Introduction to Catalysis: M.F. Baidoo
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Questions and Answers

Which process involves the reaction of ethylene with chlorine gas?

  • Epoxidation
  • Hydroformylation
  • Polymerization
  • Viny Chloride formation (correct)
  • Which catalyst is involved in the hydrogenation process?

  • Copper (correct)
  • Manganese
  • Rhodium
  • Vanadium oxide
  • What is the catalyst used in the steam reforming of methane to CO + H2?

  • Nickel (correct)
  • Rhodium
  • Cobalt
  • Platinum
  • What type of catalysis is preferred due to its reproducibility and selectivity?

    <p>Homogeneous Catalysis</p> Signup and view all the answers

    Which metal is involved in the oxidation of carbon monoxide and hydrocarbons, such as car exhaust gases?

    <p>Iron oxide</p> Signup and view all the answers

    What is the main product formed in ethylene epoxidation?

    <p>Ethylene oxide</p> Signup and view all the answers

    In which reaction does the Wacker process play a significant role?

    <p>Wacker reaction itself</p> Signup and view all the answers

    Which catalyst is commonly used in the polymerization of ethylene and propylene?

    <p>$\text{Co-Mo}$</p> Signup and view all the answers

    What type of reaction involves the addition of hydrogen to a compound?

    <p>Hydrogenation</p> Signup and view all the answers

    Which catalyst is commonly used in the epoxidation of ethylene to ethylene oxide?

    <p>Rhodium</p> Signup and view all the answers

    In which process does the Wacker reaction play a significant role?

    <p>Oxidation</p> Signup and view all the answers

    Which type of catalysis involves sites that are not easily separated from the reaction mixture?

    <p>Homogeneous catalysis</p> Signup and view all the answers

    What is the main product formed in the reaction of ethylene with chlorine gas?

    <p>Viny chloride</p> Signup and view all the answers

    Which metal is involved in the ammonium oxidation process to form NO and HNO3?

    <p>Nickel</p> Signup and view all the answers

    Which process involves the addition of a silicon-hydrogen bond to a compound?

    <p>$\text{Hydrosilylation}$</p> Signup and view all the answers

    What is the catalyst commonly used in the hydroformylation process?

    <p>$Co-W$</p> Signup and view all the answers

    What kind of reaction is involved in the formation of chiral products?

    <p>$\text{Asymmetric reactions}$</p> Signup and view all the answers

    Study Notes

    Background on Catalysis

    • Catalysts are essential for chemical transformations in the industry.
    • Approximately 85-90% of chemical products rely on catalytic processes.
    • Catalysts enable industrial processes to operate under feasible pressure conditions.

    Definition of a Catalyst

    • A catalyst accelerates a chemical reaction without changing its structure post-reaction.

    Importance of Catalysts

    • Provide a reaction pathway with lower activation energy.
    • Increase reaction rates.
    • Allow reactions to proceed under conditions where high temperatures and pressures may be impractical.
    • Overcome thermodynamic limitations on product formation.

    Classification of Catalysts

    • By State:
      • Gas, Liquid, Solid
    • By Nature:
      • Inorganic: Includes gases, metals, metal oxides, inorganic acids, and bases.
      • Organic: Comprises organic acids and enzymes.
    • By Phase System:
      • Homogeneous: Soluble catalysts in a single phase, often liquid.
      • Heterogeneous: Different phases involved in the reaction.

    Types of Catalytic Action

    • Acid-base catalysis.
    • Enzymatic/biocatalysis.
    • Photocalysis.
    • Electrocatalysis.

    Applications of Catalysis

    • Catalytic converters are significant in environmental applications to reduce emissions.

    Homogeneous Catalysis in the Chemical/Petrochemical Industry

    • Carbonylation Reactions:
      • Involves reactants like Methanol and CO producing Methyl acetate, among others.
    • Common Products and Metals:
      • Acetic acid, Acetic anhydride, and Methyl methacrylate often use Rhodium (Rh) or Cobalt (Co) as catalysts.
    • Production of Polymers:
      • Various metals such as Palladium (Pd), Rh, and Nickel (Ni) are employed in producing ethylene and propylene.

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    Description

    Learn about the importance of catalysts in chemical transformations. Explore the definition of a catalyst and how it enables industrial processes to be carried out under feasible conditions of pressure.

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