Carbohydrates and Biomolecules Overview
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Questions and Answers

Which statement accurately describes the relationship between galactose and mannose?

  • Galactose and mannose differ in the position of –OH on two different carbons. (correct)
  • Galactose and mannose have identical chemical structures.
  • Galactose and mannose are enantiomers.
  • Galactose and mannose are epimers.

In the D-isomeric form of monosaccharides, which of the following describes the arrangement of the –OH group on C-5?

  • The –OH group is on the right. (correct)
  • The –OH group is on the left.
  • The –OH group is absent on C-5.
  • The –OH group is located at the opposite end of the carbon chain.

What is formed at the anomeric carbon during the cyclization of monosaccharides?

  • A carbonyl carbon that remains unchanged.
  • A new type of glycosidic bond.
  • An enantiomer.
  • The former carbonyl carbon. (correct)

What type of bonds link monosaccharides to form polysaccharides?

<p>Glycosidic bonds. (C)</p> Signup and view all the answers

What configuration defines a glycosidic bond when the anomeric hydroxyl is in the α configuration?

<p>It is specifically an α-bond. (D)</p> Signup and view all the answers

What is an O-glycoside structure characterized by?

<p>The presence of a hydroxyl group as the main functional group (A)</p> Signup and view all the answers

Which of the following is NOT a function of carbohydrates?

<p>Genetic material storage (D)</p> Signup and view all the answers

Which classification of carbohydrates is based on the number of carbon atoms?

<p>Trioses and pentoses (A)</p> Signup and view all the answers

Which characteristic is true regarding carbohydrate isomers?

<p>Isomers share the same chemical formula but differ in structure (D)</p> Signup and view all the answers

How can carbohydrates interact with non-carbohydrate structures?

<p>By glycosidic bonds (C)</p> Signup and view all the answers

Which disaccharide contains a β(1→4) glycosidic bond?

<p>Lactose (D)</p> Signup and view all the answers

What type of glycosidic bond is found in glycogen?

<p>Both B and C (A)</p> Signup and view all the answers

What characterizes reducing sugars?

<p>They can react with chromogenic agents. (B)</p> Signup and view all the answers

Which structure is most abundant in plant cell walls?

<p>Cellulose (A)</p> Signup and view all the answers

Which statement about starch is incorrect?

<p>It is primarily stored in animal tissues. (B)</p> Signup and view all the answers

How are complex carbohydrates typically linked to other molecules?

<p>Using glycosidic bonds. (B)</p> Signup and view all the answers

Which monosaccharide is a part of lactose?

<p>β-galactose (D)</p> Signup and view all the answers

What type of glycosidic bond is characteristic of cellulose?

<p>β(1→4) (B)</p> Signup and view all the answers

In which process is maltose commonly produced?

<p>Starch hydrolysis (B)</p> Signup and view all the answers

What is the primary function of glucose in the human body?

<p>It serves as an important energy source. (D)</p> Signup and view all the answers

What is the empirical formula commonly associated with simple carbohydrates?

<p>(CH2O)n (A)</p> Signup and view all the answers

Which classification of monosaccharides refers to the position of the carbonyl group?

<p>Aldoses and Ketoses (A)</p> Signup and view all the answers

What distinguishes epimers from other isomers?

<p>Epimers differ at one specific carbon atom. (C)</p> Signup and view all the answers

Which of the following sugars is classified as a hexose?

<p>Fructose (B), Galactose (C)</p> Signup and view all the answers

How are the carbon atoms in monosaccharides typically numbered?

<p>Beginning at the end which contains the carbonyl carbon. (B)</p> Signup and view all the answers

Which of the following statements best describes isomers?

<p>Isomers have the same chemical formula but different structures. (D)</p> Signup and view all the answers

What is a common characteristic of carbohydrates?

<p>They serve multiple functions, including energy storage and structural roles. (A)</p> Signup and view all the answers

Which of the following is NOT a characteristic of monosaccharides?

<p>They are always solid at room temperature. (D)</p> Signup and view all the answers

Flashcards

Enantiomers

Mirror images of a monosaccharide molecule that differ in configuration around a single chiral carbon.

