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What is thermochemistry?
What is thermochemistry?
Thermochemistry is a branch of chemistry that describes the energy changes that occur during chemical reactions.
Energy is defined as the capacity to do work or to produce heat.
Energy is defined as the capacity to do work or to produce heat.
True (A)
What is work in terms of energy?
What is work in terms of energy?
Work is a force acting over a distance, and it is a form of energy that can be expressed as the product of force and distance.
What is heat, and how does it flow?
What is heat, and how does it flow?
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What is potential energy?
What is potential energy?
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What type of energy does a cat sitting on the highest branch of a tree possess?
What type of energy does a cat sitting on the highest branch of a tree possess?
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What happens to the cat's potential energy when it falls from the branch?
What happens to the cat's potential energy when it falls from the branch?
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Identify which of the following are forms of potential energy.
Identify which of the following are forms of potential energy.
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What is kinetic energy?
What is kinetic energy?
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A waterfall has potential energy prior to flowing downward.
A waterfall has potential energy prior to flowing downward.
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How is kinetic energy used to produce electricity in a hydroelectric plant?
How is kinetic energy used to produce electricity in a hydroelectric plant?
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What is an endothermic reaction?
What is an endothermic reaction?
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In an endothermic reaction, the reaction vessel cools as heat is absorbed.
In an endothermic reaction, the reaction vessel cools as heat is absorbed.
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In an exothermic reaction, the reaction vessel warms as heat is evolved.
In an exothermic reaction, the reaction vessel warms as heat is evolved.
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The value of q is always positive in an exothermic reaction.
The value of q is always positive in an exothermic reaction.
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What does the calorie measure?
What does the calorie measure?
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What is the SI unit of heat and energy?
What is the SI unit of heat and energy?
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What is the relationship between the calorie and the joule?
What is the relationship between the calorie and the joule?
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What does the law of conservation of energy state?
What does the law of conservation of energy state?
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To heat your home, chemical energy is converted into a different form of energy.
To heat your home, chemical energy is converted into a different form of energy.
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Sunlight is directly transformed into kinetic energy by plants.
Sunlight is directly transformed into kinetic energy by plants.
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What is thermodynamics?
What is thermodynamics?
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The first law of thermodynamics is the law of conservation of energy.
The first law of thermodynamics is the law of conservation of energy.
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What does the first law of thermodynamics imply about the total amount of energy in the universe?
What does the first law of thermodynamics imply about the total amount of energy in the universe?
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Perpetual motion machines are possible according to the first law of thermodynamics.
Perpetual motion machines are possible according to the first law of thermodynamics.
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How can humans convert chemical energy in food into kinetic energy?
How can humans convert chemical energy in food into kinetic energy?
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How do plants convert light energy into chemical energy?
How do plants convert light energy into chemical energy?
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The change in internal energy is dependent on the pathway taken to reach a particular state.
The change in internal energy is dependent on the pathway taken to reach a particular state.
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What is a state function?
What is a state function?
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What are some examples of state functions?
What are some examples of state functions?
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Heat and work are considered state functions.
Heat and work are considered state functions.
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How does the path taken to reach a specific state affect the amount of work required?
How does the path taken to reach a specific state affect the amount of work required?
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What is the relationship between change in internal energy (ΔE), heat (q), and work (w)?
What is the relationship between change in internal energy (ΔE), heat (q), and work (w)?
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What does a positive value of q signify?
What does a positive value of q signify?
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What happens to the temperature of a system when it absorbs heat?
What happens to the temperature of a system when it absorbs heat?
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What is heat capacity?
What is heat capacity?
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What are the units for heat capacity?
What are the units for heat capacity?
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What is specific heat capacity?
What is specific heat capacity?
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The specific heat capacity of water is very low, causing it to heat up quickly.
The specific heat capacity of water is very low, causing it to heat up quickly.
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What is the relationship between the heat capacity of an object, its mass, and its specific heat?
What is the relationship between the heat capacity of an object, its mass, and its specific heat?
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What is the equation used to calculate the amount of heat (q) absorbed or released by an object?
What is the equation used to calculate the amount of heat (q) absorbed or released by an object?
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What are the two reasons why adding water to a saucepan can cause its temperature to rise more slowly?
What are the two reasons why adding water to a saucepan can cause its temperature to rise more slowly?
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What is enthalpy (H)?
What is enthalpy (H)?
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What is enthalpy change (ΔH)?
What is enthalpy change (ΔH)?
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Study Notes
Thermochemistry
- Thermochemistry is a branch of chemistry that describes the energy changes that occur during chemical reactions.
- Energy is defined as the capacity to do work or produce heat.
- Work is a force acting over a distance.
- Energy = work = force × distance.
- Heat, represented by "q," is energy that transfers between objects due to a temperature difference.
- Heat flows from warmer to cooler objects.
- Only changes in heat are detectable.
Nature of Energy
- Energy is defined as the capacity to do work or produce heat.
- Work (w) is a force acting over a distance.
- Energy = work = force × distance.
- Heat (q) is energy that transfers from one object to another due to a temperature difference.
- Heat only changes can be detected.
- Heat flows from warmer to cooler objects.
Classification of Energy
- Potential energy is stored energy; it is associated with the position of an object.
- A cat sitting on a high branch has potential energy.
- If the cat falls, its potential energy converts to kinetic energy (energy of motion).
