BIOL 157: Biological Chemistry Lecture 1

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Questions and Answers

What is the unique property of carbon that allows it to form bonds with itself in various structures?

  • Electron deficiency
  • Catenation (correct)
  • Tetravalency
  • Electronegativity

Why are Si-Si bonds weaker than C-C bonds?

  • Due to the electronegativity of silicon
  • Because silicon has a larger atomic size (correct)
  • Due to smaller atomic size of silicon
  • Because silicon has more valence electrons

What is the reason for the lower bond energy of N-N bonds compared to C-C bonds?

  • Due to the larger atomic size of nitrogen
  • Due to the lone pair of electrons on nitrogen atoms (correct)
  • Due to the electronegativity of nitrogen
  • Because nitrogen has more valence electrons

What is the term for the ability of an element to form three or more bonds and produce chains of covalent bonds?

<p>Catenation (D)</p> Signup and view all the answers

Which of the following elements can produce three or more bonds and form chains of covalent bonds?

<p>Si, N, and B (D)</p> Signup and view all the answers

What is the term for the combining power of an element?

<p>Valency (C)</p> Signup and view all the answers

What is the primary use of cyclotrons in producing high-energy particles?

<p>To accelerate particles to high speed (B)</p> Signup and view all the answers

How many elements are recognized as essential to cells?

<p>32 (C)</p> Signup and view all the answers

What percentage of the mass of most cells is made up of 6 elements?

<p>99% (B)</p> Signup and view all the answers

What is the most versatile and predominant element in cells?

<p>Carbon (C)</p> Signup and view all the answers

What type of bonds can the major elements form?

<p>Covalent bonds (D)</p> Signup and view all the answers

What is similar between the composition of the Earth and its atmosphere compared to the human body?

<p>Elemental composition (B)</p> Signup and view all the answers

What percentage of groups on the periodic table have their representatives in living cells?

<p>83% (A)</p> Signup and view all the answers

Why are f-block elements excluded from living cells?

<p>They are not essential for cellular functions (C)</p> Signup and view all the answers

Why are elements with atomic numbers above 92 excluded from living cells?

<p>They are artificial (D)</p> Signup and view all the answers

What is the reason for the exclusion of lead from living cells?

<p>It is toxic to the cell (C)</p> Signup and view all the answers

Why are rare gases like helium and neon excluded from living cells?

<p>They are inert (D)</p> Signup and view all the answers

What is a beneficial use of radioactive elements in living cells?

<p>They provide valuable medical treatments (B)</p> Signup and view all the answers

What is the name of the course instructor for BIOL 157: Biological Chemistry?

<p>Seth Agyei Domfeh (D)</p> Signup and view all the answers

What is the definition of a living cell?

<p>An active cell that contains organised structures responsible for its function (B)</p> Signup and view all the answers

What are the building blocks of an organism?

<p>Atoms/Elements (C)</p> Signup and view all the answers

How were elements formed according to the Big Bang Theory?

<p>Only hydrogen and helium were formed (A)</p> Signup and view all the answers

What is required for the formation of elements in the core of stars?

<p>Very high temperatures and concentrations of reactants (C)</p> Signup and view all the answers

What is the largest atom that can be formed from nuclear fusion reaction?

<p>Iron (B)</p> Signup and view all the answers

How are elements with odd mass numbers produced?

<p>Via side-stream fusion reactions (C)</p> Signup and view all the answers

What is the name of the process that occurs when the nuclei of Fe atoms capture neutrons resulting from the explosion of a star?

<p>Neutron capture (B)</p> Signup and view all the answers

Why is carbon unique in its ability to form many compounds?

<p>This information is not provided in the text (D)</p> Signup and view all the answers

What is the name of the process by which new elements with atomic numbers beyond 92 are synthesised in the laboratory?

<p>Artificial synthesis (C)</p> Signup and view all the answers

Flashcards

Catenation

Carbon's ability to form strong bonds with itself, leading to the formation of long chains, branched structures, and rings.

Multiple Bonding in Carbon

Carbon's capacity to form single, double, or triple bonds with itself and other elements. This creates a diverse range of organic compounds.

Tetravalency of Carbon

Carbon is a group 14 element that has four valence electrons, enabling it to form four covalent bonds.

Why Silicon is Less Diverse than Carbon

Silicon, like carbon, is in group 14. However, Si-Si bonds are weaker due to silicon's larger atomic size.

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Boron's Electron-Deficiency

Boron has three valence electrons, making it electron-deficient and limiting the stability of its compounds.

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Nitrogen's Lone Pair Effect

Nitrogen has five valence electrons, but its lone pair electrons weaken the bond strength in its compounds. This limits its diversity in comparison to carbon.