D-sugars

The most common form of sugars found in humans. In the D-isomer, the –OH group on *C-5 is on the right.

Cyclization of monosaccharides

Monosaccharides can exist in ring forms. Less than 1% exists in the open-chain form. The formation of the ring creates a new chiral center called the anomeric carbon.

Glycosidic bonds

Bonds that connect sugar molecules in di-, oligo-, or polysaccharides. They are formed by glycosyltransferases.

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Polysaccharides

Polymers of monosaccharides that serve as energy storage (glycogen, starch) or structural components (cellulose).

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O-glycosidic bond

A glycosidic bond where the group attached to the sugar is an -OH group

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O-glycoside

A sugar molecule with an -OH group attached to it, forming a glycosidic bond with another molecule.

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Carbohydrates

The most abundant organic molecules in nature, often composed of carbon, hydrogen, and oxygen.

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Carbohydrate classification

Carbohydrates can be classified based on their number of carbon atoms, the type of sugar subunits, and the presence of functional groups.

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Carbohydrate functions

Carbohydrates play essential roles as energy sources, energy stores, structural components, and recognition molecules.

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Biomolecules

Organic molecules found in living organisms, primarily composed of carbon, hydrogen, oxygen, and nitrogen.

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Monosaccharide

A single sugar unit, the simplest form of a carbohydrate.

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Carbohydrate Classification (Based on Number of Sugars)

Carbohydrates are classified based on the number of sugar units they contain. Monosaccharides are single sugar units, disaccharides are composed of two sugar units, oligosaccharides have a few sugar units, and polysaccharides have many sugar units.

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Monosaccharide Classification (Based on Number of Carbons)

Monosaccharides are classified based on the number of carbon atoms they contain. Trioses have 3 carbons, tetroses have 4 carbons, pentoses have 5 carbons, and hexoses have 6 carbons.

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Monosaccharide Classification (Based on Functional Group)

Monosaccharides are classified based on the position of the carbonyl group (C=O). If the carbonyl group is at the end of the molecule, it is an aldose. If it is in the middle of the molecule, it is a ketose.

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Isomers

Compounds with the same molecular formula but different structural arrangements.

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Epimers

Carbohydrate isomers that differ in configuration at only one specific carbon atom (excluding the carbonyl carbon).

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β-bond

A glycosidic bond formed between two monosaccharides where the hydroxyl group on the anomeric carbon of one monosaccharide is linked to the hydroxyl group on the anomeric carbon of the other monosaccharide.

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Lactose

A disaccharide composed of β-galactose and α-glucose linked by a β(1→4) glycosidic bond. It is the major carbohydrate in milk.

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Maltose

A disaccharide composed of two α-glucose molecules linked by an α(1→4) glycosidic bond. It is produced by the hydrolysis of starch and is used in beer production.

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Sucrose

A disaccharide composed of α-glucose and β-fructose linked by an α(1→2) glycosidic bond. It is common table sugar and the major transport form of sugars in plants.

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Reducing sugar

A sugar that can act as a reducing agent because its anomeric carbon is not linked to another compound. This allows the sugar to open its ring structure and participate in redox reactions.

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Benedict's Test

A chemical test used to detect the presence of reducing sugars. The test relies on the ability of reducing sugars to reduce cupric ions (Cu²⁺) in the reagent to cuprous oxide (Cu₂O), resulting in a color change.

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Glucose

The primary energy source for cells in the human body. It cannot be stored directly due to osmotic effects. Instead, it is stored as glycogen in liver and muscle tissues.

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Glycogen

The animal storage form of glucose, primarily found in liver and muscle cells. It is a branched polymer of glucose with α 1,4 and α 1,6 glycosidic bonds.

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Starch

The storage form of glucose in plants. It is composed of two types of polysaccharides: amylose and amylopectin.

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Cellulose

A structural carbohydrate found in plant cell walls. It is composed of β-glucose units linked by β 1,4 glycosidic bonds. Cellulose is a major component of dietary fiber and is largely indigestible by mammals.