Types of Energy
- Electrical energy, nuclear energy, and chemical energy are different forms of potential energy.
- Examples of various types of energy illustrated: thermal, radiant, electrical, nuclear, and chemical energies.
Kinetic Energy
- Kinetic energy is the energy an object possesses due to its motion.
- Water at the top of a waterfall has potential energy.
- As it flows downward, the potential energy converts to kinetic energy, which can be used to do work in a hydroelectric plant.
Endothermic vs. Exothermic
- Endothermic reactions absorb heat from the surroundings; the system gains heat, and the surroundings lose heat.
- Exothermic reactions release heat into the surroundings; the system loses heat, and the surroundings gain heat.
- In endothermic reactions, the reaction vessel cools. Heat is absorbed. Energy is added to the system. q is positive.
- In exothermic reactions, the reaction vessel warms. Heat is evolved. Energy is subtracted from the system. q is negative.
Units of Energy
- Calorie (cal) is the heat needed to raise the temperature of one gram of water by 1°C.
- Joule (J) is the SI unit of heat and energy.
- 1 cal = 4.184 J
- 1 Calorie (Cal) or kilocalorie (kcal) = 1000 cal = 4184 J
Conservation of Energy
- The law of conservation of energy states that energy cannot be created or destroyed but can be changed from one form to another.
- The total energy in a system at the beginning must be present at the end.
- Chemical energy can be converted into heat to heat your home.
- Sunlight converts to chemical energy in green plants.
The First Law of Thermodynamics
- Thermodynamics is the study of energy and its interconversions.
- The first law of thermodynamics is the law of conservation of energy for a system.
- The total amount of energy in the universe is constant.
Energy Transformations
- Humans convert chemical energy in food into kinetic energy, like riding a bicycle.
- Plants convert electromagnetic (light) radiation from the sun into chemical energy.
Internal Energy
- Internal energy is the sum of the kinetic and potential energies of all the particles in a system.
- The change in internal energy depends only on the initial and final conditions, not on how the energy changed.
- A state function depends on the initial and final conditions, not on the path taken.
State Functions
- State functions—temperature, pressure, volume, potential energy—do not depend on the path taken.
- Heat and work are not state functions as they are path dependent.
- A car's position at the top of a ramp depends only on elevation, not how the car reached that position.
Energy Exchange
- Internal energy is the sum of the kinetic and potential energies of the particles in the system. Internal Changes are dependent on only the initial and final states and NOT the path.
- Change in internal energy, ΔE, is the sum of heat transfer, q (positive for heat absorbed), and work done by or on the system (w, positive for work done on the system).
Conventions of q and w
- A positive q indicates heat input to the system.
- A negative q indicates heat output from the system.
- A positive w indicates work done on the system.
- A negative w indicates work done by the system.
Quantity of Heat Energy Absorbed: Heat Capacity
- When a system absorbs heat, its temperature increases.
- The increase in temperature is directly proportional to the amount of heat absorbed.
- The proportionality constant is heat capacity (C).
- Heat capacity units are J/°C or J/K.
- The greater the heat capacity, the more heat needed to raise its temperature.
Specific Heat Capacity
- Specific heat capacity is the amount of heat energy to raise the temperature of one gram of a substance by 1°C.
- Water has a very high specific heat capacity compared to other substances.
- Different substances have varying specific heat capacities which determines how quickly they heat up or cool down.
Quantifying Heat Energy
- Heat absorbed by an object is determined by mass, specific heat, and temperature change.
- Heat (q) = mass (m) × specific heat capacity (Cs) × Temperature change (ΔT).
Enthalpy
- Enthalpy (H) deals with the amount of heat absorbed or released during a chemical reaction under constant pressure.
- Enthalpy change (ΔHrxn) is the heat involved in a reaction at constant pressure.
- Positive ΔH indicates an endothermic reaction (heat absorbed).
- Negative ΔH indicates an exothermic reaction (heat released).
Stoichiometry Involving ΔH
- The enthalpy change for a chemical reaction (ΔHrxn) is related to the amount of material in the reaction.
- Heat absorbed or released during chemical reactions can be calculated using ΔH, the amount of material, and stoichiometric ratios.
Hess's Law
- The enthalpy change for a reaction is independent of the route taken.
- If a chemical reaction can be expressed as a series of steps, the enthalpy change for the overall reaction is the sum of the enthalpy changes for each step.
- The overall enthalpy change depends only on the initial and final states, not the reaction pathway.
Standard Conditions
- Standard conditions are defined conditions (temperature, pressure, etc) under which physical or chemical changes are studied.
- Standard state: pure substance, gas at 1 atm pressure, in most stable form, at 25 °C (298 K).
- Standard enthalpy of formation (ΔH°f) is the enthalpy change when one mole of a compound is formed from its constituent elements in their standard states.
Calculating Standard Enthalpy Change for a Reaction
- The standard enthalpy change for a reaction is the sum of the standard enthalpies of formation of the products minus the sum of the standard enthalpies of formation of the reactants.
- ΔH°rxn = ΣnΔH°f (products) - ΣnΔH°f (reactants).
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Description
This quiz covers the fundamental concepts of thermochemistry, including the definitions and classifications of energy, work, and heat transfer. It also explores potential energy and its relation to the position of objects. Test your understanding of these essential physics and chemistry principles.