Reactions of Metal Ions with Various Reagents

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What precipitate is formed when $Mg^{2+}$ reacts with $NaOH(aq)$ and is it soluble or insoluble in excess?

White precipitate, insoluble in excess

Describe the reaction of $Ca^{2+}$ with dilute $H_2SO_4(aq)$.

White precipitate

What observation is made when $NH_4^+$ reacts with $NaOH(aq)$?

On warming, releases a gas that turns damp red litmus paper blue.

What color change occurs when $Cu^{2+}$ reacts with concentrated $HCl$?

Green-yellow solution

What precipitate is formed when $Fe^{3+}$ reacts with $Na_2CO_3(aq)$, and what additional observation can be made?

Green precipitate and gentle effervescence

What happens when $Ba^{2+}$ reacts with dilute $H_2SO_4(aq)$?

White precipitate

Study Notes

Reactions of Metal Ions with NaOH

  • Mg2+ reacts with NaOH to form a white precipitate of Mg(OH)2
  • Ca2+ reacts with NaOH to form a white precipitate of Ca(OH)2
  • Cu2+ reacts with NaOH to form a blue precipitate, insoluble in excess, forming [Cu(H2O)4(OH)2]
  • Fe2+ reacts with NaOH to form a green precipitate, insoluble in excess, forming [Fe(H2O)4(OH)2]

Reactions of Metal Ions with NH3

  • Cu2+ reacts with NH3 to form a blue precipitate, soluble in excess, forming [Cu(H2O)2(NH3)4]2+
  • Fe2+ reacts with NH3 to form a green precipitate, insoluble in excess

Reactions of Metal Ions with Na2CO3

  • Cu2+ reacts with Na2CO3 to form a blue-green precipitate of CuCO3

Reactions of Metal Ions with Dilute H2SO4

  • Ca2+ reacts with dilute H2SO4 to form a white precipitate of CaSO4
  • Sr2+ reacts with dilute H2SO4 to form a white precipitate of SrSO4
  • Ba2+ reacts with dilute H2SO4 to form a white precipitate of BaSO4

Reactions of Metal Ions with Concentrated HCl

  • Cu2+ reacts with concentrated HCl to form a green-yellow solution of [CuCl4]2-

Reactions of Metal Ions with Other Reagents

  • NH4+ reacts with NaOH to release a gas that turns damp red litmus paper blue

This quiz summarizes the reactions of different metal ions with NaOH, NH3, Na2CO3, dilute H2SO4, and concentrated HCl. Identifying the reactions helps to understand chemical properties of metal ions.

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