Chemistry: Transition Elements Enthalpies Quiz
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Questions and Answers

Which transition element has the highest enthalpy of atomization?

  • Cr
  • Mo
  • W (correct)
  • V
  • Which characteristic is responsible for the paramagnetic behavior of transition elements?

  • Presence of unpaired electrons (correct)
  • Low atomic radius
  • High electronegativity
  • High ionization energy
  • Which transition element has the lowest ionization enthalpy?

  • Co
  • Ni
  • Fe
  • Sc (correct)
  • In which transition element do we observe a significant increase in metallic/ionic radii going from M to M2+?

    <p>Mn</p> Signup and view all the answers

    Which transition element exhibits the highest oxidation state?

    <p>Ta</p> Signup and view all the answers

    Among the transition elements listed, which one shows a positive value for the 3+/2+ redox potential?

    <p>Cr</p> Signup and view all the answers

    Which property is responsible for the stabilisation of energy states?

    <p>Exchange energy</p> Signup and view all the answers

    Why does the loss of exchange energy increase stability?

    <p>It decreases the number of possible pairs of parallel spins</p> Signup and view all the answers

    Which configuration results in no loss of exchange energy?

    <p>d6</p> Signup and view all the answers

    Why does Mn+ have a lower ionisation enthalpy than Cr+?

    <p>Mn+ has a 3d54s1 configuration</p> Signup and view all the answers

    Why does Fe2+ have a lower ionisation enthalpy than Mn2+?

    <p>Fe2+ has a d6 configuration</p> Signup and view all the answers

    Why is the third ionisation enthalpy of Fe lower than that of Mn?

    <p>Fe has a more stable electron configuration</p> Signup and view all the answers

    Why do transition elements exhibit stronger bonding between atoms compared to non-transition elements?

    <p>Transition elements have a higher number of unpaired electrons in their atoms.</p> Signup and view all the answers

    In the series Sc (Z = 21) to Zn (Z = 30), why does zinc (Z = 30) have the lowest enthalpy of atomisation?

    <p>Zinc has the least number of unpaired electrons.</p> Signup and view all the answers

    What accounts for the increase in ionisation enthalpy along each series of transition elements from left to right?

    <p>Increase in nuclear charge</p> Signup and view all the answers

    How does the variation in ionisation enthalpy along a series of transition elements compare to that along a period of non-transition elements?

    <p>It increases at a slower rate</p> Signup and view all the answers

    Why does the first ionisation enthalpy of metals in the 3d series show an irregular trend?

    <p>Presence of unpaired electrons in 3d orbitals</p> Signup and view all the answers

    What effect does the removal of one electron have on the relative energies of 4s and 3d orbitals in transition elements?

    <p>It destabilizes the 4s orbital.</p> Signup and view all the answers

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