AQA Chemistry A-level 3.1.2 Amount of Substance Notes PDF

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These detailed notes cover the AQA Chemistry A-level topic 3.1.2: Amount of Substance. Topics include relative atomic/molecular mass, moles, Avogadro's constant, ideal gas equation, empirical/molecular formulas, and equations.

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AQA Chemistry A-level 3.1.2: Amount of Substance Detailed Notes This work by PMT Education is licensed under https://bit.ly/pmt-cc https://bit.ly/pmt-edu-cc CC BY-NC-ND 4.0...

AQA Chemistry A-level 3.1.2: Amount of Substance Detailed Notes This work by PMT Education is licensed under https://bit.ly/pmt-cc https://bit.ly/pmt-edu-cc CC BY-NC-ND 4.0 https://bit.ly/pmt-cc https://bit.ly/pmt-edu https://bit.ly/pmt-cc 3.1.2.1 - Mr and Ar Relative atomic mass (​Ar​) is defined as: The mean mass of an atom of an element, divided by one twelfth of the mean mass of an atom of the carbon-12 isotope. Relative molecular mass (​Mr​) is defined as: The mean mass of a molecule of a compound, divided by one twelfth of the mean mass of an atom of the carbon-12 isotope. For ionic compounds, is it known as ​relative formula mass​. 3.1.2.2 - Moles and the Avogadro Constant The mole is a ​unit of measurement​ for substances. It always contains the ​same number of particles​. This number is the ​Avogadro Constant​ (L) and allows the number of particles present in a sample of a substance with known mass to be found: (n = moles) (L = Avogadro constant) The mole is a ​very important unit of measurement​ in many calculations: (where concentration is in moldm​-3​) https://bit.ly/pmt-cc https://bit.ly/pmt-edu https://bit.ly/pmt-cc 3.1.2.3 - Ideal Gas Equation When under ​standard conditions​, gases and volatile liquids follow certain trends: pressure is proportional to temperature volume is proportional to temperature pressure and volume are inversely proportional These relationships can be combined to give the ​ideal gas equation​: In order to use this equation, the variables must be in the correct ​standard units​: p = pressure in Pascals V = volume in m​3 T = temperature in Kelvin n = moles m = mass in grams R​ is the ​ideal gas constant​, equal to ​8.31 JK​-1​mol​-1​. 3.1.2.4 - Empirical and Molecular Formula Empirical formula is the ​simplest whole number ratio​ of atoms of each element in a compound. It is found using ​molar ratios​ of each element. (see model answer) Molecular formula is the ​true number of each atom in the molecule​. It can be determined using the ​Mr of the empirical formula​ and the ​true Mr​ of the molecule. This gives a ​multiplier value which can be used to scale up the empirical formula. (see model answer) https://bit.ly/pmt-cc https://bit.ly/pmt-edu https://bit.ly/pmt-cc 3.1.2.5 - Equations and Calculations Chemical equations must be ​balanced​ before they can be used in calculations. This is because the ​reacting ratios​ must be correct. It can then be used to calculate reacting masses, percentage yield and atom economy. Percentage Yield Atom Economy In industrial chemical processes it is desirable to have a ​high atom economy​ for a reaction. This means there is​ little or no waste product​, only the desired product. Therefore it means the process is more ​economically viable​ for industrial scale manufacture. Having a high atom economy is also beneficial for the environment as it uses less natural resources and therefore often uses less energy. https://bit.ly/pmt-cc https://bit.ly/pmt-edu https://bit.ly/pmt-cc

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