Trends in Transition Elements and Atomic Sizes Quiz
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Questions and Answers

What happens to the atomic radii as we move along the 3d series?

  • Increase rapidly
  • Remain constant
  • Decrease less rapidly (correct)
  • Decrease rapidly
  • Why do ionization energies increase only slightly along the 3d series?

  • Decrease in nuclear charge
  • Addition of more electrons to 4s orbital
  • Formation of highly charged ions
  • Increase in shielding effect by 3d electrons (correct)
  • Which configuration do the doubly or more highly charged ions in the d-block have?

  • Only s-electrons
  • Both s and d electrons
  • No 4s electrons (correct)
  • Only d-electrons
  • Why is there a general trend of increasing values of second ionization enthalpy as the effective nuclear charge increases?

    <p>One d electron does not shield another electron effectively</p> Signup and view all the answers

    The trend of steady increase in second and third ionization enthalpy breaks for the formation of which ions?

    <p>Mn2+</p> Signup and view all the answers

    Which factor is responsible for the value of ionization enthalpy?

    <p>Attraction of electrons towards nucleus, repulsion between electrons, and exchange energy</p> Signup and view all the answers

    Why does ionization enthalpy generally increase along a period in the periodic table?

    <p>Due to the increase in the effective nuclear charge.</p> Signup and view all the answers

    Why are transition elements known for forming colored compounds?

    <p>Due to the presence of multiple oxidation states.</p> Signup and view all the answers

    Which factor contributes the most to the stability of higher oxidation states in transition metals?

    <p>The ability to form multiple bonds.</p> Signup and view all the answers

    Why do transition metals have higher melting points compared to main group elements?

    <p>Due to the involvement of d electrons in metallic bonding.</p> Signup and view all the answers

    Why do lanthanoids generally have higher ionization enthalpies compared to actinoids?

    <p>Due to the presence of f electrons in lanthanoids.</p> Signup and view all the answers

    Why does copper not replace hydrogen from acids?

    <p>Copper has a positive E∘ value, making it more reactive than hydrogen.</p> Signup and view all the answers

    Why are the E- values for Mn, Ni, and Zn more negative than expected?

    <p>The metals quickly lose electrons and get oxidized.</p> Signup and view all the answers

    What is the reason behind the general trend of increasing values of second ionization enthalpy as the effective nuclear charge increases?

    <p>The formation of doubly charged ions in the d-block.</p> Signup and view all the answers

    How do the properties of Mn2+ and Zn2+ ions relate to their respective E- values?

    <p>Mn2+ and Zn2+ have half-filled and fully filled d orbitals respectively.</p> Signup and view all the answers

    Why does copper have a positive E∘ value compared to hydrogen?

    <p>Copper's d-orbitals are completely filled.</p> Signup and view all the answers

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