Podcast
Questions and Answers
What is the main product formed when 1° aliphatic amines react with nitrous acid?
What is the main product formed when 1° aliphatic amines react with nitrous acid?
- Aromatic diazonium salts
- Stable aliphatic diazonium salts
- Highly unstable aliphatic diazonium salts (correct)
- N-nitrosoamines
By what mechanism do aliphatic diazonium salts decompose?
By what mechanism do aliphatic diazonium salts decompose?
- Losing nitrogen to form carbocations (correct)
- Reduction
- Formation of free radicals
- Oxidation
Which is a major reason why diazotization of primary aliphatic amines is not synthetically important?
Which is a major reason why diazotization of primary aliphatic amines is not synthetically important?
- Products are highly toxic
- Requires very high temperatures
- Produces a complex mixture of products (correct)
- Does not produce any useful compounds
What happens to arenediazonium salts if the reaction mixture's temperature exceeds 5 °C?
What happens to arenediazonium salts if the reaction mixture's temperature exceeds 5 °C?
What are the products formed when aliphatic diazonium salts decompose?
What are the products formed when aliphatic diazonium salts decompose?
Which reaction occurs when secondary amines react with nitrous acid?
Which reaction occurs when secondary amines react with nitrous acid?
What occurs when 3° aliphatic amine is mixed with HNO2?
What occurs when 3° aliphatic amine is mixed with HNO2?
Where does nitrosation occur on tertiary arylamines if the para position is open?
Where does nitrosation occur on tertiary arylamines if the para position is open?
What are the stable products in aqueous acid from reactions involving N-nitrosoammonium compounds?
What are the stable products in aqueous acid from reactions involving N-nitrosoammonium compounds?
Primary arylamines react with nitrous acid to form which type of compound?
Primary arylamines react with nitrous acid to form which type of compound?
