Chemistry Chapter on Moles and Mass
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Questions and Answers

What does the empirical formula represent?

  • A random arrangement of atoms
  • The simplest whole number ratio of atoms of each element (correct)
  • The molecular weight of a substance
  • The actual number of atoms in a molecule

The molecular formula is derived from the empirical formula and the actual molar mass of the molecule.

True (A)

What is typically calculated using balanced chemical equations?

Reacting masses, percentage yield, and atom economy.

A high atom economy signifies that there is little or no ______ in a chemical reaction.

<p>waste product</p> Signup and view all the answers

Match the terms with their definitions:

<p>Empirical formula = Simplest ratio of elements Molecular formula = Actual number of atoms in a molecule Atom economy = Efficiency of a chemical process Percentage yield = Actual yield compared to theoretical yield</p> Signup and view all the answers

Why is balancing chemical equations important?

<p>To ensure the reacting ratios are correct (C)</p> Signup and view all the answers

An empirical formula can have multiple molecular formulas that correspond to it.

<p>True (A)</p> Signup and view all the answers

What is a benefit of high atom economy?

<p>It uses fewer natural resources and produces less waste.</p> Signup and view all the answers

The multiplier value used to calculate the molecular formula is derived from the ratio of the ______ of the empirical formula to the ______ of the molecule.

<p>Mr / true Mr</p> Signup and view all the answers

Which formula provides the correct ratio of components in a compound?

<p>Empirical formula (D)</p> Signup and view all the answers

What is the relative atomic mass (Ar) defined as?

<p>The mean mass of an atom of an element, divided by one twelfth of the mean mass of an atom of the carbon-12 isotope. (D)</p> Signup and view all the answers

Relative molecular mass (Mr) is applicable to ionic compounds only.

<p>False (B)</p> Signup and view all the answers

What unit of measurement is used for the amount of substance?

<p>mole</p> Signup and view all the answers

The constant that allows for the determination of the number of particles in a mole is called the __________.

<p>Avogadro Constant</p> Signup and view all the answers

Match the following variables with their meanings in the ideal gas equation:

<p>p = Pressure in Pascals V = Volume in m³ T = Temperature in Kelvin n = Moles</p> Signup and view all the answers

What must be the unit of pressure when using the ideal gas equation?

<p>Pascals (D)</p> Signup and view all the answers

The ideal gas constant (R) is equal to 8.31 JK⁻¹mol⁻¹.

<p>True (A)</p> Signup and view all the answers

Under standard conditions, pressure and volume are __________ proportional.

<p>inversely</p> Signup and view all the answers

The ideal gas equation can be represented as PV = nRT, where R is the __________ constant.

<p>ideal gas</p> Signup and view all the answers

The given formula for moles (n) can be written as:

<p>n = PV/RT (D)</p> Signup and view all the answers

Flashcards

Relative Atomic Mass (Ar)

The average mass of an atom of an element, relative to one-twelfth the mass of a carbon-12 atom.

Relative Molecular Mass (Mr)

The average mass of a molecule of a compound, relative to one-twelfth the mass of a carbon-12 atom.

Mole

The unit of measurement for substances, representing a specific number of particles.

Avogadro Constant

The number of particles in one mole of any substance, approximately 6.022 x 10^23.

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Number of Moles (n)

The number of particles in a sample of a substance, calculated by dividing the mass of the sample by the molar mass.

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Molar Mass

The mass of one mole of a substance, expressed in grams per mole (g/mol).

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Ideal Gas Equation

The relationship between pressure, volume, temperature, and the number of moles of an ideal gas.

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Ideal Gas

A gas that obeys the ideal gas equation, with no intermolecular forces and negligible volume of molecules.

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Pressure (p)

The pressure exerted by a gas under standard conditions.

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Volume (V)

The volume occupied by a gas under standard conditions.

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Empirical Formula

The simplest whole number ratio of atoms in a compound. Found by analyzing the molar ratios of each element.

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Molecular Formula

The true number of each atom in a molecule. Determined using Mr of the empirical formula and the true Mr of the molecule.

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Balancing Chemical Equations

The process of ensuring that the number of atoms of each element on the reactant and product sides of a chemical equation are equal.

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Reacting Ratios

The ratio in which reactants combine to form products in a balanced chemical equation.

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Percentage Yield

The percentage of the total mass of reactants that is converted into the desired product in a chemical reaction.

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Atom Economy

A measure of how efficiently the atoms in reactants are used to create the desired product in a chemical reaction.

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High Atom Economy

A chemical reaction with a high atom economy produces a large percentage of the desired product with minimal waste.

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Benefits of High Atom Economy

High atom economy reduces waste and resource consumption, making chemical processes more environmentally friendly and cost-effective.

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Economically Viable

A process is economically viable if it can generate profits while minimizing its environmental impact.

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Environmental Benefits of High Atom Economy

High atom economy minimizes the use of natural resources and energy, making the process more sustainable and less harmful to the environment.

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Study Notes

Relative Atomic Mass (Ar)

  • Defined as the mean mass of an atom of an element, divided by one-twelfth the mean mass of a carbon-12 atom.

Relative Molecular Mass (Mr)

  • Defined as the mean mass of a molecule of a compound, divided by one-twelfth the mean mass of a carbon-12 atom.
  • For ionic compounds, it's known as relative formula mass.

Moles and the Avogadro Constant

  • The mole is a unit of measurement for substances, containing a constant number of particles.
  • Avogadro's constant (L) = 6.022 x 1023 particles.
  • The number of particles in a substance can be calculated using the formula: Number of particles = nL (where n = moles and L = Avogadro's constant).
  • Moles are crucial in various calculations, including those involving mass, concentration, and volume: Moles = mass/Mr = concentration x volume/1000 (where concentration is in mol/dm³).

Ideal Gas Equation

  • Under standard conditions, gases and volatile liquids follow certain trends: pressure is proportional to temperature, volume is proportional to temperature, and pressure and volume are inversely proportional.
  • Combining these relationships yields the ideal gas equation: pV = nRT = mRT/Mr, where:
    • p = pressure in Pascals
    • V = volume in m³
    • n = moles
    • T = temperature in Kelvin
    • m = mass in grams
    • R = ideal gas constant (8.31 J K⁻¹ mol⁻¹).

Empirical and Molecular Formulae

  • Empirical formula: The simplest whole number ratio of atoms of each element in a compound, determined using molar ratios.
  • Molecular formula: The true number of each atom in a molecule, calculated using the empirical formula's Mr and the molecule's true Mr (which gives a multiplier).

Equations and Calculations

  • Chemical equations must be balanced for accurate calculations and reflecting reacting proportions.
    • Balanced equations allow the calculation of reacting masses, percentage yield, and atom economy.
  • Percentage yield = (Experimental mass/Theoretical mass) x 100
  • Atom economy = (Mr of desired product/Mr of reactants) x 100.
  • High atom economy is desirable in industrial processes as it minimizes waste, reducing environmental impact and cost.

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Description

This quiz covers key concepts in chemistry regarding relative atomic mass, relative molecular mass, moles, and the Avogadro constant. You'll explore the relationships between these concepts and their applications in gas equations and calculations. Test your understanding of fundamental chemical principles and their significance in various calculations.

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