Saponification: The Process of Making Soap

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40 Questions

What is the title displayed on the laptop screen?

Saponification

What is shown in the left box below the title?

A picture of someone's hands washing soap

What phrase is written in the left box underneath 'Saponification'?

The Process of Making Soap

What does the image in the right box depict?

An assortment of bars of soap

Where do the bars of soap in the right box appear to be located?

In a store aisle

What ions are present in hard water that prevent it from lathering easily?

Ca and Mg

What substance is formed when soap reacts with hard water?

Soap scum

Which compound reacts with sodium stearate in hard water to produce calcium stearate?

Calcium hydrogen carbonate

What is one of the problems caused by using hard water?

More soap is needed to get a lather

Why is hard water unsuitable for some industrial processes?

It can interfere with dyeing

What is the hydrophobic tail of sodium stearate attracted to?

Oily, greasy substances

What is the hydrophilic head of sodium stearate attracted to?

Water molecules

What characteristic of sodium stearate makes it effective in cleaning greasy substances?

Its hydrophobic tail

Which part of sodium stearate molecule is responsible for its attraction to water?

Its hydrophilic head

Which of the following statements is true about sodium stearate?

The hydrophilic head is attracted to water molecules

Which group is present in soaps?

Sodium carboxylates (RCOO-Na)

Which group is present in detergents?

Sodium sulphonates (RSO3-Na)

What is one main difference between soaps and detergents based on their chemical groups?

Soaps contain sodium carboxylates while detergents contain sodium sulphonates.

Which cleaning agent contains sodium sulphonates?

Detergents

Which cleaning agent contains sodium carboxylates?

Soaps

Which type of detergent has a negative charge at the end?

Anionic

What type of detergent is commonly used in hospitals for its bactericidal action?

Cationic

Which type of detergent does not ionize or foam?

Non-ionic

Which additive is used in detergents to maintain or increase foam?

Foaming agents

Sodium perborate is an example of which type of additive?

Bleach

Which property allows detergents to work with both hard and soft water?

They work equally well with hard and soft water

What pH level are detergents described as being?

Neutral (pH 7)

Which advantage of detergents makes them suitable for delicate fabrics?

They are suitable for delicate fabrics

Why can detergents be used in acid solutions?

They are neutral (pH 7)

What advantage indicates that detergents have a slight disinfectant property?

They are moderately antiseptic

Which type of surfactants have no charge?

Non-ionic

Which type of surfactants are predominantly negatively charged?

Anionic

Which of the following is an example of a non-ionic surfactant?

Polyethyleneglycols

What is a characteristic of cationic surfactants?

They have a strong positive charge.

Which type of surfactant is useful for detergency and foam formation?

Non-ionic + Ionic

Which of the following is an example of an anionic surfactant?

Linear alkyl sulfonate

Which surfactant type can be both antimicrobial and beneficial in medical products?

Cationic

Non-ionic surfactants are not very effective under which conditions?

Extreme temperatures and high mineral content in water

Which of these substances is a quaternary ammonium salt?

Cetylpyridinium chloride

Which type of surfactants mix with large amounts of broth?

Non-ionic + Ionic

Study Notes

Saponification

  • The process of making soap
  • Involves the reaction of sodium stearate with calcium hydrogen carbonate in hard water to form calcium stearate and sodium hydrogen carbonate

Sodium Stearate

  • Hydrophobic tail is attracted to oily, greasy substances
  • Hydrophilic head is attracted to water molecules

Hard Water and Soap

  • Hard water consists of Ca or Mg ions and does not lather easily
  • Soap "scum" is formed by the reaction of soap with calcium hydrogen carbonate in hard water
  • Using hard water can cause problems, such as:
    • More soap is needed to get a lather
    • Difficulty cleaning scum from bathtubs and sinks
    • Unsuitable for industrial processes like dyeing

Soaps vs Detergents

  • Soaps contain sodium carboxylates (RCOO-Na) group
  • Detergents contain sodium sulphonates (RSO3-Na) group
  • Advantages of detergents:
    • Act as wetting agents
    • Work equally well with hard and soft water
    • Neutral (pH 7)
    • Can be used in acid solutions
    • Moderately antiseptic
    • Suitable for delicate fabrics

Chemical Composition of Detergents

  • Three main types of detergents:
    • Anionic: Have a negative charge at the end, e.g. sodium stearate
    • Cationic: Contain a positive ion like substituted ammonium ions
    • Non-ionic: Do not ionize or foam, e.g. polyethyleneglycols
  • Other additives include:
    • Foaming agents
    • Builders or fillers
    • Bleaches like sodium perborate

Surfactants

  • Surface active agents
  • Types of surfactants:
    • Non-ionic: Have no charge, form micelles, e.g. polyethyleneglycols, fatty acids, PLA
    • Anionic: Predominantly negatively charged, e.g. soaps, linear alkyl benzene sulfonate (LAS)
    • Cationic: Strong positive charge, e.g. quaternary ammonium salts, cetylpyridinium chloride
    • Non-ionic + Ionic: Have both positive and negative charges, e.g. fatty acids, can be in "quat" or amphoteric surfactants

Learn about the process of saponification, a crucial step in making soap. From the chemistry behind it to the final product, this quiz covers it all.

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