Chemical Industry Processes and Catalysts Quiz
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Questions and Answers

What is the main product obtained from cracking large petroleum molecules?

  • Ethanol
  • Propylene
  • Methanol
  • Gasoline (correct)
  • Which process yields high amounts of ethylene?

  • Syngas purification
  • Methanol synthesis
  • Catalytic cracking
  • Thermal cracking (correct)
  • What is the main product of methanol synthesis?

  • $C_3$ alcohols
  • $C_4$ alcohols
  • Methanol (correct)
  • Ethanol
  • Which feedstocks can be used in the Fischer-Tropsch (F-T) synthesis process to produce liquid hydrocarbons?

    <p>Natural gas, biomass, and coal</p> Signup and view all the answers

    What is the aim of the syngas purification step in the Fischer-Tropsch (F-T) synthesis process?

    <p>To remove impurities from syngas before the F-T reaction</p> Signup and view all the answers

    What is the main purpose of the fluidized catalytic cracking (FCC) process?

    <p>To convert gas oil into gasoline by breaking down large petroleum molecules into smaller hydrocarbons</p> Signup and view all the answers

    Which catalyst is used in the FCC process to increase the selectivity and yield of desired products?

    <p>ZSM-5</p> Signup and view all the answers

    What is the main cause of FCC catalyst deactivation?

    <p>Coke and tar formation</p> Signup and view all the answers

    What are the feedstocks that can be used in the Fischer-Tropsch (F-T) synthesis process?

    <p>Natural gas, coal, and biomass</p> Signup and view all the answers

    What are the 4 steps involved in the Fischer-Tropsch (F-T) synthesis process?

    <p>$1) Production of syngas, 2) Syngas purification, 3) FTS, and 4) Separation and upgrading of products$</p> Signup and view all the answers

    What is the primary purpose of naphtha reforming?

    <p>To increase the octane number of naphtha</p> Signup and view all the answers

    What can high pressure cause in hydrocracking?

    <p>High consumption of H2 and energy</p> Signup and view all the answers

    What can deactivate hydrocracking catalysts?

    <p>High amounts of metals</p> Signup and view all the answers

    What is the typical catalyst used for producing lubricants, diesel, and middle or heavy distillates?

    <p>Base metal oxides of Co, Mo, Ni, or W supported on acid-treated Al2O3, Al2O3-SiO2, or a zeolite</p> Signup and view all the answers

    What is added to the Pt-Re/Al2O3 catalyst to enhance its selectivity in the reforming process?

    <p>Re</p> Signup and view all the answers

    What is the typical catalyst used for naphtha reforming?

    <p>Pt or Pt-Re supported on g-Al2O3</p> Signup and view all the answers

    What is the purpose of hydrocracking?

    <p>To selectively crack polyaromatics to gasoline, diesel fuel, and jet fuel</p> Signup and view all the answers

    What are the commonly used catalysts for producing lubricants, diesel, and middle or heavy distillates?

    <p>Co, Mo, Ni or W base metal oxides</p> Signup and view all the answers

    What is the purpose of catalytic reforming?

    <p>To increase the octane number of the naphtha cut</p> Signup and view all the answers

    What is the effect of high pressure of hydrogen in hydrocracking?

    <p>Causes high consumption of hydrogen and energy</p> Signup and view all the answers

    Which catalyst deactivation mode is not mentioned in the text?

    <p>Attrition</p> Signup and view all the answers

    What is the effect of quinoline on hydrocracking activity?

    <p>Decreases activity</p> Signup and view all the answers

    Why are acid sites and metal sites provided for reforming reactions?

    <p>To improve reaction selectivity</p> Signup and view all the answers

    Which two processes are discussed in Section 4 of the Masters in Energy course?

    <p>Hydrocracking and steam-reforming</p> Signup and view all the answers

    What is the main advantage of hydrocracking over FCC?

    <p>Hydrocracking requires lower temperatures</p> Signup and view all the answers

    Study Notes

    Chemical Industry Processes and Catalysts

    • Methanol is primarily used for the production of formaldehyde in the chemical industry
    • SiO2-Al2O3 catalysts were primarily used in the cracking process practiced 5-6 decades ago, which has been shifted to modern zeolite catalysts
    • The main purpose of the fluidized catalytic cracking (FCC) process is to convert gas oil into gasoline by breaking down large petroleum molecules into smaller hydrocarbons
    • ZSM-5 is a zeolite catalyst used in the FCC process to increase the selectivity and yield of desired products
    • Aromatic hydrogenation is not a typical reaction in Fluid Catalytic Cracking (FCC)
    • The main cause of FCC catalyst deactivation is coke and tar formation
    • In a two-stage FCC process, the first stage operates at high temperature and short residence time, while the second stage operates at low temperature and long residence time
    • The ICI process for methanol production offers advantages such as reduced compression power, longer catalyst life, and larger capacity with single train converter designs, resulting in increased productivity
    • The Fischer-Tropsch (F-T) synthesis process can use natural gas (NG) as one of the feedstocks, along with coal and biomass
    • The Sabatier reaction led to BASF's Co-catalyzed liquid HC synthesis at severe conditions, which was a significant step in the development of the Fischer-Tropsch (F-T) synthesis process
    • The 4 steps involved in the Fischer-Tropsch (F-T) synthesis process are: 1) Production of syngas, 2) Syngas purification, 3) FTS, and 4) Separation and upgrading of products

    Catalytic Processes in Petroleum Refining

    • Pt or Pd supported on shape-selective zeolites, such as Faujasite, Modernite, and ZSM-5, are commonly used as catalysts for producing gasoline from S and N-free feeds.
    • Injection of cold high pressure H2 between the fixed bed reactors in the hydrocracking process is to cool the product stream.
    • Pt or Pt-Re supported on g-Al2O3 with a BET area of 200 m2/g is typically used as a catalyst for naphtha reforming.
    • Hydrocracking is a process that combines cracking and hydrogenation to selectively crack polyaromatics to gasoline, diesel fuel, and jet fuel.
    • The high pressure of hydrogen (80 - 200 atm) in hydrocracking causes high consumption of hydrogen and energy.
    • Hydrocracking is typically processed in the temperature range of 290 - 525 °C.
    • The presence of acid sites and metal sites in the catalyst helps in enhancing the selectivity of the reforming reactions.
    • The main purposes of hydrocracking and catalytic reforming are to reduce the sulfur content in the feedstock and to convert heavy hydrocarbons into lighter, more valuable products such as gasoline.
    • To minimize the formation of light gases and maximize the production of gasoline, suitable desulfurization and denitrification processes need to be implemented.
    • The base metal oxides of Co, Mo, Ni or W are commonly used as catalysts for producing lubricants, diesel, and middle or heavy distillates.
    • The primary purpose of naphtha reforming is to increase the octane number of the naphtha cut.
    • The typical catalyst used for naphtha reforming is Pt or Pt-Re supported on g-Al2O3.

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    Description

    Test your knowledge about chemical industry processes and catalysts with this quiz covering topics such as fluidized catalytic cracking, methanol production, and Fischer-Tropsch synthesis. Explore key concepts including catalyst types, reactions, and process steps.

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