation (Al3+) and sulfur forms a -2 anion (S2-), leading to the empirical formula Al2S3.

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What is the name of SrO?

The correct name for SrO is strontium oxide, following the naming rules for ionic compounds.

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What is the name of PCl3?

PCl3 is named phosphorus trichloride, indicating three chlorine atoms bonded to a phosphorus atom.

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What is the formula for ammonium carbonate?

Ammonium carbonate has the formula (NH4)2CO3, as ammonium is a polyatomic cation and carbonate is a polyatomic anion.

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What is the name of CrCl3?

CrCl3 is named chromium (III) chloride, with the Roman numeral indicating chromium's +3 charge.

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Which subatomic particle is the smallest and lightest?

Electrons are the smallest and lightest subatomic particles, being negatively charged and orbiting the nucleus.

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How many electrons, protons, and neutrons are in an atom of 40Ar?

An atom of 40Ar has 18 electrons, 18 protons, and 22 neutrons (40 - 18 = 22).

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What are isotopes?

Isotopes are atoms of the same element with the same number of protons but differing numbers of neutrons.

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Study Notes

Atomic Structure and Composition

  • Atoms contain protons, neutrons, and electrons
  • Protons and neutrons are located in the nucleus
  • Electrons orbit the nucleus

Identifying Elements

  • Potassium is a metal
  • Chlorine is a nonmetal
  • Aluminum and Sulfur combine to form Al₂S₃

Chemical Formulas and Names

  • SrO is called strontium oxide
  • PCl₃ is phosphorous trichloride
  • Ammonium carbonate's formula is (NH₄)₂CO₃

Subatomic Particles

  • Electrons are the smallest and lightest subatomic particles

Isotopes

  • Isotopes have the same number of protons but different numbers of neutrons

Atomic Mass

  • The average atomic mass of silicon (Si) is 28.1 amu
  • Elements in the same group exhibit similar chemical properties

Chemical Bonding

  • Ionic compounds form from the transfer of electrons between atoms

Quantum Numbers

  • Quantum numbers (n, l, ml, ms) describe the properties of electrons in an atom

Electron Configurations

  • The electron configuration of nitrogen is 1s²2s²2p³
  • The electron configuration of zinc (Zn) is [Ar] 4s²3d¹⁰
  • The electron configuration of Nickel is [Ar] 4s²3d⁸

Atomic Structure

  • Orbitals are regions of space where electrons are likely to be found

Radioactivity

  • Radioactivity is the spontaneous emission of energy in the form of radiation by some atomic nuclei

Periodic Table Arrangement

  • Elements on the periodic table are arranged by increasing atomic number

Predicting Ionic Compounds

  • Empirical formulas predict the simplest ratio of ions in an ionic compound

Electromagnetic Radiation

  • Wavelength and frequency are inversely related

Subatomic Particles: Protons, Neutrons, and Electrons

  • Atoms contain protons, neutrons, and electrons
  • Protons: Positively charged particles. Neutrons: Neutral. Electrons: Negatively charged particles found outside the nucleus.

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