Chemistry Chapter 6: The Periodic Table

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Questions and Answers

Which statement about ionization energy is true?

  • Ionization energy decreases as you move down a group. (correct)
  • Ionization energy increases as you move down a group.
  • Ionization energy is constant across a period.
  • Ionization energy is the energy required to add an electron.

The second ionization energy of an element is always lower than the first ionization energy.

False (B)

What is the term used to describe the energy required to remove an electron from a gaseous atom?

Ionization energy

As nuclear charge increases, the ionization energy tends to __________.

<p>increase</p> Signup and view all the answers

Which of the following elements has the highest first ionization energy?

<p>Ne (D)</p> Signup and view all the answers

Ionization energy generally decreases from left to right across a period.

<p>False (B)</p> Signup and view all the answers

What happens to ionization energy as more electrons are removed from an atom?

<p>It increases.</p> Signup and view all the answers

Who arranged elements according to increasing atomic mass in the mid-1800s?

<p>Dmitri Mendeleev (C)</p> Signup and view all the answers

The modern periodic table is arranged according to increasing atomic mass.

<p>False (B)</p> Signup and view all the answers

What is the Periodic Law?

<p>When elements are arranged in order of increasing atomic number, there is a periodic repetition of their physical and chemical properties.</p> Signup and view all the answers

Elements on the periodic table are organized into horizontal rows called ______.

<p>periods</p> Signup and view all the answers

What significant flaw did Mendeleev's periodic table have?

<p>It had pairs of elements that were incorrectly placed. (D)</p> Signup and view all the answers

Match the following scientists with their contributions to the periodic table:

<p>Dmitri Mendeleev = First periodic table based on atomic mass Henry Moseley = Periodic table based on atomic number J.W. Dobereiner = Triads of elements based on similar properties John Dalton = Early theories of atomic structure</p> Signup and view all the answers

There are ______ periods in the periodic table.

<p>7</p> Signup and view all the answers

What are the three broad classes of elements mentioned?

<p>Metals, nonmetals, and metalloids.</p> Signup and view all the answers

Which of the following are classes of elements found in the periodic table?

<p>Metalloids (A), Nonmetals (B), Metals (D)</p> Signup and view all the answers

Nonmetals are generally good conductors of electricity.

<p>False (B)</p> Signup and view all the answers

What is the main characteristic of noble gases in terms of their reactivity?

<p>They are very stable and rarely react.</p> Signup and view all the answers

The element _______ is a fuming dark red liquid nonmetal.

<p>Bromine</p> Signup and view all the answers

Match the following classes of elements with their characteristics:

<p>Metals = Good electrical conductors Nonmetals = Brittle and poor conductors Metalloids = Intermediate properties Noble Gases = Inert with full electron configurations</p> Signup and view all the answers

Which groups are classified as representative elements?

<p>1A to 2A and 3A to 8A (A)</p> Signup and view all the answers

Metals are typically ductile and malleable.

<p>True (A)</p> Signup and view all the answers

What is the electron configuration of noble gases?

<p>The outer s and p sublevels are completely full.</p> Signup and view all the answers

Which of the following statements about noble gases is true?

<p>Noble gases have 8 valence electrons. (D)</p> Signup and view all the answers

Alkali metals have 2 valence electrons.

<p>False (B)</p> Signup and view all the answers

What is the electron configuration for Argon?

<p>1s2 2s2 2p6 3s2 3p6</p> Signup and view all the answers

Atoms form ions to achieve __________ gas configuration.

<p>noble</p> Signup and view all the answers

Match the following blocks with their respective characteristics:

<p>s-block = Includes alkali and alkaline earth metals p-block = Contains halogens and noble gases d-block = Transition metals that fill d orbitals f-block = Inner transition elements</p> Signup and view all the answers

Which of the following elements is an alkaline earth metal?

<p>Calcium (C)</p> Signup and view all the answers

The first d orbital, 3d, fills up in period 3.

<p>False (B)</p> Signup and view all the answers

Which statement accurately describes alkali metals?

<p>They lose 1 electron to form positive ions. (D)</p> Signup and view all the answers

Electronegativity increases as you move down a group in the periodic table.

<p>False (B)</p> Signup and view all the answers

What are valence electrons?

<p>Electrons in the outermost energy level.</p> Signup and view all the answers

What phenomenon occurs when outermost electrons are blocked from the nucleus by inner electron layers?

<p>Shielding effect</p> Signup and view all the answers

The atomic radius generally _____ from left to right across a period.

<p>decreases</p> Signup and view all the answers

Match the following groups of elements with their tendency regarding electron loss or gain:

<p>Alkali Metals = Lose 1 electron Alkaline-Earth Metals = Lose 2 electrons Halogens = Gain 1 electron Noble Gases = Do not gain or lose electrons</p> Signup and view all the answers

Which factor primarily influences periodic trends in atomic radius?

