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Questions and Answers
What defines a functional group in organic chemistry?
What defines a functional group in organic chemistry?
Which functional group is represented by the structure -COOH?
Which functional group is represented by the structure -COOH?
What is the primary characteristic of a hydroxyl group?
What is the primary characteristic of a hydroxyl group?
Which statement about the methyl group is accurate?
Which statement about the methyl group is accurate?
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What role does 'R' play in the representation of organic compounds?
What role does 'R' play in the representation of organic compounds?
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Which of the following groups is not a major functional group found in biological molecules?
Which of the following groups is not a major functional group found in biological molecules?
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Which functional group is described as containing a nitrogen atom attached to two hydrogen atoms?
Which functional group is described as containing a nitrogen atom attached to two hydrogen atoms?
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Which functional group can be identified by the structure C=O?
Which functional group can be identified by the structure C=O?
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What are polysaccharides primarily composed of?
What are polysaccharides primarily composed of?
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Which polysaccharide serves as the main form of stored carbohydrate in the body?
Which polysaccharide serves as the main form of stored carbohydrate in the body?
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Which of the following is true about cellulose?
Which of the following is true about cellulose?
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Chitin is primarily found in which of the following?
Chitin is primarily found in which of the following?
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What structural feature distinguishes chitin from cellulose?
What structural feature distinguishes chitin from cellulose?
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Which polysaccharide is known for being an ideal storage molecule for energy?
Which polysaccharide is known for being an ideal storage molecule for energy?
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What percentage of total organic carbon on Earth does cellulose comprise?
What percentage of total organic carbon on Earth does cellulose comprise?
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What characteristic is true for polysaccharides in general?
What characteristic is true for polysaccharides in general?
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What is another name for the sulfhydryl group?
What is another name for the sulfhydryl group?
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Which class of organic molecules is characterized by the formula (CH2O)n?
Which class of organic molecules is characterized by the formula (CH2O)n?
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What type of reaction is characterized by the loss of a water molecule when two substances are joined?
What type of reaction is characterized by the loss of a water molecule when two substances are joined?
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What distinguishes aldoses from ketoses in monosaccharides?
What distinguishes aldoses from ketoses in monosaccharides?
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Which of the following is a primary role of the phosphate group in nucleotides?
Which of the following is a primary role of the phosphate group in nucleotides?
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Why can't humans digest cellulose?
Why can't humans digest cellulose?
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What type of carbohydrate consists of two monosaccharides?
What type of carbohydrate consists of two monosaccharides?
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What are the basic building blocks of nucleic acids?
What are the basic building blocks of nucleic acids?
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Study Notes
Overview of Organic Chemistry
- Organic chemistry studies carbon-containing compounds, focusing on their structures, synthesis, and reactions.
- Organic molecules, primarily hydrocarbons, feature carbon atoms bonded to hydrogen and other elements.
Functional Groups
- Functional groups are specific atom arrangements that grant molecules characteristic properties.
- Major functional groups in biological molecules include:
- Hydroxyl (-OH)
- Methyl (-CH3)
- Carboxyl (-COOH)
- Carbonyl (C=O)
- Amino (-NH2)
- Phosphate (-PO4)
Methyl Group
- The methyl group is the smallest hydrocarbon functional group (-CH3).
- Methylation plays a role in regulating gene expression, protein function, and RNA metabolism.
Hydroxyl Group
- The hydroxyl group (-OH) is present in alcohols, phenols, and carboxylic acids.
- Common in biological molecules, found in carbohydrates, amino acids, and nucleic acids.
- Ethanol (EtOH) is an example of a molecule containing a hydroxyl group.
Carbonyl Group
- The carbonyl group features a carbon atom double-bonded to an oxygen atom (C=O).
- Exists in two varieties: at the end (aldehyde) or in the middle (ketone) of a carbon chain.
Carboxyl Group
- The carboxyl group (-COOH) consists of a carbon atom double-bonded to an oxygen atom and bonded to a hydroxyl group.
- Present in carboxylic acids and amino acids.
Amino Group
- The amino group (-NH2) consists of nitrogen bonded to two hydrogen atoms.
- Found in all amines and amino acids, it provides bonding opportunities due to the presence of a lone electron.
Sulfhydryl Group
- Comprises a sulfur atom bonded to a hydrogen atom (-SH).
- Known as a thiol group, this functional group is important in biological systems.
Polysaccharides
- Complex carbohydrates made of monosaccharide chains linked by glycosidic bonds.
- Ideal for energy storage, large and insoluble, and fold into compact shapes.
Types of Polysaccharides
- Glycogen: A branched polysaccharide stored in animals’ liver and muscles; it serves as the main carbohydrate reservoir for glucose.
- Cellulose: The most abundant organic compound, crucial for plant structure; it is fully permeable to water and solutes.
- Chitin: An unbranched polysaccharide found in arthropod cuticles and fungal cell walls, similar to cellulose.
Phosphate Group
- Part of nucleotides (-PO4); critical for energy transfer in cells (ATP).
- Regulates protein function depending on its presence or absence.
Monomers and Polymers
- Oligomers consist of fewer than 50 monomers linked together.
- Condensation reactions join substances with the loss of a water molecule.
- Hydrolysis reactions involve water being added, resulting in decomposition.
Classes of Organic Molecules
- Four major classes include:
- Carbohydrates
- Proteins
- Lipids
- Nucleic Acids
Carbohydrates
- Composed of carbon and water in the ratio of one carbon to one water molecule (CH2O)n, often referred to as saccharides.
- Types include:
- Monosaccharides (e.g., glucose, fructose): Single sugar molecules.
- Disaccharides (e.g., lactose, sucrose): Formed from two monosaccharides.
- Polysaccharides: Composed of multiple sugars, which can be similar or diverse.
Families of Carbohydrates
- Aldoses: Have a carbonyl at the end of the carbon chain.
- Ketoses: Have a carbonyl within the chain, commonly as 2-ketoses.
Starch vs Cellulose
- Starch is digestible due to alpha glycosidic linkages.
- Cellulose has beta glycosidic linkages, making it indigestible for humans due to a lack of suitable enzymes.
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