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Study Notes

Carbohydrates

  • Carbohydrates are organic molecules abundant in nature.
  • Their empirical formula often follows (CH₂O)ₙ.
  • They have various functions, including being a dietary requirement and a storage form of energy.
  • They are components of cell membranes and form structural components of many organisms.

Learning Outcomes

  • Students will learn how carbohydrates are classified.
  • Isomers and epimers of carbohydrates will be understood.
  • Glycosidic bond nomenclature will also be understood.
  • The structure and function of various carbohydrates will be appreciated.

Biomolecules

  • Biomolecules are organic molecules created by living organisms.
  • They primarily consist of carbon, hydrogen, oxygen, and nitrogen.
  • Biomolecules include lipids, proteins, carbohydrates, and nucleic acids.

Carbohydrate Classification & Structure

  • Carbohydrates are classified based on the number of sugar units.
  • Monosaccharides are single sugar units.
  • Disaccharides consist of two monosaccharides.
  • Oligosaccharides contain 3-10 monosaccharides.
  • Polysaccharides have more than 10 monosaccharides.
  • Examples of monosaccharides include glucose, fructose, and galactose.
  • Examples of disaccharides include sucrose, lactose, and maltose.

Monosaccharide Classification

  • Monosaccharides are classified by the number of carbon atoms (triose, tetrose, pentose, hexose).
  • Based on the functional group, they can be aldoses (aldehyde group) or ketoses (ketone group).

Isomers

  • Isomers have the same chemical formula but different structures.
  • Examples of isomers include glucose, galactose, and fructose.
  • Epimers are isomers differing at only one asymmetric carbon atom.
  • Enantiomers are nonsuperimposable mirror images.

Cyclization of Monosaccharides

  • Rings are formed by chemical reactions between monosaccharides.
  • This process alters the form of the carbohydrate.
  • The alpha (α) and beta (β) forms change depending on the hydroxyl group position.

Polymerization

  • Monosaccharides link together to create disaccharides.
  • The linkages between sugars are called glycosidic bonds.
  • Important polysaccharides include glycogen, starch, and cellulose.

Naming of Glycosidic Bonds

  • Glycosidic bonds are named based on the anomeric configuration.
  • Alpha (α) bonds occur in one form and beta (β) bonds in another.

Common Disaccharides

  • Sucrose, lactose, and maltose are common disaccharides.
  • Sucrose is composed of glucose and fructose.
  • Lactose is comprised of galactose and glucose.
  • Maltose is composed of two glucose molecules.

Reducing Sugars

  • Reducing sugars have a free hydroxyl group on the anomeric carbon.
  • This allows the sugar to act as a reducing agent.

Glucose - Biomedical Importance

  • Glucose is the primary sugar in humans.
  • It's a vital energy source for cells.
  • Glucose is stored as glycogen in animals.
  • It's also present in nucleotides and nucleic acids.

Polymers of Glucose - Glycogen

  • Glycogen is a storage form of glucose in animals, primarily in muscle and liver tissue.
  • It consists of α(1→4) and α(1→6) glycosidic bonds.

Polymers of Glucose - Starch

  • Starch is a storage form of glucose in plants and comprises two main polysaccharides.
  • The types are amylose and amylopectin.
  • Amylose: linear, α(1→4) glycosidic bonds; while amylopectin is branched, comprising α(1→4) and α(1→6) glycosidic bonds..

Cellulose

  • Cellulose is a structural carbohydrate in plant cell walls.
  • It's formed by β(1→4) glycosidic bonds and is typically indigestible in humans.

Cellulose vs Starch

  • The difference between cellulose and starch lies in the type of glycosidic bonds (α vs. β).
  • This structural difference affects their digestive properties and uses.

Complex Carbohydrates

  • Carbohydrates can be connected to other non-carbohydrate molecules via glycosidic bonds.
  • These connections form essential structures in cells.

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Description

This quiz covers essential concepts about carbohydrates, their classification, and their structural roles as biomolecules. Students will explore the empirical formulas, functionalities, isomers, and nomenclature, enhancing their understanding of these fundamental organic molecules. Prepare to test your knowledge of carbohydrates and their significance in biological systems.

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