<p>All of the above (D)</p> Signup and view all the answers

As you go down a group in the periodic table, atoms generally become smaller.

<p>False (B)</p> Signup and view all the answers

What happens to the size of atoms as you increase atomic number down a group?

<p>Atoms get bigger.</p> Signup and view all the answers

Which element has a greater nuclear charge compared to hydrogen?

<p>Helium (B)</p> Signup and view all the answers

Oxygen has a higher first ionization energy than nitrogen.

<p>False (B)</p> Signup and view all the answers

What is the electronegativity of fluorine?

<p>4.0</p> Signup and view all the answers

The first ionization energy of lithium is lower than that of _____.

<p>hydrogen</p> Signup and view all the answers

Match the elements with their corresponding first ionization energy trend:

<p>Helium = Highest Hydrogen = Lower than He Lithium = Lower than H Beryllium = Higher than Li</p> Signup and view all the answers

Which element has a lower first ionization energy than beryllium?

<p>Boron (C)</p> Signup and view all the answers

Neon has a higher first ionization energy than helium.

<p>False (B)</p> Signup and view all the answers

What trend occurs in electronegativity on the periodic table?

<p>Increases from left to right and decreases from top to bottom.</p> Signup and view all the answers

The measure of how strongly an atom attracts electrons when in a compound is called _____.

<p>electronegativity</p> Signup and view all the answers

Which factor primarily contributes to the increase in ionization energy from lithium to beryllium?

<p>Greater nuclear charge (C)</p> Signup and view all the answers

Li has the same shielding effect as Be.

<p>True (A)</p> Signup and view all the answers

What significantly affects the first ionization energy of sodium compared to lithium?

<p>Increased shielding and distance from nucleus.</p> Signup and view all the answers

Fluorine is the most ______________ element.

<p>electronegative</p> Signup and view all the answers

Flashcards

What is the Periodic Law?

The idea that when elements are arranged in order of increasing atomic number, there is a repeating pattern in their physical and chemical properties.

What is a Period on the periodic table?

Horizontal rows of elements in the periodic table. Each row represents elements with the same number of electron shells.

What is a Group on the periodic table?

Vertical columns of elements on the periodic table with similar chemical properties because they have the same number of valence electrons. There are 18 groups.

Who is Dmitri Mendeleev?

A Russian chemist who arranged elements in order of increasing atomic mass, creating the first periodic table.

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Who is Henry Moseley?

A British physicist who rearranged elements in the periodic table by atomic number, making it more accurate.

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How is the Periodic Table organized?

The arrangement of elements in the periodic table based on their atomic number, which results in a periodic repetition of their properties.

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What are triads?

A set of three elements with similar properties, where the middle element has properties in between the other two. This was an early attempt at organizing elements.

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What is an Atomic Number?

The atomic number of an element is the number of protons in its nucleus. It determines the element's identity and its position on the periodic table.

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Metals

Elements that are good conductors of heat and electricity, have luster, are malleable and ductile. Examples include copper, gold and iron.

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Nonmetals

Elements that are poor conductors of heat and electricity, are typically brittle, and may be gases, liquids or solids.

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Metalloids

Elements that have properties that fall in between metals and nonmetals.

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Valence Electrons

The outermost energy level of an atom that contains electrons. The number of valence electrons determines an element's reactivity.

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Group (Family) on the Periodic Table

A group of elements in the periodic table that have similar chemical properties due to having the same number of valence electrons, and thus react in similar ways.

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Period

A horizontal row of elements in the periodic table. Elements in the same period have the same number of electron shells.

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Representative Elements

Elements located in groups 1A through 7A or 1, 2, 13-17 on the periodic table. They have a wide range of reactivity and are essential for many biological and industrial processes.

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Alkali and Alkaline Earth Metals

Elements in groups 1A and 2A of the periodic table, known for being highly reactive and readily losing electrons to form positive ions.

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Periodic Table Groups and Valence Electrons

All elements in the same vertical column of the periodic table have the same number of valence electrons, resulting in similar chemical behavior.

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Core Electrons

The electrons in the inner energy levels of an atom, not involved in chemical bonding. They are closer to the nucleus and shielded from external interactions.

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Ion Formation

Atoms gain or lose electrons to achieve a stable, noble gas configuration. This results in the formation of positively charged ions (cations) or negatively charged ions (anions).

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Ionization

The process of atoms gaining or losing electrons to become ions.

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Alkali Metals

Group 1 elements in the periodic table, characterized by having one valence electron.

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Alkaline Earth Metals

Group 2 elements in the periodic table, characterized by having two valence electrons. They are less reactive than alkali metals.

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Noble Gases

Group 18 elements in the periodic table, characterized by having a full outer shell of electrons (octet). This makes them very stable and unreactive.

