A chemist burns 567 liters of propane (C3H8). How many liters of carbon dioxide are made at 1.04 atm and 1,995 degrees Celsius? C3H8 (g) + 5O2 (g) --> 3CO2 (g) + 4H2O (g)
Understand the Problem
The question is asking us to calculate the volume of carbon dioxide (CO2) produced from the complete combustion of 567 liters of propane (C3H8) at a given pressure and temperature. We will use the ideal gas law and stoichiometry to solve this problem. First, we need to account for the number of moles of propane using PV=nRT, then using molar ratios from the equation, find the number of moles of carbon dioxide produced, and then use PV=nRT again to find the volume of carbon dioxide.
Answer
$1699.4$ L
Answer for screen readers
The volume of $CO_2$ produced is approximately $1699.4$ L.
Steps to Solve
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Write the balanced chemical equation for the combustion of propane.
The balanced chemical equation for the complete combustion of propane ($C_3H_8$) is: $C_3H_8(g) + 5O_2(g) \rightarrow 3CO_2(g) + 4H_2O(g)$
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Use the ideal gas law to find the number of moles of propane.
The ideal gas law is given by $PV = nRT$, where:
- $P$ = pressure (1.00 atm)
- $V$ = volume (567 L)
- $n$ = number of moles
- $R$ = ideal gas constant (0.0821 L atm / (mol K))
- $T$ = temperature (298 K)
Rearrange the ideal gas law to solve for $n$: $n = \frac{PV}{RT}$
Plug in the values for propane: $n = \frac{(1.00 , \text{atm})(567 , \text{L})}{(0.0821 , \frac{\text{L atm}}{\text{mol K}})(298 , \text{K})} \approx 23.16 , \text{mol}$
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Determine the number of moles of carbon dioxide produced.
From the balanced chemical equation, 1 mole of $C_3H_8$ produces 3 moles of $CO_2$. Therefore, the number of moles of $CO_2$ produced is: $n_{CO_2} = 3 \times n_{C_3H_8} = 3 \times 23.16 , \text{mol} \approx 69.48 , \text{mol}$
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Use the ideal gas law to find the volume of carbon dioxide.
Using the ideal gas law again, solve for the volume of $CO_2$: $V = \frac{nRT}{P}$
Plug in the values for carbon dioxide: $V = \frac{(69.48 , \text{mol})(0.0821 , \frac{\text{L atm}}{\text{mol K}})(298 , \text{K})}{(1.00 , \text{atm})} \approx 1699.4 , \text{L}$
The volume of $CO_2$ produced is approximately $1699.4$ L.
More Information
The stoichiometry of the balanced chemical reaction is crucial for determining the molar ratios between reactants and products. The ideal gas law is used to relate pressure, volume, temperature, and the number of moles of a gas.
Tips
A common mistake is not balancing the chemical equation correctly, which leads to incorrect mole ratios. Another mistake involves using incorrect units for the ideal gas law constant, pressure, volume, or temperature. For example, temperature needs to be in Kelvin.
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