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Essential Elements in Cells

The building blocks of life, cells contain approximately 32 elements that are essential for their functions.

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Major Elements in Cells

These major elements (C, H, O, N, P, and S) make up over 99% of the mass of a cell.

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Carbon's Importance in Cells

Carbon is the most versatile and abundant element in cells due to its unique properties.

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Minor Elements in Cells

These include Na, Mg, Ca, B, V, Mo, Mn, Fe, Co, Ni, Cu, Zn, Si, Se, Cl, Cr, and I. They are crucial for specific cell functions.

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p-Block Dominance in Cells

Most major elements in cells belong to the p-block of the periodic table.

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Covalent Bonding in Cells

The major elements in cells primarily form covalent bonds, sharing electrons to achieve stability.

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Non-Metallic Nature of Major Elements

Most major elements in cells are classified as non-metals, lacking the typical characteristics of metals.

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Size and Number Significance in Major Elements

They tend to have smaller atomic sizes or lower atomic numbers, influencing their bonding behavior.

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Goldilocks Principle in Major Elements

These elements are neither too reactive, causing instability, nor inert, preventing interactions. This balance allows for efficient functioning within cells.

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Functions of Minerals

Minerals are inorganic substances with specific functions in the body. These functions can include building strong bones and teeth, aiding in muscle contraction, and regulating fluid balance.

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Earth's Influence on Human Composition

The Earth's composition and atmosphere are remarkably similar to the human body, influencing the types of elements present within us.

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Chemical Democracy in Cells

The diversity of elements found in living cells reflects the presence of elements from almost every group within the periodic table.

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Artificial Elements

These elements are created in laboratories and are not naturally occurring.

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Inert Nature of Elements

Rare gases and some scarce elements like actinides and lanthanides are chemically unreactive and less likely to readily participate in cellular processes.

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Toxic Elements

Certain elements can have harmful effects on cells, disrupting their normal functions and leading to toxicity.

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Radioactive Nature of Elements

Radioactive elements emit particles or radiation that can damage cellular structures and DNA, leading to potential health risks.

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Big Bang Theory

This model posits that the universe began as a single, incredibly hot and dense point of matter that expanded rapidly, leading to the formation of elements.

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Stellar Hypothesis

Elements heavier than hydrogen and helium are believed to have formed through nuclear fusion reactions within stars and released into the universe upon stellar explosions.

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Artificial Synthesis of Elements

Scientists have synthesized new elements with atomic numbers beyond 92 in laboratories through controlled nuclear reactions.

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Study Notes

Carbon's Unique Properties

  • Carbon has an ideal size, allowing it to form stable covalent bonds.
  • Carbon has the power of catenation, forming bonds with itself in straight chains, branches, or rings.
  • Carbon can form multiple bonds with itself or other elements, providing a variety of organic compounds.
  • Carbon has tetravalency.

Comparison with Other Elements

  • Silicon is a congener of carbon, but Si-Si bonds are weak due to its larger atomic size.
  • Boron has three valence electrons, forming electron-deficient compounds that limit boron compounds' stability.
  • Nitrogen has five valence electrons, with a relatively lower bond energy due to lone pair electrons.

Elements in Cells

  • About 32 elements are recognized as essential to cells.
  • Over 99% of cell mass is made up of six major/bulk elements: C, H, O, N, P, and S.
  • Carbon is the most versatile and predominant in the cell.
  • Minor or trace elements include Na, Mg, Ca, B, V, Mo, Mn, Fe, Co, Ni, Cu, Zn, Si, Se, Cl, Cr, and I.

Features of Major Elements

  • They are mostly p-block elements.
  • They can form covalent bonds.
  • They are non-metals.
  • They have smaller atomic sizes or numbers.
  • They are neither too reactive nor inert (unreactive).

Functions of Minerals in the Body

  • Various minerals have distinct functions in the body.

Factors for Inclusion of Elements in Cells

  • The composition of the Earth and its atmosphere is similar to that of the human body.
  • Chemical democracy: almost every group on the periodic table has its representative in living cells.

Factors for Exclusion of Elements in the Cells

  • Artificial nature: elements with atomic numbers above 92 are made.
  • Inert nature: rare gases and scarce elements like actinides and lanthanides.
  • Toxic nature: certain elements can cause harm to cells.
  • Radioactive nature: radioactive elements give off particles or radiations that could harm cells.

Origin of Elements

  • The Big Bang theory: elements are believed to be formed from an infinitely hot and dense ball of primordial matter.
  • Fusion reactions in stars (Stellar hypothesis): elements other than hydrogen and helium were formed in the center of stars and released upon their explosion.
  • Artificial synthesis (laboratory synthesis): new elements with atomic numbers beyond 92 have been synthesized in the laboratory.

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