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Ionization Energy (First IE)

The amount of energy required to remove one electron from a gaseous atom.

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Second Ionization Energy

The energy required to remove the second electron from a gaseous atom.

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Second IE Trend

Always greater than the first ionization energy.

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Third Ionization Energy

The amount of energy required to remove the third electron from a gaseous atom.

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Nuclear Charge Impact

The greater the nuclear charge (protons), the greater the ionization energy.

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Shielding Effect

The more occupied energy levels (shells) between the nucleus and outer electrons, the lower the ionization energy.

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Ionization Energy Trend (Down Group)

As you go down a group in the periodic table, the first ionization energy decreases.

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Ionization Energy Trend (Across Period)

As you go across a period in the periodic table, the ionization energy generally increases.

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Atomic Radius

A measure of the size of an atom, defined as half the distance between the nuclei of two identical atoms bonded together.

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Electronegativity

The tendency of an atom to attract electrons towards itself when it is forming a chemical bond.

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Ionization Energy

The energy required to remove one electron from a neutral gaseous atom.

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Ionic Radius

The distance between the nucleus and the outermost electron in an ion.

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Group Trends

Elements in the same vertical column of the periodic table, characterized by similar chemical properties due to having the same number of valence electrons.

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Period Trends

Elements in the same horizontal row of the periodic table, characterized by varying chemical properties as they move across the table.

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First Ionization Energy

The amount of energy required to remove one mole of electrons from one mole of gaseous atoms in their ground state.

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Valence Shell

The outermost energy level of an atom, containing the valence electrons.

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Effective Nuclear Charge

A measure of the attraction between the nucleus and the valence electrons.

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Atomic Size

The distance between the nucleus and the outermost electrons.

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Period Trend of First Ionization Energy

As you move across a period, the first ionization energy generally increases.

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Group Trend of First Ionization Energy

As you move down a group, the first ionization energy generally decreases.

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Exceptions to the Period Trend of First Ionization Energy

The first ionization energy of the elements generally increases as you move across a period, with some exceptions due to electron configuration.

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Explanations for the Group Trend of First Ionization Energy

The first ionization energy of the elements generally decreases as you move down a group, due to the increasing distance between the nucleus and the valence electrons.

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Stability of Half-Filled or Fully-Filled Subshells

The first ionization energy is generally lower for elements with half-filled or fully-filled subshells due to their greater stability.

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Exception to the Period Trend of First Ionization Energy: Nitrogen

The first ionization energy of nitrogen is lower than that of oxygen because the removal of an electron from nitrogen results in a half-filled p subshell, which is more stable.

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Exception to the Period Trend of First Ionization Energy: Oxygen

The first ionization energy of fluorine is higher than that of oxygen because the removal of an electron from oxygen results in a more stable electron configuration, with two electrons in each p orbital.

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Period Trend of Electronegativity

As you move across a period, the electronegativity generally increases.

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Group Trend of Electronegativity

As you move down a group, the electronegativity generally decreases.

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Study Notes

Chapter 6: "The Periodic Table"

  • The periodic table organizes elements based on their properties.
  • Initially, only about 13 elements were identified by 1700.
  • Chemists sought a systematic way to organize increasing numbers of discovered elements.
  • Early attempts like Dobereiner's triads grouped elements with similar properties.
  • In the mid-1800s, Dmitri Mendeleev's table organized elements by increasing atomic mass.
  • Mendeleev left spaces for undiscovered elements and predicted their properties accurately.
  • Henry Moseley, in 1913, arranged elements by increasing atomic number, which is the foundation of the modern periodic table.
  • The modern periodic table includes elements' symbols, atomic numbers, and atomic masses.

Section 6.1: Organizing the Elements

  • Objectives included explaining how elements are organized in a periodic table, comparing early and modern periodic tables, and identifying three broad classes of elements.
  • Chemists used the properties of elements to group them.
  • Elements like gold and copper have been known for thousands of years, while most others were discovered later.

Section 6.2: Classifying the Elements

  • Objectives included describing information in a periodic table, classifying elements based on electron configuration, distinguishing representative and transition metals.
  • The periodic table organizes elements according to their electron configurations.
  • Objectives included describing trends in atomic size, explaining how ions form, and describing periodic trends for first ionization energy, ionic size, and electronegativity.
  • Atomic size trends are affected by energy levels, nuclear charge, and shielding.
  • Ionization energy is the energy to remove an electron from a gaseous atom.
  • Trends in ionization energy are influenced by nuclear charge, shielding, and distance from the nucleus.
  • Electronegativity is the measure of how strongly an atom attracts electrons in a compound.
  • Electronegativity generally increases across a period from left to right but is lower for metals, who donate electrons, in comparison to nonmetals who prefer to accept electrons and in metals.

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